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Lighting Up Invisible Twisted Intramolecular Charge Transfer State by High Pressure
摘要： The twisted intramolecular charge transfer (TICT) state plays an important role in determining the performance of optoelectronic devices. However, for some non-fluorescent TICT molecules, 'invisible' TICT state could only be visualized by modifying the molecular structure. Here, we introduce a new facile pressure-induced approach to light up the TICT state through the use of the pressure related liquid–solid phase transition of the surrounding solvent. Combining ultrafast spectroscopy and quantum chemical calculations, it reveals that the 'invisible' TICT state can emit fluorescence when the rotation of a donor group is restricted by the frozen acetonitrile solution. Furthermore, the TICT process can even be effectively regulated by the external pressure. Our study offers a unique strategy to achieve dual fluorescence behavior in charge transfer molecules and is of significance for optoelectronic and biomedical applications.
关键词： Dual fluorescence,Twisted intramolecular charge transfer,High pressure,Ultrafast spectroscopy
更新于2025-09-19 17:15:36
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Cross-band infrared laser absorption of carbon monoxide for thermometry and species sensing in high-pressure rocket flows
摘要： A novel cross-band laser absorption spectroscopy technique has been developed for quantitative measurements of gas temperature and carbon monoxide (CO) in high-pressure, high-temperature rocket combustion flows. The strategy enables a broad range of sensor operability by simultaneously probing rovibrational transitions in both the fundamental and first overtone bands of CO near 4.98 μm and 2.32 μm, respectively, which sustain large differences in temperature dependence despite collisional broadening. Scanned-wavelength modulation spectroscopy methods are integrated for noise rejection in the harsh rocket operating environment. Initial experiments using the cross-band thermometry technique have been conducted on a single-element-injector rocket combustor with RP-2/GOx and CH4∕GOx propellant combinations at pressures up to 75 bar. Measurements of the first overtone bandhead (2.32 μm) maintained adequate signal-to-noise at even higher pressures (up to 105 bar), although deviating significantly from spectral simulations. To account for collisional effects at high gas densities, empirical models for line mixing, developed via shock tube studies, were employed to enable quantitative interpretation of measured signals for temperature and CO mole fraction in the rocket combustor.
关键词： thermometry,high-pressure rocket flows,species sensing,carbon monoxide,cross-band laser absorption spectroscopy
更新于2025-09-19 17:13:59
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[IEEE 2019 IEEE Pulsed Power & Plasma Science (PPPS) - Orlando, FL, USA (2019.6.23-2019.6.29)] 2019 IEEE Pulsed Power & Plasma Science (PPPS) - 2D Simulations of the NS-Laser Shock Peening
摘要： We report on the impact of H2 high-pressure annealing (HPA) onto In0.7Ga0.3As MOSCAPs and quantum-well (QW) MOSFETs with Al2O3/HfO2 gate-stack. After HPA with process condition of 300 °C, H2 ambient and pressure of 20 atm, we observed notable improvements of the capacitance–voltage (CV) characteristics in InGaAs MOSCAPs with Al2O3/HfO2 gate-stack, such as reduction of equivalent-oxide-thickness and less frequency dispersion in the accumulation region. There was 20% improvement of the interfacial trap density ( Dit). Then, we incorporated the HPA process into the fabrication of sub-100-nm In0.7Ga0.3As QW MOSFETs, to investigate the impact of HPA process. After HPA process, the device with L g = 50 nm exhibits improved subthreshold-swing (SS) = 105 mV/decade, in comparison with SS = 130 mV/decade for the reference device without HPA process. Finally, we carried out reliability assessment under a constant-voltage-stress (CVS), and it turns out that the HPA process was effective in mitigating a shift of threshold voltage ((cid:2)VT ) during the CVS. These are attributed to the effective passivation of oxide traps in the high-k dielectric layer and interfacial traps, after HPA process in the H2 ambient.
关键词： interfacial trap density (Dit),subthreshold-swing (SS),high-pressure annealing,atomic layer deposition (ALD),InGaAs MOSFET
更新于2025-09-19 17:13:59
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Spectral characteristics of underwater laser-induced breakdown spectroscopy at high pressure conditions
摘要： Laser-induced breakdown spectroscopy (LIBS) has been proven to be an attractive technique for the in-situ oceanic applications. However, when applying LIBS into deep-sea, the pressure effect caused by different ocean depth is inescapable and could have great influence on the LIBS signals. In this work, spectral characteristics of underwater LIBS were investigated as a function of pressure in the range of 0.1–45 MPa. A high-pressure chamber built in the laboratory was used to simulate the high-pressure environment of deep-sea. Optimal laser energy and detection delay were first determined under different pressure conditions and were shown to be independent on the external pressure. The increase in pressure has a significant impact both on the peak intensity and line broadening of the observed spectra. The peak intensity of Na, Li and K lines increases with the increasing pressure until a maximum intensity reached at 12.5 MPa. Above this value, the peak intensity decreases gradually up to 45 MPa. For Ca line, the maximum intensity was observed at 30 MPa. The line broadening keeps constant at low pressures from 0.1 to 10 MPa while it increases linearly at higher pressures, indicating a higher electron density caused by the compression effect of the high external pressure. We also compared the spectral data obtained from the high-pressure chamber and from the field sea trials, and the good consistency between the laboratory data and sea-trial data suggested the key role of pressure effect on underwater LIBS signals for the practical deep-sea applications.
关键词： high-pressure chamber,underwater laser-induced breakdown spectroscopy,deep-sea application,pressure effect,spectral characteristics
更新于2025-09-16 10:30:52
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High pressure and high temperature induced polymerization of C<sub>60</sub> quantum dots
摘要： We synthesized C60 quantum dots (QDs) with a uniform size by a modified ultrasonic process and studied its polymerization under high pressure and high temperature (HPHT). Raman spectroscopy showed that a phase assemblage of a dimer (D) phase (62 vol %) and one-dimensional chain with an orthorhombic (O) phase (38 vol %) was observed at 1.5 GPa and 300°C. At 2.0 GPa and 430°C, the proportion of the O phase increases to 46 vol %, while the corresponding D phase decreases to 54 vol %. Compared with bulk and nanosized C60, C60 QDs cannot easily form a high-dimensional polymeric structure. This fact is probably caused by the small particle size, orientation of the disordered structure of C60 QDs and the barrier of oxide function groups between C60 molecules. Our studies enhance understanding the polymerization behavior of low-dimension C60 nanomaterials under HPHT conditions.
关键词： high pressure and high temperature,C60 quantum dots,fullerene polymer
更新于2025-09-16 10:30:52
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Laser heating setup for diamond anvil cells for <i>in situ</i> synchrotron and in house high and ultra-high pressure studies
摘要： The diamond anvil cell (DAC) technique combined with laser heating is one of the major methods for studying materials at high pressure and high temperature conditions. In this work, we present a transferable double-sided laser heating setup for DACs with in situ temperature determination. The setup allows precise heating of samples inside a DAC at pressures above 200 GPa and could be combined with synchrotron beamline equipment. It can be applied to X-ray diffraction and X-ray transmission microscopy experiments. In the setup, we use high-magnification and low working distance infinity corrected laser focusing objectives that enable us to decrease the size of the laser beam to less than 5 μm and achieve the maximum optical magnification of 320 times. All optical components of the setup were chosen to minimize chromatic and spatial aberrations for accurate in situ temperature determination by multiwavelength spectroscopy in the 570–830 nm spectral range. Flexible design of our setup allows simple interchange of laser sources and focusing optics for application in different types of studies. The setup was successfully tested in house and at the high-pressure diffraction beamline ID15B at the European Synchrotron Radiation Facility. We demonstrate an example of application of the setup for the high pressure–high temperature powder diffraction study of PdH and X-ray transmission microscopy of platinum at 22(1) GPa as a novel method of melting detection in DACs.
关键词： high pressure,diamond anvil cell,X-ray transmission microscopy,X-ray diffraction,synchrotron,laser heating,high temperature
更新于2025-09-16 10:30:52
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Improved Ferroelectric Switching in Sputtered HfZrOx Device Enabled by High Pressure Annealing
摘要： HfZrOx exhibiting ferroelectricity in ultra-thin layers can be deposited in various ways. Specifically, in sputtered HZO layers, only weak ferroelectric switching with gradual transition and small remnant polarization (Pr) is demonstrated using conventional rapid thermal annealing at high temperatures of at least 750 oC. Here we show that rapidly transited ferroelectric switching with a larger 2 Pr of 24 μC/cm2 is achieved by introducing a high pressure annealing (HPA) at even lower temperature of 550 oC. Our findings reveal that the HPA enhances the crystallinity of grains in the HZO, thereby enlarging the Pr and strengthening breakdown conditions. Through short pulse techniques, how interface and bulk region in the HZO are involved in the switching depending on the HPA is also investigated.
关键词： HfZrOx,Ferroelectric switching,high pressure annealing
更新于2025-09-16 10:30:52
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Table-top nuclear magnetic resonance system for high-pressure studies with <i>in situ</i> laser heating
摘要： High pressure Nuclear Magnetic Resonance (NMR) is known to reveal the behavior of matter under extreme conditions. However, until now, significant maintenance demands, space requirements, and high costs of superconducting magnets render its application unfeasible for regular modern high pressure laboratories. Here, we present a table-top NMR system based on permanent Halbach magnet arrays with a diameter of 25 cm and height of 4 cm. At the highest field of 1013 mT, 1H-NMR spectra of ice VII have been recorded at 25 GPa and ambient temperature. The table-top NMR system can be used together with double sided laser heating setups. Feasibility of high-pressure high-temperature NMR was demonstrated by collecting 1H-NMR spectra of H2O at 25 GPa and 1063(50) K. The change in the signal intensity in a laser-heated NMR diamond anvil cell has been found to yield a convenient way for temperature measurements.
关键词： diamond anvil cell,laser heating,Halbach magnet,Nuclear Magnetic Resonance,high-pressure
更新于2025-09-16 10:30:52
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EXPRESS: Two-Dimensional Temperature Measurement in a High Temperature and Pressure Combustor Using Computed Tomography Tunable Diode Laser Absorption Spectroscopy (CT-TDLAS) with a Wide-Scanning Laser at 1335–1375 nm
摘要： Tunable diode laser absorption spectroscopy (TDLAS) technology is a developing method for temperature and species concentration measurements with the features of non-contact, high precision, high sensitivity, etc. The difficulty of two-dimensional (2D) temperature measurement in actual combustors has not yet been solved because of pressure broadening of absorption spectra, optical accessibility, etc. In this study, the combination of computed tomography (CT) and TDLAS with a wide scanning laser at 1335–1375 nm has been applied to a combustor for 2D temperature measurement in high temperature of 300–2000 K and high pressure of 0.1–2.5 MPa condition. An external cavity type laser diode with wide wavelength range scanning at 1335–1375 nm was used to evaluate the broadened H2O absorption spectra due to the high temperature and high pressure effect. The spectroscopic database in high temperature of 300–2000 K and high pressure of 0.1–5.0 MPa condition has been revised to improve the accuracy for temperature quantitative analysis. CT reconstruction accuracy was also evaluated in different cases, which presented the consistent temperature distribution between CT reconstruction and assumed distributions. The spatial and temporal distributions of temperature in the high temperature and high pressure combustor were measured successfully by CT-TDLAS using the revised spectroscopic database.
关键词： high temperature and high pressure field,TDLAS,computed tomography,2D,Two-dimensional temperature measurement,combustion,CT,tunable diode laser absorption spectroscopy
更新于2025-09-12 10:27:22
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Laser modification of high-pressure high-temperature nanodiamonds
摘要： Micro-thin semitransparent films of purified high pressure high temperature nanodiamonds were produced on a glass substrate. A focused 632.8 nm He-Ne laser irradiation is shown to cause an emission of light in the green region of the optical spectrum accompanied with laser-induced blackening of the obtained films. Possible mechanisms of the observed phenomenon are discussed.
关键词： optical spectrum,laser modification,nanodiamonds,sp2-carbon,sp3-carbon,high-pressure high-temperature
更新于2025-09-12 10:27:22