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Multi-mode photocatalytic performances of CdS QDs modified CdIn2S4/CdWO4 nanocomposites with high electron transfer ability
摘要： In general, quantum dots have the property of generating a plurality of charge carriers using hot electrons or using a single high-energy photon to improve the photocatalytic properties of the material. In this paper, CdS QDs@CdIn2S4/CdWO4 modified by CdS QDs was synthesized by the microwave-assisted hydrothermal method, and its composition, crystal structure, morphology, and surface physicochemical properties were well characterized. Electron microscopy results showed that CdS QDs@CdIn2S4/CdWO4 composite material exhibited a sheet structure with a length of ca. 350 nm and a width of ca. 50 nm, and CdS QDs uniformly distributes with a diameter of about 5 nm on the sheet structure. UV-visible diffuse reflectance tests showed that the combination of CdS QDs and CdIn2S4 can extend the light absorption range of CdWO4 to the visible region. Photoluminescence spectroscopy confirmed that CdS QDs had efficient electron transport capabilities. The multi-mode photocatalytic activity of CdS QDs@CdIn2S4/CdWO4 showed an excellent ability to degrade organic pollutants. Under the conditions of no co-catalyst and Na2S-Na2SO3 as the sacrificial agent, the hydrogen production of CdS QDs@CdIn2S4/CdWO4 can reach 221.3 μmol g?1 when exposed to visible light (λ > 420 nm) for 8 h.
关键词： CdS QDs,Quantum dots,Microwave-assisted hydrothermal method,CdWO4,Multimode photocatalysis,H2 evolution,CdIn2S4
更新于2025-09-10 09:29:36
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Synthesis of TiO <sub/>2</sub> (B) and High-temperature Stable Anatase TiO <sub/>2</sub> Nanowires by Hydrothermal Method and Investigation of Photocatalytic Activity
摘要： In this study, TiO2 nanowires (TNWs) were synthesized through hydrothermal method and were characterized using X-Ray diffraction (XRD), transmission electron microscopy (TEM) and BET techniques. Monoclinic TiO2 (B) is the dominant phase of TNWs up to 600 ℃ which is completely transformed into a highly crystalline anatase phase at 800 ℃. The photocatalytic activity of TNWs, prepared at various calcination temperatures, was investigated in the removal of Rhodamine B (RhB) as an organic model pollutant. The results indicated that the photocatalytic activity of TNWs, prepared at 800 ℃ calcination temperature (TNWs-800), was better than that of other samples and even TiO2-P25 nanoparticles.
关键词： Anatase TiO2 nanowires,Photocatalytic activity,TiO2 (B),Hydrothermal method,High-temperature
更新于2025-09-10 09:29:36
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The preparation and photocatalytic performance research of CdSe and wool ball-like GO/CdSe microspheres
摘要： Different morphologies of CdSe and GO (graphene oxide)/CdSe microspheres like wool ball and walnut shape have been made through hydrothermal method using CTAB as surfactant. X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), X-ray energy dispersive spectrometer (EDS), scanning electron microscope (SEM), Raman spectra, and UVevis absorption spectrum, were used to intensively investigate the structures, morphologies, chemical compositions and optical properties of CdSe and GO/CdSe microspheres. The results of XRD revealed that GO/CdSe microspheres have lead-zinc mineral structure. The results of XRD, EDS, XPS and Raman spectra showed that GO/CdSe microspheres were grown on GO sheets. Also UVevis absorption spectrum indicated that GO/CdSe microspheres enhanced absorbance in UV light region and visible light region. Through comparative experiments, the results showed that pH ? 4 is the optimal pH value for degrading Rhodamine B (RhB) solution. To study the photocatalytic performance of GO/CdSe microspheres, we catalyzed the degradation of RhB aqueous solution irradiated by visible light. The photocatalytic results showed that the wool ball-like GO/CdSe microspheres exhibited better photocatalytic activity than rough CdSe.
关键词： GO/CdSe microspheres,Hydrothermal method,Morphologies,GO,Photocatalytic activity
更新于2025-09-10 09:29:36
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One-step hydrothermal synthesis of carbon dots-polymer composites with solid-state photoluminescence
摘要： Carbon dots (CDs) and CDs-polymer composites were one-step synthesized in a hydrothermal process using hexamethylenetetramine and polycarbonate as precursors. Their optical properties and the application as solid-state phosphors towards white light-emitting diodes (LEDs) were thoroughly investigated. CDs solutions exhibit strong yellow emission under blue illumination and possess excitation-independent luminescent behavior. Owing to precursor polymerization, CDs-polymer composites were synthesized in one step. The dried CDs-polymer composite powders exhibit excellent optical stability and no luminescence quenching was observed. Under light blue illumination, the powders show broad yellow luminescence with the peak wavelength centered at 550 nm and PL quantum yield of 14.86%. For their practical applications, stable white light emission was demonstrated by coating a 455nm blue LED with the powders. Our research offers a valuable reference for growing CDs-polymer composites in a facile, low-cost and low-temperature hydrothermal process and developing white LEDs with light blue LEDs and metal-free phosphors.
关键词： white light-emitting diodes (LEDs),phosphors,solid-state photoluminescence,hydrothermal method,carbon materials,luminescence
更新于2025-09-10 09:29:36
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ZnO nanospheres based simple hydrothermal route for photocatalytic degradation of azo dye
摘要： This novel work presents a promising application to use Zinc oxide nanospheres as nanocatalysts in photocatalytic degradation of methyl orange dye. The hydrothermal route was utilized in the synthesis process of ZnO nanospheres. The size of the synthesized ZnO nanoparticles is around 200-250 nm diameter. The synthesized nano-oxides were characterized utilizing several instruments such as X-ray diffraction, Brunauer, Emmett, and Teller (BET), and scanning electron microscope (SEM). The resulting nanoparticles are utilized as an efficient tool for degradation of methyl orange (MO) dye under UV radiation. Essential parameters were studied on degradation process involving the initial concentration of MO, pH, stirring the solution, dose of the ZnO nanospheres, the oxygen content of the solution, calcination of the nanomaterials. All activity experiments under UV radiation provide excellent results for the degradation process of MO. Also, the recovery of ZnO nanomaterials was investigated based on the photocatalytic process efficiency. The results show the high possibility of reuse ZnO nanospheres for several photocatalytic processes. Also, the nanocatalysts were applied for a real environmental sample with providing high photocatalytic performance.
关键词： methyl orange,ZnO nanospheres,photocatalytic degradation,hydrothermal method,azo dyes
更新于2025-09-10 09:29:36
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Enhanced visible-light-driven photocatalytic activity of F doped reduced graphene oxide - Bi <sub/>2</sub> WO <sub/>6</sub> photocatalyst
摘要： The reduced graphene oxide‐Bi2WO6 (rGO‐BWO) photocatalysts with the different RF/O values (molar ratio of the F molar mass and the O's molar mass of Bi2WO6) had been successfully synthesized via one‐step hydrothermal method. The F‐doped rGO‐BWO samples were characterized by X‐ray diffraction patterns (XRD), field‐emission scanning electron microscopy (FE‐ESEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller surface area (BET), X‐ray photoelectron spectroscopy (XPS) and UV–vis diffuse reflectance spectra (DRS). The results indicate that F ions had been successfully doped into rGO‐BWO samples. With the increasing of the RF/O values from 0 to 2%, the evident change of the morphology and the absorption edges of F‐doped rGO‐BWO samples and the photocatalytic activities had been enhanced. Moreover, the photocatalytic activity of F‐doped rGO‐BWO with RF/O = 0.05 were better than rGO‐BWO and the other F‐doped rGO‐BWO under 500 W Xe lamp light irradiation. The enhanced photocatalytic activity can be attributed to the morphology of the intact microsphere that signify the bigger specific surface area for providing more possible reaction sites for the adsorption–desorption equilibrium of photocatalytic reaction, the introduction of F ions that may cause the enhancement of surface acidity and creation of oxygen vacancies under visible light irradiation, the narrower band gap which means needing less energy for the electron hole pair transition.
关键词： photocatalytic activity,rGO‐Bi2WO6,fluorine doping,hydrothermal method
更新于2025-09-10 09:29:36
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Highly efficient ethanol gas sensor based on hierarchical SnO2/Zn2SnO4 porous spheres
摘要： In this work, hierarchucal porous SnO2/Zn2SnO4 nanospheres were succesfully prepared via a facile one-step hydrothermal method with subsequent calcination process. Scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were employed in order to investigate the structural and morphological properties of the as-prepared composites. The results showed that the SnO2/Zn2SnO4 composites were cpmposed of many porous nanospheres with a uniform diameter of about 500 nm. Moreover, the as-prepared products were used as sensing material for the fabrication of gas sensor. The sensing performance of the sensor was systematically evaluated, and the sensor exhibited excellent ethanol-sensing property. The optimum operating temperature was 250 oC with a reponse of 30.5 toward 100 ppm ethanol. Also, the sensor showed good selectivity, stability and a low detection limit of 0.5 ppm (response 1.4). The good sensing performance of SnO2/Zn2SnO4 nanospheres can be attibuted to the porous structure as well as the heterojunction formed between SnO2 and ZnSn2O4.
关键词： SnO2/Zn2SnO4,Porous sphere,Hydrothermal method,Ethanol,Gas sensor
更新于2025-09-09 09:28:46
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Photoactivity of Ag/TiO2 Microsphere by One-Step Hydrothermal Method
摘要： Ag/TiO2 microsphere photocatalyst was prepared via one step hydrothermal method and prepared catalyst was used for photodegradation of rhodamine B under visible light. The Ag/TiO2 catalyst was characterized through X-ray diffraction (XRD) and scanning electron microscope (SEM). The results showed Ag was uniformly distributed in the titanium matrix. The 6 % Ag doped TiO2 catalyst had the higher photoactivity than other proportion to degrade rhodamine B 86.6 % within 60 min under visible light. The Ag doped TiO2 also had the good activity under solar light cut off UV light.
关键词： Ag doped TiO2,Photodegradation,Hydrothermal method,Microsphere
更新于2025-09-09 09:28:46
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Effects of Hydrothermal Treatment Duration on Morphology of WO <sub/>3</sub> Nanostructures
摘要： Tungsten trioxide (WO3) nanostructures have been synthesized by a simple wet chemical hydrothermal method at a temperature of 120 °C using sodium tungstate (Na2WO4 · 2H2O) as precursor material. In order to study the growth mechanism of WO3 nanostructures, the time of hydrothermal treatment was varied between 1 and 48 h. The morphology and structure of the synthesized WO3 samples were characterized by scanning electron microscopy and X-ray diffraction techniques. The duration of hydrothermal treatment significantly affected the nanostructure morphology evolution due to the limited concentration of a directional capping NaCl agent during synthesis of WO3 crystals.
关键词： Nanorod,Hydrothermal Method,Tungsten Oxide
更新于2025-09-09 09:28:46
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A Novel Study: The Effect of Graphene Oxide on the Morphology, Crystal Structure, Optical and Electrical Properties of Lanthanum Ferrite Based Nano Electroceramics Synthesized by Hydrothermal Method
摘要： Lanthanum Ferrite based nanocomposites were prepared with various Graphene oxide contents by the hydrothermal method. The crystalline structure, morphological properties, electrical and optical properties of samples were investigated. X-ray diffraction results indicate that all the nano electroceramics are polycrystalline with an Orthorhombic structure. Results from scanning and transmission electron microscopes indicate that the Bismuth ferrite/Graphene oxide powders have nanostructure. The optical band gaps of the nano electroceramics were calculated for the various amount of Graphene oxide. The electrical properties of samples were investigated with the temperature depend on conductivity measurements. The measurement shows that the electrical conductivity changes with increasing temperature and graphene oxide dopants of all samples. Activation energy values of the nanocomposites decrease with increasing graphene oxide content. The dielectric properties of Lanthanum Ferrite/Graphene Oxide nanocomposites (real and imaginer) with respect to frequency variation (1 KHz–5 MHz) were measured at room temperature. The relative permittivity, dielectric loss and alternating current conductivity values of the samples were estimated. It is show that relative permittivity, dielectric loss and alternating current conductivity increase with increasing frequency. The polarization-electric field hysteresis loop of all Lanthanum Ferrite/Graphene Oxide nano electroceramics was measured at the room temperature. The loop shows proper saturation with enhanced saturation polarization and coercive electric field. The obtained findings suggest that the physical and electrical properties of Lanthanum Ferrite/Graphene Oxide nano electroceramics can be changed by Graphene Oxide doping. These materials can be used for a variety of technological applications in the field of dielectric and ferroelectric.
关键词： Dielectric Properties,Graphene Oxide,Lanthanum Ferrite,Ferroelectric,Hydrothermal Method
更新于2025-09-09 09:28:46