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Investigation of arc dynamics during vacuum arc remelting of a Ti64 alloy using a photodiode based instrumentation
摘要： Understanding the arc dynamics during VAR is important for controlling the final quality of the ingot, as the spatial and temporal distribution of the arc dictates the electric current and energy inputs at the ingot top, which in turn affect the hydrodynamics of the metal in the molten pool and the solidification conditions of the ingot. The arc dynamics during vacuum arc remelting was quantitatively investigated based on the analysis of the light emitted by the arc and reflected by the molten pool using photodiodes placed inside a full-scale furnace. The measurements allowed us to determine the location of the arc luminosity centroid and to follow its displacement as a function of time. They were made during the melt of a Ti64 alloy with an imposed alternated electromagnetic stirring of high intensity. The arc dynamics was found to be most of the time periodic, asymmetrical, and strongly correlated to the evolution of the stirring magnetic field. The arc centroid exhibited three regular displacement patterns throughout the melt. A common characteristic to all three patterns was the relative stability of the centroid during stirring plateaus and its rapid motion during stirring ramps. An evolution towards a much more centered distribution of the centroid was observed with the arc power decrease during the hot-topping phase. Possible implications of the observed arc dynamics on the final quality of the VAR ingot are discussed.
关键词： Electric arc,Photodiodes,Titanium alloy,Vacuum arc remelting,Dynamics
更新于2025-09-23 15:21:21
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Effects of TiC on the microstructure and properties of TiC/TiAl composite coating prepared by laser cladding
摘要： In order to study the effect of TiC on the microstructure and properties of cladding coatings, TiC/TiAl composite coatings have been prepared by using a laser cladding technique on TiAl alloy, and the microstructure and properties of the resulting composite coatings have been investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), micro-hardness testing, X-ray stress measurements, friction and wear testing, and an electrochemical workstation. The results showed that when the particle size of TiC is up to micron, the growth of TiC is more developed, the dendrite growth direction is disordered, and the cladding quality is poor. When the particle size of TiC is nanoscale, the morphology of the reinforcement phase TiC is mainly granular and thin rods, which is uniform in the coating and the direction of growth is regular. When the concentration of TiC reaches 20%, the microstructure of the cladding layer grows well and is dense. The microhardness and wear resistance of the coatings prepared by adding nano TiC are better than those of the coatings prepared by micron TiC. When the content of nano TiC in the coatings increases from 10% to 20%, the microhardness and wear resistance of the coatings are obviously improved. The residual stress of the coating is positively related to the crack rate. The residual stress in the coating is tensile stress, and the crack type is the crystal crack in the hot crack. When the particle size of TiC is small and the concentration is high, the coating shows better corrosion resistance.
关键词： TiAl alloy,TiC/TiAl composite coating,Laser cladding,Properties,Microstructure
更新于2025-09-23 15:21:21
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Investigation into the Effect of Increasing Target Temperature and the Size of Cavity Confinements on Laser-Induced Plasmas
摘要： In this work, the effect of the sample temperature on the magnesium (Mg) and titanium (Ti) plasmas generated by a Q-switched Neodymium-doped Yttrium Aluminum Garnet (Nd:YAG) laser operating at its fundamental wavelength of 1064 nm has been investigated. We observed that increasing the sample temperature significantly enhanced the emission intensities of the plasmas. Comparing the emission peak intensities of the case of 100°C to the case of 300°C, we recorded a substantial enhancement of the peak intensities of the latter compared to the former. From these results it can be observed that increasing the sample temperature has a significant effect on the emission intensities of the plasmas. We also studied the plasma dynamics and found that increasing the sample temperature also decreases the air density around the Mg sample surface. The reduction in the air density resulted in a decrease in the radiation process and lowers collision probability. Furthermore, as the plasma expands, the plasma pressure also decreases. In addition, we also employed circular and square cavities to confine the titanium plasma, and investigated the effect of the sizes of the circular and square cavities on the titanium plasma. We observed a general improvement in the emission intensities with both the circular and square cavities and attributed this improvement to the plasma compression effect of the shock waves produced by the plasma within the cavities.
关键词： electron temperature,LIBS,Mg-alloy,electron density,cavity confinement,Ti-alloy
更新于2025-09-23 15:21:01
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Plasmonic performance of Au <sub/>x</sub> Ag <sub/>y</sub> Cu <sub/>1a??xa??y</sub> alloys from many-body perturbation theory
摘要： We present a detailed appraisal of the optical and plasmonic properties of ordered alloys of the form AuxAgyCu1-x-y, as predicted by means of first-principles many-body perturbation theory augmented by a semi-empirical Drude–Lorentz model. In benchmark simulations on elemental Au, Ag, and Cu, we find that the random-phase approximation (RPA) fails to accurately describe inter-band transitions when it is built upon semi-local approximate Kohn–Sham density-functional theory band-structures. We show that non-local electronic exchange-correlation interactions sufficient to correct this, particularly for the fully-filled, relatively narrow d-bands which contribute strongly throughout the low-energy spectral range (0–6 eV), may be modeled very expediently using band-stretching operators that imitate the effect of a perturbative G0W0 self-energy correction incorporating quasiparticle (QP) mass renormalization. We thereby establish a convenient work-flow for carrying out approximated G0W0 + RPA spectroscopic calculations on alloys and, in particular here, we have considered alloy concentrations down to 12.5% in AuxAgyCu1-x-y, including all possible crystallographic orderings of face-centred cubic type. We develop a pragmatic procedure for calculating the Drude plasmon frequency from first principles, including self-energy effects, as well as a semi-empirical scheme for interpolating the plasmon inverse lifetimes between stoichiometries. A distinctive M-shaped profile is observed in both quantities for binary alloys, in qualitative agreement with previous experimental findings. A range of optical and plasmonic figures of merit are discussed, and plotted for ordered AuxAgyCu1-x-y at three representative solid-state laser wavelengths. On this basis, we predict that certain compositions may offer improved performance over elemental Au for particular application types. We predict that while the loss functions for both bulk and surface plasmons are typically diminished in strength through binary alloying, certain stoichiometric ratios may exhibit higher-quality (longer-lived) localized surface-plasmons and surface-plasmon polaritons, at technologically-relevant wavelengths, than those in elemental Au.
关键词： alloy design for plasmonics,theoretical spectroscopy,many-body perturbation theory
更新于2025-09-23 15:21:01
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Effect of laser shock processing on oxidation resistance of laser additive manufactured Ti6Al4V titanium alloy
摘要： The high-temperature oxidation resistance of laser additive manufactured (LAM) Ti6Al4V before and after laser shock processing (LSP) was investigated. The samples were oxidized at 400?800 °C for 1?50 h in air. The results revealed that the rate of weight gain of the Ti6Al4V fabricated through LAM decreased, and LSP had a positive effect on increasing the oxidation resistance. At an oxidation temperature of 700 °C, an aluminum-rich layer was observed in the cross-section before LSP. After LSP, the aluminum-rich layer changed to three layers. The aluminum-rich layer prevented the diffusion of oxygen, which improved the oxidation resistance of the Ti6Al4V.
关键词： Ti6Al4V titanium alloy,High-temperature oxidation resistance,Laser shock processing,Laser additive manufacturing
更新于2025-09-23 15:21:01
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Microstructure and properties of CeO2-doped CoCrFeMnNi high entropy alloy fabricated by laser metal deposition
摘要： Rare earth elements are usually regarded as e?cient additives for property enhancement of many types of alloys. In the present study, the CoCrFeMnNi high entropy alloy (HEA) was doped with CeO2, and such composites were for the ?rst time obtained by the laser metal deposition (LMD) process. The microstructure, phase compositions, microhardness and crystallographic texture of the HEA/CeO2 composites were investigated. It was demonstrated that CoCrFeMnNi HEA/CeO2 samples were successfully obtained by the LMD process. Meanwhile, small irregular shape oxides rich in Mn and Cr were observed in the HEA/ CeO2 composite. Rare earth element Ce was found to be evenly distributed throughout the sample. Heterogeneous dendritic microstructure with a long columnar grains oriented along the build direction was observed. The measured average microhardness is 181.72 ± 9.72 HV0.1.
关键词： Composite,CeO2,High entropy alloy,Laser metal deposition,Additive manufacturing,CoCrFeMnNi
更新于2025-09-23 15:21:01
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Study on the intelligent model database modeling the laser welding for aerospace aluminum alloy
摘要： With the purpose of improving the modeling e?ciency, the model database is established targeting that in-telligent modeling of laser welding for aerospace aluminum alloy. The model database consists of material database, heat source model database and weld joint structure database. The aerospace aluminum alloys are classi?ed reasonably in order to establish the material model database which can manage the thermo-physical properties of aluminum alloys. The heat source models of laser welding are summarized to establish model database on the basis of the di?erent energy distribution characteristics. The joint structure database includes butt joint, T-joint and lap joint. Modeling of arbitrary structures can be implemented quickly and e?ciently when modelers invoke and assemble this model database. The ?nite element model is e?ciently established and accurately solved by taking the 5A90 and 2219 aluminum alloy laser welding as an example. Finally, it is found that the model database established in this paper can greatly improve the modeling e?ciency of laser welding numerical simulation.
关键词： Laser welding,Model database,Aluminum alloy,Structural model,Heat source model,Material model
更新于2025-09-23 15:21:01
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Comparative Study on Microstructure and Aluminum Distribution Between Laser Beam Welding and Electron Beam Welding of Tia??6Ala??4V Alloy Plates
摘要： Ti–6Al–4V alloy plates with a thickness of 4 mm were joined by electron beam welding (EBW) and laser beam welding (LBW). The comparison of LBW and EBW was performed according to grain morphology, microstructure, aluminum distribution, and microhardness of the joints. Results indicate that compared with LBW joint, more equiaxed grains are observed around the central zone of the EBW joint. The microstructure in fusion zone (FZ) of EBW joint presents more uneven with obviously coarser acicular martensite α′. Moreover, the aluminum element content of EBW joint is substantially lower, which demonstrates a more significant burning loss behavior in EBW process. The lower aluminum content in the upper center areas of the joints is attributed to the more significant element burning loss caused by higher temperature, whereas more uniform aluminum distribution in the upper part of the joints is ascribed to stronger convection form within the upper part of the joint. In addition, the characteristics of convection and thermal field within the molten pool are recognized as vital factors influencing the aluminum distribution. The lower microhardness profile in FZ of the EBW joint is principally attributed to coarser acicular martensite α′ and lower aluminum element in EBW joint.
关键词： Electron beam welding,Microhardness,Microstructure,Burning loss,Titanium alloy,Laser beam welding
更新于2025-09-23 15:21:01
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Influence of magnetic field orientation on laser-induced magnetization precession in Ni-Mn-Sn Heusler alloy film
摘要： Laser-induced magnetization precession is investigated in Ni-Mn-Sn Heulser alloy film using pump-probe all-optical technique. The studies are performed as a function of external magnetic field H applied at various angles with respect to the sample normal. Strong dependence of precession parameters, frequency f, amplitude A and effective damping, two precession modes, identified as Damon-Eshbach (DE) and first-order standing spin wave (PSSW) modes were observed. The values of wave vector for DE mode have been determined. The experimentally obtained exponentially decayed. The dependencies of the magnetization precession parameters have been well simulated in the frame of phenomenological approach, based on Landau-Lifshitz-Gilbert equation.
关键词： standing spin wave mode,pump-probe all-optical technique,Landau-Lifshitz-Gilbert equation,Ni-Mn-Sn Heusler alloy,Damon-Eshbach mode,Laser-induced magnetization precession
更新于2025-09-23 15:21:01
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Analysis of alloy and solar cells with double-pulse calibration-free laser-induced breakdown spectroscopy
摘要： We applied variant of calibration free laser induced Breakdown Spectroscopy (CF-LIBS) approach for the compositional analysis of standard Gd/Ge/Si alloy and solar cells. The double pulse laser induced plasma was produced on the sample surface and the emission spectra were recorded at optimized interpulse delay and energy ratio. The Plasma temperature, determined using Boltzmann plot, was used to determine the concentration of all species present in a sample. The results are compared with reference values as well as conventional CF-LIBS results, which show that conventional and variant CF-LIBS results are similar and in close agreement to reference values. It is worth mention that the variant CF-LIBS results, but the approach is simpler and faster. Therefore, this approach was applied to three unknown polycrystalline silicon solar cells, which yield Al, C, Ca, Fe, In, Ti, Sb and Sn in the parts per million (ppm). This approach can potentially be applied for real-time trace monitoring in manufacturing processes of photovoltaic devices where conversion e?ciency depends strongly on impurities’ concentration.
关键词： Alloy and solar cells,Double pulse LIBS,Laser induced plasmas,Quantitative elemental analysis,Calibration free LIBS,Plasma parameters
更新于2025-09-23 15:21:01