- 标题
- 摘要
- 关键词
- 实验方案
- 产品
过滤筛选
- 2019
- 2018
- IoT
- Organic photovoltaic
- Sensors
- UHF RFID Tags
- Energy Harvesting
- organic light emitting diodes
- conjugated polymer
- polarized emission
- chiral dopant
- Circular polarization
- Optoelectronic Information Science and Engineering
- Optoelectronic Information Materials and Devices
- Hanyang University
- Univ. Grenoble Alpes, Grenoble INP
- Dracula Technologies
-
AIEgen Nanoparticles of Arylamino Fumaronitrile Derivative with High Near-infrared emission for Two-photon Imaging and in vivo Cell Tracking
摘要： Developing of two-photon materials for live-cell imaging and in vivo analysis in-deep have been received great attention, and it is still urgent so that such microscopy technique could be promoted and advanced into new progress using the powerful probs. Herein, a new arylamino fumaronitrile derivative NPAPF was synthesized and transferred as aggregation-induced emission luminogen (AIEgen) fluorescent nanoparticles (AF-NPs) via assembly technique. This AF-NPs exhibited two-photon absorption cross-section at 2.6×106 GM with 19.5% of fluorescence quantum yield. Moreover, utilizing the great potential of AF-NPs, two-photon imaging of live cells with good cytocompatibility is realized upon two-photon microscopy. By in vivo long-term tracing studies of mesenchymal stem cells, we demonstrated the tremendous advantage of AF-NPs tracer in monitoring the stem cells transplant. Therefore, our unique AF-NPs provided an efficient two-photon-absorbing probe for investigating biological mechanism and behavior, and also opened a new avenue for spatiotemporal visualization of transplanted stem cells.
关键词： organic nanoparticles,aggregation-induced emission,two-photon,in vivo imaging,mesenchymal stem cell
更新于2025-09-04 15:30:14
-
Pd/TiO2 @ Carbon Microspheres Derived from Chitin for Highly Efficient Photocatalytic Degradation of Volatile Organic Compounds
摘要： Facing the serious air pollution caused by the volatile organic compounds (VOCs), the highly efficient degradation and removal of VOCs have attracted great attentions. To develop efficient novel photocatalysts, Pd/TiO2 @ carbon nanofibrous microspheres were constructed by carbonizing the TiO2/chitin microspheres, followed by immobilizing Pd nanoparticles on the TiO2/carbon microspheres via a green pathway. The composite microspheres were composed of carbon nanofibers, on which TiO2 nanoparticles and ultra-small Pd nanoparticles with mean size of 1 nm were well immobilized and distributed, supported by transmission electron microscope and elemental mappings results. The Pd/TiO2 @ carbon microspheres were used for the gas phase photodegradation of VOCs. The results demonstrated that the conversion of toluene and benzene to CO2 and H2O reached 96.4% and 91.7%, respectively, which were higher than the reported values in the literatures. The combination of TiO2 and Pd nanoparticles played an important role on the enhancement of the catalytic activity. Moreover, the Pd/TiO2 @ carbon microspheres could be recycled and reused. This work provided a new strategy to eliminate VOCs, which was beneficial to a sustainable world.
关键词： catalyst TiO2 nanoparticles,Chitin microsphere,Pd nanoparticles,degradation of volatile organic compounds,carbon nanofibers
更新于2025-09-04 15:30:14
-
[ACS Symposium Series] Raman Spectroscopy in the Undergraduate Curriculum Volume 1305 || Connecting Organic and Physical Chemistry Students with Raman Spectroscopy
摘要： The profile of Raman spectroscopy may be elevated in the undergraduate chemistry curriculum by intentionally tying together students’ experiences in the organic and physical chemistry laboratories. In this way the valuable role Raman spectroscopy can play in structure elucidation is highlighted. The Committee on Professional Training of the American Chemical Society includes the category of optical molecular spectroscopy (e.g., IR, UV-Vis, Raman, and fluorescence spectroscopies) as an option in the panel of instruments required for certification. To the authors’ knowledge there are no Raman spectroscopy experiments that build directly on the analysis of compounds synthesized by students in a prior course for the intended purpose of scaffolding the curriculum. This chapter highlights the roles Raman spectroscopy may play in the determination of molecular structure when used in conjunction with other, more common techniques. Indeed, direct comparison to infrared spectroscopy holds the potential to reinforce that technique and its applications while introducing the study of Raman spectra. A set of three reaction products from electrophilic aromatic substitution, Diels-Alder, and aldol condensation (this including site-specific deuteration) is explored. All of these reactions are currently part of the organic chemistry curriculum. By combining analyses performed in organic chemistry with new laboratories written for the physical chemistry laboratory the authors hope to impress upon undergraduates the value of Raman spectroscopy in a context that builds on their previous experiences with other molecular spectroscopy methods.
关键词： structure elucidation,undergraduate chemistry curriculum,electrophilic aromatic substitution,Diels-Alder reaction,Raman spectroscopy,infrared spectroscopy,deuteration,physical chemistry,aldol condensation,organic chemistry
更新于2025-09-04 15:30:14
-
Comprehensive Membrane Science and Engineering || 3.5 Photocatalytic Processes in Membrane Reactors
摘要： Photocatalytic membrane reactors (PMRs) represent an interesting alternative technology useful both in the field of water and air purification and in organic syntheses. The necessity to develop chemical products and industrial processes that reduce or eliminate the use and the generation of toxic substances along with the risk for human health and for environment constitutes the aim of the research efforts based on the principles of green chemistry.
关键词： air purification,green chemistry,Photocatalytic membrane reactors,water purification,organic syntheses
更新于2025-09-04 15:30:14
-
The structure of PA-Se-S-Cd composite materials probed with FTIR spectroscopy
摘要： Composite organic-inorganic functional materials are of significant importance in various applications of science and technology. In this work, PA-Se-S and PA-Se-S-Cd composite materials obtained by employing the sorption-diffusion method are discussed. A single precursor – K2SeS2O6 – was used as the source of both sulfur and selenium. In the aqueous solution, SeS2O6 2? and its decomposition products diffused into the polymer where they reacted with Cd2+ ions so that to form cadmium chalcogenide particles. Fourier-transform infrared (FTIR) spectroscopy was used to characterize the interactions between polyamide 6 and inorganic constituents, namely, K2SeS2O6, CdS and CdSe. The spectral behavior of amide I, II, A and B bands evidenced the competing formation of complex bonding structures based on the formation of covalent, electrostatic and hydrogen bonding between the PA 6 amide (NHCO) groups and the inorganic constituents. The number and the type of the formed bonds depend on the polyamide 6 exposure time in the K2SeS2O6 precursor solution. Such a complex interaction induces obvious conformational changes of the polyamide 6 chains. A possible bonding mechanism has been proposed to explain the observed spectral phenomena.
关键词： Inorganic-organic hybrid materials,Cadmium chalcogenides,Polyamide 6,Infrared spectra,Potassium selenotrithionate
更新于2025-09-04 15:30:14
-
AIP Conference Proceedings [Author(s) SolarPACES 2017: International Conference on Concentrating Solar Power and Chemical Energy Systems - Santiago, Chile (26–29 September 2017)] - MicroSol-R: Versatile solar facility for research and industry
摘要： Since February 2016, a new CSP micro-power plant called “MicroSol-R” is in operation at PROMES-CNRS. This platform aims at developing research and innovation in the field of heat transfer fluids, thermal energy storage, solar thermal power conversion at small scale, power plant operation strategy, etc. In addition, it was designed to be a useful tool for training. MicroSol-R is a versatile facility open to collaboration with industry and laboratories. This paper presents the facility and first results after one year of operation. The performances and characteristics of the solar field, the thermocline heat storage and the organic Rankine cycle are presented.
关键词： CSP,thermal energy storage,solar thermal power,heat transfer fluids,organic Rankine cycle,MicroSol-R
更新于2025-09-04 15:30:14
-
An unusual dependency on the hole-scavengers in photocatalytic reductions mediated by a titanium-based metal-organic framework
摘要： The reductive reactions driven by photo-generated electrons on photocatalysts were generally considered to be irrelevant to the employed hole-scavengers. Herein, we report an unexpected dependence of photocatalytic debromination of decabromodiphenyl ether (BDE 209) on the hole-scavengers catalyzed by amine-functionalized MIL-125(Ti). It was found that the debromination only occurred when triethanolamine, rather than the conventional alcohols, was used as the hole-scavenger. Further low-temperature ESR experiments indicate that triethanolamine participates in the formation of the active catalytic Ti (Ⅲ) species, which shuttle the electron to BDE 209, producing reductive debromination products.
关键词： Photocatalysis,Hole-scavengers,BDE 209,Metal-organic frameworks
更新于2025-09-04 15:30:14
-
Effects of n-butyl amine incorporation on the performance of perovskite light emitting diodes
摘要： The efficiency of perovskite light emitting diodes (PeLEDs) is crucially limited by leakage current and nonradiative recombination. Here we introduce n-butyl amine (BA) to modulate the growth of perovskite films as well as improve the performance of PeLEDs, and investigate in details the effects of BA incorporation on the structural, optical, and electrical characteristics of perovskite films. The results indicate that BA would terminate the grain surface and inhibit crystal growth, leading to increased radiative recombination. However, BA overload would make the films loose and recreate shunt paths. The electrical detriment of BA overload outweighs its optical benefit. As a result, optimal PeLEDs can be obtained only with moderate BA incorporation.
关键词： optical and electrical characteristics,butyl amine,crystal growth,bulky organic cations,perovskite light emitting diodes
更新于2025-09-04 15:30:14
-
Tuning effective hyperfine fields in PEDOT:PSS thin films by doping
摘要： Using electrically detected magnetic resonance spectroscopy, we demonstrate that doping the conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) with ethylene glycol allows for the control of effective local charge carrier hyperfine fields through motional narrowing. These results suggest that doping of organic semiconductors could enable the tuning of macroscopic material properties dependent on hyperfine fields such as magnetoresistance, magneto-optical responses, and spin diffusion.
关键词： organic semiconductors,spin diffusion,motional narrowing,hyperfine fields,PEDOT:PSS
更新于2025-09-04 15:30:14
-
Synthesis and investigation of charge transport properties in adducts of hole transporting carbazole derivatives and push-pull azobenzenes
摘要： In order to investigate the viability of a material design for bulk heterojunction (BHJ) organic solar cells, where hole transporting group is bound to the donor moiety, we report the synthesis and charge transport characteristics of 3-(diphenylamino)carbazolyl- functionalized derivatives of 2-(4-((4-(dimethylamino)phenyl)diazenyl)benzylidene)-1H-indene-1,3-dione (DMAAzi) chromophore. Three different bounding configurations were examined in these adducts. Additionally, a trityl- functionalized derivative of DMAAzi was prepared and used for comparison purposes. All of the synthesized materials form thin amorphous films from volatile organic solvents and exhibit glass transition temperatures in the range from 89 °C to 124 °C. The molecular ionization energy and electron affinity energy levels in thin films were measured. Photo-induced time of flight (ToF) method was used in to determine charge carrier drift mobilities. It was found out that the formation of deep charge trap states with local energies at approximately 0.60 - 0.78 eV takes place and has a considerable negative effect on the hole drift mobility of the investigated compounds.
关键词： charge transport,molecular glasses,carbazole,organic photovoltaics,azobenzene dyes
更新于2025-09-04 15:30:14