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Template growth of Au/Ag nanocomposites on phosphorene for sensitive SERS detection of pesticides
摘要： We report template growth and dense packing of noble metallic nanoparticles on few-layer phosphorene for sensitive SERS detection. Phosphorene obtained by electrochemical exfoliation serves as both the template and reductant in the fabrication of noble metallic nanoparticles which are dispersed on phosphorene without aggregation or pile-up. The BP/Ag/Au and BP/Au/Ag nanocomposites with a nanogap structure exhibit excellent SERS sensitivity and reproducibility with respect to Rhodamine 6G (R6G). The BP/Au/Ag nanocomposite is further utilized as the SERS substrate for the detection of two fungicides, thiabendazole and thiram, and detection limits of 10-7 and 10-8 M are achieved. Template growth of Au/Ag nanocomposites is demonstrated to be a green strategy for the fabrication of SERS substrates and has large potential in applications such as pesticide detection.
关键词： template growth,nanocomposites,phosphorene,SERS
更新于2025-11-21 11:01:37
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Dielectric and Piezoelectric Properties of Textured Lead-Free Na0.5Bi0.5TiO3-Based Ceramics
摘要： This work provides a comparative study of the dielectric and piezoelectric properties of randomly oriented and textured 0.88Na0.5Bi0.5TiO3-0.08K0.5Bi0.5TiO3-0.04BaTiO3 (88NBT) ceramics. Textured ceramics were fabricated by template grain growth (TGG) method using NaNbO3 (NN) for templates. For textured ceramics with 4 wt% NN templates, a Lotgering factor of 96% and piezoelectric coe?cient d33 of 185 pC/N were obtained. Compared to the randomly oriented ceramics, textured ceramics show lower strain hysteresis (H = 7.6%), higher unipolar strain of 0.041% with corresponding large signal piezoelectric coe?cient d33* of 200 pm/V at applied ?eld of 2 kV/mm. This enhancement can be explained by the grain orientation along <001> direction by texturing, where an engineered domain con?guration is formed after polarization, leading to decreased hysteresis and increased piezoelectric property.
关键词： electrical conductivity,textured ceramics,template grain growth,piezoelectric materials
更新于2025-11-14 17:28:48
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Self-template construction of honeycomb-like mesoporous YPO4:Ln3+ (Ln?=?Eu, Tb) phosphors with tuneable luminescent properties
摘要： Rare earth (RE)-based phosphors with mesoporous structure that can improve the absorption and utilization of light have attracted much attention recently. Herein, we develop a novel and facile self-template strategy to synthesize honeycomb-like mesoporous YPO4:Ln3+ (Ln = Eu, Tb) phosphors using Y4O(OH)9NO3: Ln3+ as the precursor through a simple H3PO4 etching process. The maximum specific surface area of the mesoporous YPO4:Ln3+ phosphors can reach 406 m2 g?1. The influence of mesoporous structure, crystallinity, and the concentration of rare earth ions on the photoluminescence performance of mesoporous YPO4:Ln3+ phosphors was investigated. The results of fluorescence measurements indicate the mesoporous YPO4:Ln3+ phosphors exhibit better photoluminescence performance after calcination at 900 °C due to the large surface area and high crystallinity. The optimum doped concentrations of Eu3+ and Tb3+ ions are 0.12 and 0.08, respectively, and the concentration quenching occurs among nearest-neighbor ions. This work provide a new sight on preparation of phosphors for white light-emitting diodes lamps.
关键词： Mesostructure,Ultrahigh specific surface area,Temperature dependent luminescence,Self-template strategy
更新于2025-11-14 17:15:25
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A direct one-step synthesis of ultrathin g-C3N4 nanosheets from thiourea for boosting solar photocatalytic H2 evolution
摘要： Two-dimensional (2D) graphitic carbon nitride (g-C3N4) nanosheets, as the promising photocatalyst with fascinating properties, have become a 'rising star' in the field of photocatalysis. Although g-C3N4 nanosheets exfoliated from the bulk g-C3N4 powders are extensively emerged, developing a simple synthetic approach is still full of challenge. To this end, here we report a direct polymerization strategy to fabricate the ultrathin g-C3N4 nanosheets, that is only heating treatment of thiourea in air without addition of any template. The photocatalytic activities of as-prepared samples were evaluated by photoreduction of water to hydrogen (H2) using triethanolamine as sacrificial agent and Pt as co-catalyst under visible-light irradiation (λ > 420 nm). As a result, our few-layered g-C3N4 nanosheets with an average thickness of 3.5 nm exhibit a superior visible-light photocatalytic H2 evolution rate (HER) of 1391 μmol g?1 h?1 and a remarkable apparent quantum efficiency of 6.6% at 420 nm. Eventually, the HER of as-fabricated ultrathin g-C3N4 nanosheets is not only much higher than the dicyandiamide-derived g-C3N4 or melamine-derived g-C3N4, but also greater than the thermal-oxidation etched g-C3N4 nanosheets under the same condition.
关键词： g-C3N4 nanosheets,Template-free polymerization,Solar energy conversion,2D materials,Photocatalysis,One-step synthesis
更新于2025-11-14 17:03:37
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Synthesis of visible light responsive iodine-doped mesoporous TiO2 by using biological renewable lignin as template for degradation of toxic organic pollutants
摘要： The visible light responsive I-doped mesoporous TiO2 (I/TiO2-T) catalysts were synthesized by facile hydrolysis method with lignin as a template. The resulting I/TiO2-T catalysts synthesized from different amounts of I as a dopant and lignin as a template were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis diffuse spectroscopy (DRS), Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL), and electrochemical impedance spectroscopy (EIS). The photocatalytic activities of the resulting catalysts were investigated by the degradation of p-chlorophenol under artificial visible light irradiation. The results showed that the lignin-templated TiO2 with a suitable amount of I-doping (I/TiO2-T) had higher catalytic activity than the catalyst prepared form I-doped TiO2 without lignin template (I/TiO2). Complete degradation of p-chlorophenol was achieved by I/TiO2-T with suitable amount of I-doping at 60 min. However, 95.7, 10.7, and 5.5% of the p-chlorophenol was degraded with I/TiO2, TiO2-T, and P25 catalysts, respectively, under 140 min visible light irradiation. The enhanced catalytic activities of the samples with template and I-doping may be due to the small grain size and high specific surface area of the catalysts. The band gap and the electrical properties of TiO2 also could be adjusted with I-doping. The I-doped TiO2 with the extrinsic I5+-to-Ti4+ and the iodine-to-oxygen donor defects could be excited by visible irradiation for efficient pollutants degradation. A possible photocatalytic mechanism for the degradation of the pollutants with I/TiO2-T under visible light irradiation was also proposed.
关键词： Mesoporous TiO2,Visible light,I-doped,Lignin template
更新于2025-11-14 17:03:37
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A Facile Approach for Fabricating Microstructured Surface Based on Etched Template by Inkjet Printing Technology
摘要： Microstructures are playing an important role in manufacturing functional devices, due to their unique properties, such as wettability or ?exibility. Recently, various microstructured surfaces have been fabricated to realize functional applications. To achieve the applications, photolithography or printing technology is utilized to produce the microstructures. However, these methods require preparing templates or masks, which are usually complex and expensive. Herein, a facile approach for fabricating microstructured surfaces was studied based on etched template by inkjet printing technology. Precured polydimethylsiloxane substrate was etched by inkjet printing water-soluble polyacrylic acid solution. Then, the polydimethylsiloxane substrate was cured and rinsed, which could be directly used as template for fabricating microstructured surfaces. Surfaces with raised dots, lines, and squares, were facilely obtained using the etched templates by inkjet printing technology. Furthermore, controllable anisotropic wettability was exhibited on the raised line microstructured surface. This work provides a ?exible and scalable way to fabricate various microstructured surfaces. It would bring about excellent performance, which could ?nd numerous applications in optoelectronic devices, biological chips, microreactors, wearable products, and related ?elds.
关键词： inkjet printing,microstructured surface,anisotropic wettability,etched template
更新于2025-11-14 15:27:09
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Revealing the role of kapok fibre as bio-template for In-situ construction of C-doped g-C3N4@C, N co-doped TiO2 core-shell heterojunction photocatalyst and its photocatalytic hydrogen production performance
摘要： For the first time, C-doped g-C3N4@C, N co-doped TiO2 core-shell heterojunction photocatalyst was successfully prepared by an in-situ one-pot hydrothermal bio-template approach, assisted by calcination treatment at 500?°C. Kapok fibre was used as a bio-templates and in-situ C doping in g-C3N4 and TiO2 during the formation of core-shell heterojunction photocatalyst. Moreover, the used of urea as g-C3N4-precursor also contribute to band-gap narrowing by an in-situ carbon and nitrogen doping in TiO2. Various characterisation techniques were employed to understand the effect TiO2 precursor concentration on the evolution of core-shell nanostructure heterojunction photocatalyst that can affect and boost the catalytic activity. The detailed understanding of the concurrent growth of C-doped g-C3N4 (CCN) and C, N co-doped TiO2 mechanism, as well as the formation of core-shell nanostructures heterojunction formation, are also proposed in this study. Our finding indicated that the bio-template core-shell nanostructure heterojunction photocatalysts showed a dramatic increase in photoinduced electron-hole separation efficiency as demonstrated by the photoelectrochemical and photoluminescence analyses. The enhancement in photogenerated charge carrier separation and narrower band gap resulted in superior photocatalytic activities with the highest rate of hydrogen production was recorded by CCN/T-1.5 sample (625.5 μmol h-1 g-1) in methanol aqueous solution. The well-developed interconnected heterojunction formation with appropriate CCN and TiO2 contents in core-shell nanoarchitectures system is a prime factor for the future design of a highly efficient visible-light-driven photocatalyst.
关键词： Bio-template,Heterojunction photocatalyst,Core-shell,Co-doping,Photocatalytic hydrogen production,Visible light
更新于2025-09-23 15:23:52
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Photocatalytic hydrogen production by biomimetic indium sulfide using Mimosa pudica leaves as template
摘要： Biomimetic sulfur-deficient indium sulfide (In2.77S4) was synthesized by a template-assisted hydrothermal method using leaves of Mimosa pudica as a template for the first time. The effect of this template in modifying the morphology of the semiconductor particles was determined by physicochemical characterization, revealing an increase in surface area, decrease in microsphere size and pore size and an increase in pore volume density in samples synthesized with the template. X-ray photoelectron spectroscopy (XPS) analysis showed the presence of organic sulfur (S-O/S-C/S-H) and sulfur oxide species (eSO2, SO3^2-, SO4^2-) at the surface of the indium sulfide in samples synthesized with the template. Biomimetic indium sulfide also showed significant amounts of Fe introduced as a contaminant present on the Mimosa pudica leaves. The presence of these sulfur and iron species favors the photocatalytic activity for hydrogen production by their acting as a sacrificial reagent and promoting water oxidation on the surface of the templated particles, respectively. The photocatalytic hydrogen production rates over optimally-prepared biomimetic indium sulfide and indium sulfide synthesized without the organic template were 73 and 22 mmol g^-1 h^-1, respectively, indicating an improvement by a factor of three in the templated sample.
关键词： Photocatalytic hydrogen production,XPS analysis,In2.77S4,Template-assisted hydrothermal
更新于2025-09-23 15:23:52
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Performance Analysis of Flash LiDAR Based TRN Using Different Correlation Functions
摘要： This paper compares and analyzes a performance of template matching based terrain referenced navigation using correlation functions according to different error types and correlation functions. Conventional batch processing TRN generally utilizes the radar altimeter and adopts mean square difference, mean absolute difference, and normalized cross correlation for matching a batch profile with terrain database. If a flash LiDAR is utilized instead of the radar, it is possible to build a profile in one-shot. A point cloud of the flash LiDAR can be transformed into 2D profile, unlike a vector profile obtained from batch processing. Therefore, using the flash LiDAR we can apply new correlation functions such as image Euclidean distance and image normalized cross correlation which have been used in computer vision field. The simulation result shows that specific correlation functions are suitable for different types of errors.
关键词： Flash LiDAR,Template matching,TRN
更新于2025-09-23 15:23:52
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Synthesis and photocatalytic properties of biomimetic morphology silicon carbide
摘要： Silicon carbide materials with bionic morphology are prepared by impregnation-calcination method using the template of leaf vein. The microstructure, element composition, and band gap of biomimetic morphology silicon carbide are characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy(XPS). Photocatalytic property of biomimetic morphology silicon carbide has been measured by the dye decolorization reaction. The results demonstrate that calcination temperature has the important effect on the formation of silicon carbide. The morphology of silicon carbide can keep the original biomimetic shape of leaf vein template, and there is meosporous structure with a diameter of 2-4 nm on the interior of material. The average gain size of materials is about 16.9 nm and the specific surface area of materials is about 84.7 m2/g. After calculation, the band gap of material is 3.02 eV. For performance testing, the degradation rate of silicon carbide is 92.86% for the first time, and after the fourth repetition, the degradation rate decreased to 86.74%.
关键词： Biological Template,Silicon Carbide,Biomimetic Morphology,Photocatalytic Property
更新于2025-09-23 15:23:52