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3D structured laser engraves decorated with gold nanoparticle SERS chips for Paraquat herbicide detection in environments
摘要： Fabrication of SERS-active substrates is a thrust area of research in the field of SERS. Here, we report the fabrication of a new SERS-active substrate composed of Au nanostructures grown on aluminum sheets marked with laser lines (L-Mark SERS chips). The SERS activity of these SERS chips exploited with environmentally important herbicide, paraquat, and dye molecule of methylene blue. Density functional theory (DFT) calculation was performed to theoretically study the molecular structure and Raman vibrational modes of the paraquat. A detailed discussion has been devoted to uniformity, reproducibility, and practical utility of the fabricated substrates. Especially, great amount of discussion has been given to paraquat detection in soil extracts. The results emanate the ultra-sensitive detection of paraquat, uniform enhanced signals over the substrates, and high reproducibility. The report successfully demonstrated the detection of paraquat in drinking water, tap water, agri-water, environmental water, and soil extracts. Liquid chromatography-mass spectrometry (LC-MS) measurements were also performed to demonstrate the realiability of the SERS method. The L-Mark SERS chips based paraquat detection is simple, rapid, and sensitive. We propose that the present sensors hold the potential to be used in herbicide detection and monitoring in-the-field experiments.
关键词： Au nanostructures,SERS,DFT,L-Mark SERS chips,Paraquat,LC-MS
更新于2025-09-12 10:27:22
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Paper-based Versatile SERS Chip with Smartphone-based Raman Analyzer for Point of Care Application
摘要： With the advanced development of the miniaturized Raman spectroscopy, surface enhanced Raman spectroscopy (SERS) has extended its applications into the field of Point of Care Testing (POCT) and demonstrated its great significance in virtue non-invasive property and capability of fingerprint identification. In the SERS-based analysis and/or sensing system, the preparation of low cost, high-performance SERS substrate is critically important. In this manuscript, vacuum filtration is utilized to fabricate the silver nanoparticles (AgNPs) embedded nylon filter membrane (ANFM) as flexible paper-based SERS chips. By characterizing the typical analytes with the miniaturized smartphone-based Raman analyzer, the proposed SERS chips have successfully demonstrated good sensitivity, repeatability and stability. The lowest concentration as detected can approach 1 pmol for Rhodamine 6G (RH6G) and 10 pmol for both crystal violet (CV) and malachite green (MG), respectively. With the help of microporous structure of the membrane, the ANFM based SERS chips can implement the separation of small molecules from complex mixture and can achieve “purified” SERS signals of targeted molecules. Besides, with the function of anti-friction resistance and flexibility, the ANFM can serve as SERS papers to pre-concentrate the contaminates by multiple swapping and further enhance the SERS signals for point of care analysis. Therefore, we demonstrate multi-functions of the flexible ANFM based SERS chips, which provides a promising solution for the POCT analysis with SERS technique on account of its flexibility and low fabrication cost.
关键词： silver nanoparticles,SERS chips,nylon filter membrane,Point of Care Testing,smartphone-based Raman analyzer,Surface-enhanced Raman spectroscopy
更新于2025-09-09 09:28:46