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CO2 laser interactions with wood tissues during single pulse laser-incision
摘要： Incising is a technique used to improve fluid flow in impermeable woods during wood treatment processes. Previous studies relating to the laser-incision of wood have neglected many aspects such as detailed analysis of the anatomy of the wood, including consideration of tangential/radial faces and earlywood/latewood interactions with the laser beam. By considering wood anatomy, a complete investigation of the CO2 laser-incision processes is presented that yields new knowledge of laser beam interaction with growth rings when incising into tangential/radial faces, and the low-density earlywood and higher density latewood within the growth ring. Southern Yellow Pine, Radiata Pine, European Redwood and Beech, each having different bulk densities, were laser-incised using a 2 kW ROFIN CO2 laser with radiation in the far-infrared regime (10.6 μm). Microstructural characterisations were carried out to better understand the effect of CO2 laser-incision and its parameters on the depth, diameter and quality of the incised holes. The laser-incised hole shapes were found to be uniform in depth, however, the hole circularity was significantly affected by the presence of earlywood and latewood tissues. Maximum and minimum diameters of incised holes were measured in the Radiata Pine (~1.3 mm) and in the Beech (~0.7 mm), respectively. Similarly, for equal laser powers used, the maximum and minimum depths of laser-incised holes were measured in the European Redwood (~33 mm) and in the Beech (~25 mm), respectively, with the laser incident on the radial face of the samples. CO2 laser pulse duration had a greater effect on diameter and depth of incised holes when compared to laser power and showed that the CO2 laser pulse duration is a dominant parameter when designing CO2 laser-incision processes.
关键词： Laser-incision,Wood,Circularity,Depth,Diameter,CO2 laser
更新于2025-11-21 11:24:58
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A highly stretchable, transparent and conductive wood fabricated by in-situ photopolymerization with polymerizable deep eutectic solvents
摘要： The rational design of high-performance flexible transparent electrically conducting sensor attracts considerable attention. However, these designed devices predominantly utilize glass and plastic substrates, which are expensive and not environmentally friendly. Here, novel transparent and conductive woods (TCWs) were fabricated by using renewable wood substrate and low-cost conductive polymer. Polymerizable deep eutectic solvents (PDES), acrylic-acid (AA)/choline chloride (ChCl), were used as backfilling agents and in-situ photopolymerized in the delignified wood, which endowed the materials with high transparency (transmittance of 90 %), good stretchability (strain up to 80 %), and high electrical conductivity (0.16 S m-1). The retained cellulose orientation and strong interactions between cellulose-riched template and poly(PDES) render the TCWs excellent mechanical properties. Moreover, the TCWs exhibited excellent sensing behaviors to strain/ touch, even at low strain. Therefore, these materials can be used to detect weak pressure such as human being’s subtle bending-release activities. This work provides a new route to fabricate functional composite materials and devices which have promising potential for electronics applications in flexible displays, tactile skin sensors and other fields.
关键词： deep eutectic solvent,stretchable wood,porous,transparent wood,strain/touch sensor
更新于2025-11-21 11:18:25
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Detection of Knot Defects on Coniferous Wood Surface Using Near Infrared Spectroscopy and Chemometrics
摘要： Lumber pieces usually contain defects such as knots, which strongly affect the strength and stiffness. To develop a model for rapid, accurate grading of lumbers based on knots, Douglas fir, spruce-pine-fir (SPF), Chinese hemlock, and Dragon spruce were used. The experiments explored the effects of modelling methods and spectral preprocess methods for knot detection, and investigated the feasibility of using a model built within one species to discriminate the samples from other species, using a novel variable selection method-random frog to select effective wavelengths. The results showed that least squares-support vector machines coupled with first derivative preprocessed spectra achieved best performance for both single and mixed models. Models built within Dragon spruce could be used to classify knot samples from SPF and Chinese hemlock but not Douglas fir, and vice versa. Eight effective wavelengths (1314 nm, 1358 nm, 1409 nm, 1340 nm, 1260 nm, 1586 nm, 1288 nm, and 1402 nm) were selected by RF to build effective wavelengths based models. The sensitivity, specificity, and accuracy in the validation set were 98.49%, 93.42%, and 96.30%, respectively. Good results could be obtained when using data at just eight wavelengths, as an alternative to evaluating the whole spectrum.
关键词： Coniferous wood,Knot detection,Near infrared spectroscopy (NIRS),Random frog algorithm,Least squares-support vector machines (LS-SVM)
更新于2025-09-23 15:23:52
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Transparent wood bearing a shielding effect to infrared heat and ultraviolet via incorporation of modified antimony-doped tin oxide nanoparticles
摘要： Optically transparent wood (TW) is an emerging candidate for applications in energy efficient buildings. In this study, anti-ultraviolet and infrared heat shielding TW was prepared based on the delignification of the wood's substrate. This was followed by infiltration of pre-polymerized methyl methacrylate (PMMA) with modified antimony-doped tin oxide (ATO) nanoparticles. The ATO addition enhanced the interfacial bonding among the compounds, which improved the fracture strength, leading to a high fracture strength of 96.4 MPa and modulus of 4.27 GPa with addition of 0.3% ATO. Furthermore, the obtained ATO/TW exhibited high transparency, excellent near infrared (NIR) heat shielding performance, and ultraviolet (UV) shielding properties according to the ultraviolet–visible spectrophotometer measurement, the infrared heat shielding simulation test, and the UV-shielding test. The TW treated with 0.3% ATO still maintained a very low thermal conductivity of around 0.2 W m?1 K?1. After addition of 0.7% ATO, the obtained TW had a quite low UV transmittance of ＜20%. The Aspergillus niger maintained high viability after UV irradiation treatment when shielded with TW treated with 0.7% ATO. The findings indicate that the multifunctional and durable ATO/TW has a potential to be used as energy-saving building material.
关键词： A. Nano composites,A. Wood,B. Ultraviolet shielding,B. Infrared heat shielding
更新于2025-09-23 15:23:52
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Image of O2 dynamics released by oak wood submerged in model wine with nanoparticle sensors
摘要： Oxidation of wine while in contact with oak wood is a well-known fact and recognized as an important process in wine ageing. The slow and continuous di?usion of oxygen from the oak wood entrapped in its porosity occurs and encourages the reactions usually related with wine aging. In this work, oxygen sensitive particles were used to study the oxygen dynamics from di?erent anatomical regions of the oak wood and simultaneously the oxygen increasement because of the deoxygenation of the wood and the oxygen depletion due to its consumption by the tannins and other compounds released from the wood. To this end, core-shell-type PSPVP nanoparticles stained with Macrolex Fluorescence Yellow and Pt-TFPP were employed as reference and oxygen-sensitive particles respectively. Moreover, a Guppy Pro RGB camera was employed to monitor the particles performing ratiometric oxygen imaging, using the green and red channels to acquire the light emitted from the reference and the oxygen-sensitive particles respectively. Because the volume of nanosensors corresponding to each surface unit is very di?erent from that of the wood region, di?erent exposure times were chosen to obtain the images at each of the times. The results show the wood degassing process during the ?rst minutes of the experiment, the oxygen release from di?erent structural elements of the wood, its consumption by the released compounds from wood and the di?usion of the oxygen through the model wine.
关键词： Nanoparticles,Wine,Oxygen consumption,Optical oxygen imaging,Oak wood
更新于2025-09-23 15:23:52
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Potential of Near-infrared Spectroscopy to Detect Defects on the Surface of Solid Wood Boards
摘要： Defects on the surface of solid wood boards directly affect their mechanical properties and product grades. This study investigated the use of near-infrared spectroscopy (NIRS) to detect and classify defects on the surface of solid wood boards. Pinus koraiensis was selected as the raw material. The experiments focused on the ability to use the model to sort defects on the surface of wood into four types, namely live knots, dead knots, cracks, and defect-free. The test data consisted of 360 NIR absorption spectra of the defect samples using a portable NIR spectrometer, with the wavelength range of 900 to 1900 nm. Three pre-processing methods were used to compare the effects of noise elimination in the original absorption spectra. The NIR discrimination models were developed based on partial least squares and discriminant analysis (PLS-DA), least squares support vector machine (LS-SVM), and back-propagation neural network (BPNN) from 900 to approximately 1900 nm. The results demonstrated that the BPNN model exhibited the highest classification accuracy of 97.92% for the model calibration and 97.50% for the prediction set. These results suggest that there is potential for the NIR method to detect defects and differentiate between types of defects on the surface of solid wood boards.
关键词： Surface defects,BPNN,PLS - DA,LS-SVM,Near-infrared spectroscopy,Solid wood boards
更新于2025-09-23 15:22:29
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The Role of Rayleigh-Wood Anomalies and Surface Plasmons in Optical Enhancement for Nano-Gratings
摘要： We propose and report on the design of a 1-D metallo-dielectric nano-grating on a GaAs substrate. We numerically study the impact of grating period, slit and wire widths, and irradiating angle of incidence on the optical response. The optimal wire width, w = 160 nm, was chosen based on previous results from investigations into the influence of wire width and nano-slit dimensions on optical and electrical enhancements in metal-semiconductor-metal photodetectors. In this present project, resonant absorption and reflection modes were observed while varying the wire and nano-slit widths to study the unique optical modes generated by Rayleigh-Wood anomalies and surface plasmon polaritons. We observed sharp and diffuse changes in optical response to these anomalies, which may potentially be useful in applications such as photo-sensing and photodetectors. Additionally, we found that varying the slit width produced sharper, more intense anomalies in the optical spectrum than varying the wire width.
关键词： Rayleigh-Wood anomalies,photo-sensing,nano-optics,plasmonics
更新于2025-09-23 15:21:01
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Green production of fluorescent carbon quantum dots based on pine wood and its application in the detection of Fe3+
摘要： Carbon quantum dots (CQDs) have novel applications as fluorescent nanomaterials in various fields. In this study, a green hydrothermal carbonisation (HTC) method is proposed to produce CQDs from pine wood (P-CQDs). The P-CQDs exhibited excellent fluorescence characteristics, with the optimal excitation wavelength being 330 nm and a corresponding emission wavelength of 447 nm. A blue light emission under ultraviolet light was observed and a typical graphene structure was seen in the HR-TEM images with a fringe spacing of 0.21 nm. Moreover, the mechanism of P-CQD formation during the HTC process was proposed. It was observed that P-CQDs demonstrated an aromatic polymer structure rich in oxygen-containing groups. This is because of the condensation, chain breaking, and chain forming reactions occurring among the hydrolytic products of the cellulose, hemicellulose, and lignin in pine wood. The fluorescence quenching results indicated that the P-CQDs selectively detected Fe3+ in an aqueous phase. This implies that these CQDs have broad application prospects for Fe3+ detection. More importantly, this signifies that the large-scale and low-cost production of CQDs and Fe3+ sensors will now be possible.
关键词： CQDs,Formation mechanism,Fluorescence characteristic,Fe3+ sensor,Pine wood
更新于2025-09-23 15:19:57
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Rapid identification of wood species by near-infrared spatially resolved spectroscopy (NIR-SRS) based on hyperspectral imaging (HSI)
摘要： Conventional near-infrared (NIR) spectroscopy has shown its potential to separate wood species non-destructively based on the aggregate effect of light absorption and scattering values. However, wood has an aligned microstructure, and there is a large refractive index (RI) mismatch between the wood cell wall substance (n≈1.55) and the cell lumen (air≈1.0, water≈1.33). Light scattering is dominant over absorption μ′ (cid:31)( ) a in wood, and this fact can be utilized for complex classification purposes. In this study, an NIR hyperspectral imaging (HSI) camera combined with one focused halogen light source (? 1 mm) was designed to evaluate the light scattering patterns of five softwood (SW) and 10 hardwood (HW) species in the wavelength range from 1002 to 2130 nm. Several parameters were combined to improve the data quality, such as image histogram plots of defined spaced bins (associated with diffuse reflectance values of light), variance calculation on the frequency (the number of pixels in each bin) of each histogram and the principal component analysis (PCA) of all the variance values at each wavelength. The identification accuracy of the quadratic discriminant analysis (QDA) under the five-fold cross-validation method was 94.1%, based on the first three principal component (PC) scores.
关键词： spatially resolved spectroscopy,light scattering characteristics,wood species identification,hardwood,quadratic discriminant analysis (QDA),near-infrared hyperspectral imaging camera,principal component analysis (PCA),softwood,halogen spot-light source
更新于2025-09-19 17:15:36
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Surface Properties of Beech Wood after CO2 Laser Engraving
摘要： The paper deals with the properties of a beech wood surface treated by CO2 laser engraving. The studied concerns were the discoloration, changes to morphology assessed through roughness and waviness parameters, and surface wetting with standard liquids (water and diiodomethane), with the aim of determining the wood surface free energy. The results have confirmed that the studied properties of the beech wood surface varied significantly, which were affected by the laser beam power P and raster density n. With increasing P and n, the lightness L* (expressed in CIE L*a*b* color space) decreased significantly. We also observed significant variation in the color coordinates a* and b*. At 8% laser power, the roughness and waviness parameters measured parallel as well as perpendicular to the grain increased proportionally with the increasing raster density. However, 4% laser power was not associated with distinct changes. Increasing the raster density reduced beech wood surface wetting equally with water and with diiodomethane. This was reflected in the higher contact angle values. The wood surface exhibited higher hydrophobicity at 4% laser power. At this power, the increasing raster density was reflected in the decreasing surface free energy, due to its polar component decrease. At 8% laser power, the changes in surface free energy were very minor from the practical viewpoint. The results suggest a potential good adhesion between film-forming materials and wood. However, the gluing performance may be negatively affected by the high roughness attained at 8% laser power and at higher raster densities.
关键词： color,wetting,surface properties,CO2 laser,roughness,contact angle,beech wood,surface free energy
更新于2025-09-19 17:13:59