1：Experimental Design and Method Selection:

The study involved delignification of wood substrate using NaClO2, surface modification of ATO nanoparticles with KH570 silane coupling agent, dispersion of modified ATO in MMA, pre-polymerization, infiltration into delignified wood, and polymerization to form ATO/TW composites. Methods included SEM, TEM, FT-IR, UV-Vis-NIR spectrophotometry, thermal conductivity measurement, mechanical testing, infrared heat shielding simulation, and UV shielding tests.

2：Sample Selection and Data Sources:

Poplar wood (P. adenopoda Maxim) samples of dimensions 25 mm × 25 mm × 1 mm and 50 mm × 50 mm × 1 mm were used. Chemicals were analytical grade from specified suppliers.

3：List of Experimental Equipment and Materials:

Equipment included SEM (JSM-7500F), TEM (Tecnai G20, JEM 2100), UV-Vis spectrophotometer (Cary100), UV-Vis-NIR spectrophotometer (Lambda 950), FT-IR spectrometer (Kingslh, ZN-04), laser flash thermal analyzer (LAF-457), electromechanical universal testing machine (CMT5504, MTS), infrared lamp (PHILIPS, R125), QUV accelerated weathering tester, portable spectrocolorimeter (CM-2300D, MINOLTA). Materials included sodium chlorite, acetic acid, sodium acetate, ethanol, acetone, MMA, AIBN, ATO nanoparticles, KH570, Aspergillus niger.

4：Experimental Procedures and Operational Workflow:

Wood delignification with NaClO2 solution, ATO modification with KH570, dispersion in MMA, pre-polymerization with AIBN, infiltration into delignified wood under vacuum, polymerization at 70°C, characterization of morphology, optical properties, thermal conductivity, mechanical properties, infrared heat shielding simulation, and UV shielding tests including weathering and fungal viability assays.

5：Data Analysis Methods:

Data analyzed using spectrophotometers for transmittance, thermal analyzer for conductivity, universal testing machine for stress-strain curves, and colorimeter for color changes; statistical methods not specified.