- 标题
- 摘要
- 关键词
- 实验方案
- 产品
过滤筛选
- 2019
- composite electrode
- silver nanowire
- reduced graphene oxide
- zinc oxide
- Optoelectronic Information Materials and Devices
- China Jiliang University
- Guangdong Poly-Optoelectronics Co.
-
Zinc Oxide Nanoparticles Synthesized by Suaeda japonica Makino and Their Photocatalytic Degradation of Methylene Blue
摘要： Green chemistry gained special attention for the environmental safety. In addition, green synthesized plant based nanoparticles for the degradation of industrial pollutant dye also received special focuses. Thus, photocatalytic activity of nanosized zinc oxide (Sj-ZnONps) synthesized by a simple co-precipitation method using sodium hydroxide, zinc nitrate, and Suaeda japonica extract as starting materials was carried out. The reaction was implemented in comparatively low temperature (50oC) without further calcination. The absorption spectrum demonstrated an extinction peak at ~362 nm, which is characteristic to the ZnO nanoparticles. Field-emission transmission electron microscope revealed smaller agglomeration of hexagonal Sj-ZnONps (~100 nm). X-ray diffraction patterns exposed polycrystalline ZnO with hexagonal wurtzite structure. The self-assembly of Sj-ZnONps was achieved due to the capping of phytoconstituents present in extract as evident from Fourier-transform infrared spectroscopy analysis. The photocatalytic degradation of Sj-ZnONps was estimated in reduction of methylene blue (MB). The reaction mixtures comprising of MB, S. japonica extract and Sj-ZnONps had the most significant decrease of MB by 54 %. In conclusion, the Sj-ZnONps can be used as a photocatalyst for decomposition of organic pollutions present in water.
关键词： Photocatalytic degradation,Green synthesis,Suaeda japonica Makino,Methylene blue,Zinc oxide nanoparticles
更新于2025-09-23 15:21:21
-
Nanocrystalline ZnO Obtained by the Thermal Decomposition of [Zn(H2O)(O2C5H7)2] in 1-Butanol: Synthesis and Testing as a Sensing Material
摘要： The influence of conditions of heat treatment of a solution [Zn(H2O)(O2C5H7)2] in 1-butanol (temperature 125–185°C, treatment times 2, 4, and 6 h) on dispersion and microstructure of the formed nanocrystalline and poorly aggregated zinc oxide, promising component for optoelectronics, including as receptor materials of chemical gas sensors, was investigated. IR spectroscopy showed that the precursor decomposition occurs through the cleavage of the Cβ–Cγ bond of the ligand to form acetone and butyl acetate. It was determined that at the minimum treatment temperature and time (125°C, 2 h) ZnO nanoparticles are nearly spherical, and under hard conditions, rodlike particles are formed. At 125°C (treatment times 4 and 6 h), rodlike particles are organized into dense agglomerates resembling bundles in shape, and at the higher temperatures there is no aggregation of ZnO nanoparticles. The high CO selectivity and sensitivity (4–100 ppm) was revealed for oxide coatings obtained by screen printing using ZnO nanopowders synthesized at 125°C (treatment times 2 and 4 h).
关键词： ZnO,acetylacetonate,zinc oxide,gas sensor,nanoparticles,1-butanol
更新于2025-09-23 15:21:21
-
Investigation on annealing temperature-dependent optical properties of electron beam evaporated ZnSe thin films
摘要： This research work is devoted to studying optical properties of zinc selenide (ZnSe) thin films deposited by electron beam evaporation technique and annealed at different temperatures in a nitrogen environment. The structural analysis by X-ray diffraction confirmed that the obtained ZnSe films had cubic zinc-blende structure with preferred orientation along plane (111). Based on Swanepoel's envelope method, some important optical parameters such as absorption coefficient, extinction coefficient, refractive index and optical band gap, were evaluated through the transmission spectrum ranging from 300 to 1500 nm at room temperature. The optical band gap increased from 2.52 to 2.65 eV with the increasing annealing temperature. However, both the thickness and refractive index of the films decreased. In addition, the dispersion parameters of the refractive index and energy were also studied by using Wemple-DiDomenico single oscillator model.
关键词： Optical properties,Thin films,Electron beam evaporation,Zinc selenide,Thermal annealing
更新于2025-09-23 15:21:21
-
Highly Enhanced Photocatalytic Water-splitting Activity of Gallium Zinc Oxynitride Derived from Flux-assisted Zn/Ga Layered Double Hydroxides
摘要： The Ga/Zn-oxynitride solid solution [(GaN)1-x(ZnO)x] is one of the promising visible-light harvesting photocatalysts for overall water-splitting. A series of (GaN)1-x(ZnO)x (0.11 ≤ x ≤ 0.33) are synthesized by calcining the carbonate-type Zn/Ga-LDH precursor with and without sodium carbonate flux at 850 oC for 8 - 14 h under a NH3 gas-flow. The solid solutions without flux are determined to be low in crystallinity but plate-like in morphology with preferred orientation could be observed. On the other hand, those with flux turn out to be better in crystallinity, and eventually exhibit significantly higher photocatalytic activity for overall water splitting under visible-light irradiation than those without flux. In addition, the bandgap energies can also be engineered from 2.57 eV to 2.72 eV by changing the synthetic parameter such as nitridation time. It is, therefore, suggested that the present new approach can offer new opportunities for designing the next generation photocatalytic systems.
关键词： Overall water splitting,Photocatalyst,Gallium Zinc Oxynitride,Layered double hydroxides,Flux
更新于2025-09-23 15:21:21
-
Design of color tunable thin film polymer solar cells for photovoltaics printing
摘要： Color tunable thin film polymer solar cells have demonstrated the potentials of a wide applications in photovoltaics printing, which is significant for ink pollution reduction and energy saving. This work presents a new effective approach to realize color-tuning photovoltaic cells with optical microcavity structures. Aluminum-doped zinc oxide is utilized as electron transport layer material. With its high electrical conductivity, the thickness tuning range can be quite large, which means the cavity length has a wide variation range. It thus provides sufficient space for optical thin film design to obtain multi colors. By the transfer matrix method, device reflection and absorption spectra are numerically investigated. Based on that, the optical principles for color tunability are explored. In further step, the relationship between device photovoltaics performance and reflective colors are also discussed. Finally, the color coordinates and luminosities are calculated. As results, the colors of the devices designed are capable to cover a relatively large region in Commission Internationale de l′Eclairage (CIE) 1931 x, y chromaticity diagram, which is available to be integrated into the advertisement poster boards, building wall printing and other display applications.
关键词： optical microcavity,thin film polymer solar cells,aluminum-doped zinc oxide,photovoltaics printing,color tunable
更新于2025-09-23 15:21:01
-
Effects of background gases and pressure in pulsed laser deposition of Al-doped ZnO
摘要： Background gases (O2, He or Ar) with the pressure from ~ 10?3 Pa to 133.3 Pa are used in 355 nm laser deposition of Al-doped ZnO at room temperature. The effects of these gases and pressure on plasma formation are studied by optical emission spectroscopy (OES) and time of flight (TOF) measurement. The OES results show that the emission intensity of the species in O2 and Ar decrease slightly and then increase exponentially above ~ 5 Pa. The emission intensity in Ar is the highest, followed by emission in O2 whilst the emission in He is low and weakly depend on background gas pressure. TOF measurements indicate that the ion velocity decrease with increasing O2 and Ar pressure at about 5–10 Pa. The ion velocity is highest in He while the ion velocities in O2 and Ar are similar. Thin-film samples deposited in different gas at 2.6 Pa are amorphous, but those deposited at 133.3 Pa are crystalline and exhibit different morphologies and optical properties depending on type of gas. Samples deposited in O2 are highly transparent but those deposited in He and Ar contain nano and micron-sized structures with <50% transmittance. In addition, Zn crystallites are detected by X-ray diffraction.
关键词： Pulsed laser deposition,Background gases,Aluminum-doped zinc oxide,Pressure,Laser produced plasma,Nanostructured films
更新于2025-09-23 15:21:01
-
Effect of Uncontrollable Impurities on the Absorption Spectrum of a NaGd(WO4)2 Laser Crystal
摘要： Three NaGd(WO4)2 single crystals were grown by the Czochralski method using charges of different chemical purity. The impurity compositions of the grown crystals were analyzed by inductively coupled plasma mass spectrometry. The optical absorption spectra of the crystals were measured, and the effect of uncontrollable impurities on their optical properties and color was analyzed. The green color encountered in NaGd(WO4)2 crystals in some cases was shown to be due to the uncontrollable impurities of d elements, among which the chromium impurity had the most significant effect.
关键词： optical absorption,impurity purity,color centers,single crystals,zinc tungstate,ytterbium
更新于2025-09-23 15:21:01
-
CuSCN as the Back Contact for Efficient ZMO/CdTe Solar Cells
摘要： The replacement of traditional CdS with zinc magnesium oxide (ZMO) has been demonstrated as being helpful to boost power conversion e?ciency of cadmium telluride (CdTe) solar cells to over 18%, due to the reduced interface recombination and parasitic light absorption by the bu?er layer. However, due to the atmosphere sensitivity of ZMO ?lm, the post treatments of ZMO/CdTe stacks, including CdCl2 treatment, back contact deposition, etc., which are critical for high-performance CdTe solar cells became crucial challenges. To realize the full potential of the ZMO bu?er layer, plenty of investigations need to be accomplished. Here, copper thiocyanate (CuSCN) is demonstrated to be a suitable back-contact material with multi-advantages for ZMO/CdTe solar cells. Particularly, ammonium hydroxide as the solvent for CuSCN deposition shows no detrimental impact on the ZMO layer during the post heat treatment. The post annealing temperature as well as the thickness of CuSCN ?lms are investigated. Finally, a champion power conversion e?ciency of 16.7% is achieved with an open-circuit voltage of 0.857 V, a short-circuit current density of 26.2 mA/cm2, and a ?ll factor of 74.0%.
关键词： zinc magnesium oxide,copper thiocyanate,CdTe,CuSCN
更新于2025-09-23 15:21:01
-
[IEEE 2019 IEEE 11th International Conference on Humanoid, Nanotechnology, Information Technology, Communication and Control, Environment, and Management ( HNICEM ) - Laoag, Philippines (2019.11.29-2019.12.1)] 2019 IEEE 11th International Conference on Humanoid, Nanotechnology, Information Technology, Communication and Control, Environment, and Management ( HNICEM ) - Voltage Characterization of Magnesium-doped Zinc Oxide by Electrodeposition Method for Solar Photovoltaic (PV) Cells
摘要： The research paper adapted the study of Rajpal and Kumar (2016). The Magnesium (Mg)-doped Zinc Oxide (ZnO) was prepared using the electrodeposition method. The samples obtained from the experiment were then collated to observe the photoconductivity value and the percentage of Voltage Regulation of the plates. Three (3) different tilt angle orientation were utilized in gathering the data of the Voltage Regulation percentage (%VR) and photoconductivity. The photoconductivity value acquired from the undoped plate is 0.7083 while, for the doped plates are 0.8438V, 0.6897V and 0.7204V. On the other hand, the %VR acquired for 0?, 13? and 20° were 1.283%, 5.820% and 3.456%, respectively. Moreover, the percent Battery Charge collated from the experiment are 0.39%, -1.20% and 1.11%, respectively. Further, the experiments showed that sun exposure and temperature have a significant impact on the electrical conductivity and output of the cells.
关键词： electrodeposition,tilt angles,Magnesium-doped,zinc oxide
更新于2025-09-23 15:21:01
-
Zinc oxide quantum dots for textile dyes and real industrial wastewater treatment: Solar photocatalytic activity, photoluminescence properties and recycling process
摘要： Three samples of ZnO quantum dots (ZQDs) were synthesized by a modified sol–gel method at different temperatures for 3 h. The first sample (S1) was prepared at room temperature 27 °C, while second and third samples (S2) and (S3) were prepared by the calcination process at 500 and 900 °C, respectively. A study of XRD and TEM determines the purity, high crystallinity and the presence of elongated shape of the prepared catalysts. On using TEM, DRS and EBT analysis, the crystallite size values, bandgap energy, and active surface area were (7.1 nm, 3.49 eV, and 150.1 m2/g), (9.8 nm, 3.45 eV and 112.2 m2/g) and (13.5 nm, 3.39 eV and 78.94 m2/g) for S1, S2, and S3, respectively. The Photoluminescence properties showed that the fluorescence rate for S1 was doubled the observed one in the S2 sample. The photodegradation results of both methyl orange as an industrial raw material and real industrial wastewater of S1 sample showed the finest activity when compared with the rest samples. It was cleared from the collecting data that the photocatalytic performance decreases with the crystallite size increases The mineralization efficiency of the real industrial wastewater that exposed to sunlight for six months were evaluated according to the allowed COD limit for Egyptian Environmental Law, In addition the recycling process for reusable for ZnO prepared samples for 8 times investigated and evaluated.
关键词： Real industrial wastewater,Zinc oxide quantum dots,Solar photocatalytic activity,Recycling process,Sol-gel method
更新于2025-09-23 15:21:01