- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Data on characterization and validation of assays for ultrasensitive quantitative detection of small molecules: Determination of free thyroxine with magnetic and interferometric methods
摘要： The presented data refer to optimization and quantitative characterization of a rapid lateral flow assay based on high-affinity bifunctional ligand and magnetic nanolabels, which was developed for detection of small molecules of thyroid hormones. The results were obtained by including the magnetic particle quantification method, spectral-correlation interferometry and spectral-phase interferometry, dynamic light scattering, enzyme linked immunosorbent assay. The long-term stability of "antibody – magnetic nanoparticle" conjugates is shown. The assay specificity is confirmed, and verification of successful combination of magnetic particles and antibodies is demonstrated. The kinetic and equilibrium dissociation constants are determined for interactions between thyroxine and monoclonal antibodies. The obtained data could be used for design of other platforms for detection of small molecules.
关键词： ELISA,Lateral flow assay,Small molecules,Ultrasensitive detection,Free thyroxine,Interferometry,Magnetic nanolabels,Dynamic light scattering
更新于2025-09-23 15:22:29
-
Light scattering by a homogeneous sphere near a plane boundary II
摘要： The problem of light scattering by a homogeneous sphere above a plane boundary is considered in this paper. Hankel transformation and Erdélyi’s formula are used to satisfy the boundary conditions on the plane and the determination of the unknown coefficients in the scattered field is achieved by matching the electromagnetic boundary conditions on the surface of the sphere. Existence and uniqueness of the solution involving these unknown coefficients are shown and the extinction efficiency factor is presented.
关键词： plane boundary,Light scattering,homogeneous sphere,extinction efficiency factor
更新于2025-09-23 15:22:29
-
Influence of the capping layer material on the interfacial Dzyaloshinskii-Moriya interaction in Pt/Co/capping layer structures probed by Brillouin light scattering<sup></sup>
摘要： Influence of the capping layer material on the interfacial Dzyaloshinskii-Moriya interaction in Pt/Co/capping layer structures probed by Brillouin light scattering. Co ultrathin films, of various thicknesses (0.8 nm ≤ tCo ≤ 2.5 nm), have been grown by sputtering on Si substrates, using Pt buffer layers and different capping layers (Cu, Ir, MgO and Pt). The x-ray diffraction revealed that our films have a (111) out-of-plane texture with various degrees of strains. Their magnetic properties have been studied by vibrating sample magnetometry (VSM) and Brillouin light scattering (BLS) in the Damon-Eshbach geometry. VSM characterizations revealed that films with Co thickness below (above) the spin reorientation transition thickness, which is capping layer dependent, are perpendicularly (in-plane) magnetized, suggesting the existence of an interface anisotropy. The magnetic dead layer has been taken into account to precisely determine the surface anisotropy constant was found to be 1.42 ± 0.02 erg/cm2 and of 1.33 ± 0.02 erg/cm2 for the Pt/Co/Cu and Pt/Co/Ir samples, respectively, suggesting that it is due to the Pt/Co interface and that the top Co/Cu or Co/Ir interfaces have a negligible contribution. A lower value of 1.07 ± 0.02 erg/cm2 has been obtained for Pt/Co/MgO most probably due to over-oxidation of Co at the Co/MgO interface. The BLS measurements revealed a pronounced nonreciprocal spin waves propagation, due to the interfacial Dzyaloshinskii-Moriya interaction (iDMI) induced by Pt interface with Co, which increases with decreasing Co thickness. The surface iDMI constant Ds estimated at -0.8 pJ/m, -1.05 pJ/m and –0.95 pJ/m, respectively for Pt/Co/Ir, Pt/Co/Cu and Pt/Co/MgO for the samples where a linear thickness dependence of the effective iDMI constant has been observed.
关键词： Dzyaloshinskii-Moriya interaction,Brillouin light scattering,spin waves and Perpendicular magnetic anisotropy,Interface effects
更新于2025-09-23 15:22:29
-
Interfacial Tensions and Viscosities in Multiphase Systems by Surface Light Scattering (SLS)
摘要： Hypothesis Multiphase systems are relevant in many fields of process engineering. For process and product design in connection with multiphase systems, knowledge on the thermophysical properties of the individual phases such as viscosity and on the interfacial tension between these is required but often lacking in literature. Experiments In the present study, the applicability of surface light scattering (SLS) for the simultaneous measurement of interfacial tensions and viscosities in multiphase systems in macroscopic thermodynamic equilibrium is demonstrated. For two model systems consisting of n-decane and methanol as well as n-dodecane and methanol forming a vapor-liquid-liquid equilibrium at atmospheric pressure, surface fluctuations which show an oscillatory behavior at the vapor-liquid and liquid-liquid interface could be associated with hydrodynamic modes. Findings From an exact theoretical description of the dynamics of the surface fluctuations, absolute data for the dynamic viscosities of the two liquid phases as well as the vapor-liquid and liquid-liquid interfacial tensions could be determined at temperatures between (333 and 358) K with total measurement uncertainties (k = 2) down to about 2%. For both systems studied at temperatures close to the upper critical solution temperature, the viscosities of the two liquid phases approach each other and the liquid-liquid interfacial tension tends to zero.
关键词： liquid-liquid systems,interfacial tension,multiphase systems,interfaces,upper critical solution temperature,vapor-liquid systems,viscosity,surface light scattering
更新于2025-09-23 15:21:21
-
Light scattering from the critical modes of the Verwey transition in magnetite
摘要： We present inelastic light scattering data on a single crystal of magnetite (Fe3O4) across the Verwey transition. We identify anomalies of the lattice vibrations that originate from strong coupling to electronic excitations. We reveal spectroscopic signatures of diffusive modes in the electronic contribution to the Raman response function. We thereby provide information on the critical dynamics and the hierarchy of the structural and electronic modes in the mechanism of the Verwey transition.
关键词： Raman spectroscopy,Verwey transition,critical dynamics,inelastic light scattering,magnetite
更新于2025-09-23 15:21:21
-
seed layers
摘要： We characterize asymmetric growth of magnetic bubble domains in perpendicularly magnetized Co/Ni multilayers grown on PtxIr1?x seed layers by application of perpendicular and in-plane magnetic fields. Using a refined model of domain wall creep that incorporates contributions from the anisotropic elastic energy, ε, and a chirality-dependent prefactor, v0, we elucidate factors that govern the mobility of Dzyaloshinskii domain walls as a function of seed-layer composition. The interfacial Dzyaloshinskii-Moriya interaction (DMI) magnitude is found to decrease monotonically with xIr, which is independently confirmed by Brillouin light scattering. Moreover, the persistence of significant asymmetry in velocity curves across the full composition range supports previous assertions that a chirality-dependent attempt frequency akin to chiral damping could play a critical role in the observed trends. This work helps resolve fundamental questions about the factors governing Dzyaloshinskii domain-wall creep and demonstrates varying Pt-Ir seed-layer composition as a method to tune DMI.
关键词： Dzyaloshinskii domain-wall creep,PtxIr1?x seed layers,Brillouin light scattering,interfacial Dzyaloshinskii-Moriya interaction,Co/Ni thin films
更新于2025-09-23 15:21:21
-
[ACS Symposium Series] Gels and Other Soft Amorphous Solids Volume 1296 || Probe Diffusion Dynamic Light Scattering of Polymer solutions and Gels
摘要： Probe diffusion dynamic light scattering technique is a powerful to investigate the dynamics of polymer chains in polymer solutions and gels. Not only the local dynamics and/or local viscosity but also the gel point and the post-gel dynamics can be investigated. In this chapter, we discuss (1) a conventional probe diffusion of radical polymerization of poly(N-isopropylacrylamide) (PNIPAM) aqueous system, (2) an in-situ isorefractive probe diffusion of tetra-arm poly(ethylene glycol) (Tetra-PEG) undergoing sol-gel transition via cross-end-coupling, and (3) of PNIPAM radical polymerization. It is demonstrated that the gel point is determined as a function of the reaction conversion, which is a more universal measure than the reaction time. The post-gel dynamics explored by the probe particles illuminates the local dynamics in a “pool” of the sol phase surrounded by a gel network. Furthermore, comparison in dynamics is made between well-controlled uniform networks (Tetra-PEG gels) and randomly cross-linked more heterogeneous networks (PNIPAM gels) the probe size from the viewpoints of dependence and scattering angle dependence.
关键词： gel point,Tetra-PEG,post-gel dynamics,Probe diffusion,PNIPAM,gels,polymer solutions,dynamic light scattering
更新于2025-09-23 15:21:21
-
[Springer Series in Optical Sciences] Fano Resonances in Optics and Microwaves Volume 219 (Physics and Applications) || Fano Resonances in Light Scattering by Finite Obstacles
摘要： Light scattering by ?nite obstacles, either a single particle or a number of particles in arbitrary con?guration, exhibits various resonant effects. It turns out that almost any resonant response, either in directional or total light scattering, can be ef?ciently described in terms of Fano resonance. One of the peculiar features of the Fano resonance is complete destructive interference, which can be associated with radiationless excitations, such as nontrivial anapole modes.
关键词： Fano resonance,finite obstacles,light scattering,anapole modes
更新于2025-09-23 15:21:21
-
Scattering of light from disordered photonic structures
摘要： We study theoretically and experimentally the scattering of light from ordered and disordered photonic structures. As an example, we consider a thin slab of a woodpile-type photonic crystal and introduce random fluctuations in the rod orientation, revealing a crossover from the Laue diffraction to the formation of speckle patterns. We observe a nontrivial interplay between order and disorder when the orientational disorder is added only in one direction of the square woodpile structure. Namely, ordered sets of rods produce disordered patterns and, vice versa, disordered sets of rods produce ordered patterns. We explain this effect theoretically and experimentally by the fact that light scatters only from the intersection points of different rods.
关键词： light scattering,Laue diffraction,speckle patterns,photonic structures,disorder
更新于2025-09-23 15:21:21
-
Nonlinear Optics || Spontaneous Light Scattering and Acoustooptics
摘要： In this chapter, we describe spontaneous light scattering; Chapters 9 and 10 present descriptions of various stimulated light-scattering processes. By spontaneous light scattering, we mean light scattering under conditions such that the optical properties of the material system are unmodified by the presence of the incident light beam. We shall see in the following two chapters that the character of the light-scattering process is profoundly modified whenever the intensity of the incident light is sufficiently large to modify the optical properties of the material system.
关键词： stimulated light-scattering,spontaneous light scattering,material system,optical properties,incident light
更新于2025-09-23 15:21:01