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Structural, electrical, optical and thermoelectric properties of e-beam evaporated Bi-rich Bi2Te3 thin films
摘要： Bi-rich Bi2Te3 thin films are prepared at 300 K using e-beam evaporation technique. A source power of 45 W for e-beam was used. Post deposition, these as-deposited Bi-rich Bi2Te3 (Bi-BT-AD) films are annealed at 100 °C (Bi-BT-100), 200 °C (Bi-BT-200) and 300 °C (Bi-BT-300) for 1 h under a pressure of 3 × 10-4 Pa. X-ray diffraction measurements reveal the presence of Bi phase together with crystalline Bi2Te3 indicating the possible presence of Bi-rich Bi2Te3 phase in the Bi-BT-AD film. The broad peaks from Bi2Te3 (015) plane indicates nanocrystalline nature of particles. With annealing, no change in diffraction pattern is observed for Bi-BT-100. However, Bi-BT-200 and Bi-BT-300 films show the emergence of x-ray reflection from unknown phases around 2θ ~ 20° and 47°. This indicates Bi related secondary phase segregation and the thermodynamic instability for the presence of Bi in Bi2Te3 lattice. From Raman studies it is discerned that Bi secondary phase coexist along with the Bi-rich Bi2Te3 nanocrystalline grains. On vacuum annealing Bi-rich Bi2Te3 thin films prevails as evidenced from the p-type electrical characteristics, while excess Bi disappears and converts into an unknown minor phase. The resistivity of all the annealed films are ~ 0.9 × 10-4 Ωcm. The Seebeck coefficients also do not show any change and remain around 33 to 36 μV/K. Thermoelectric properties of Bi-BT-100 exhibit high power factors when measured at different ΔT with a maximum of ~ 17.5 × 10-4 W/K2m for ΔT=100 °C. Thus, unlike the near-stoichiometric thin films, Bi-rich thin films require low temperature annealing (~100 °C) to achieve optimized parameters. Bi-rich Bi2Te3 thin films also show higher power factor compared to the near-stoichiometric thin films. Thus, favourable thermoelectric properties can be achieved at 300 K for temperature sensitive device fabrication using Bi-rich Bi2Te3 thin films.
关键词： Bismuth-rich bismuth telluride,thin films,electron-beam evaporation,power factor.
更新于2025-09-23 15:23:52
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Diamond like carbon films with embedded Cu nanoclusters deposited by reactive high power impulse magnetron sputtering: Pulse length effects
摘要： In the present study diamond like carbon films with embedded Cu nanoclusters (DLC:Cu films) were deposited by reactive high power impulse magnetron sputtering (HIPIMS). HIPIMS pulse length (pulse on time) effects were considered. The dependence of the chemical composition on pulse length was found. Structure of diamond like carbon matrix of the nanocomposite films studied by Raman scattering spectroscopy has indicated weak increase of the sp3/sp2 carbon bond ratio with HIPIMS pulse length. Studies of the shape and dimensions of copper nanoclusters performed by He ion microscopy have shown that increase of the HIPIMS pulse on time resulted in increased number of the nanoclusters and subsequent increase of the Cu nanoclusters size. Study of optical properties revealed surface plasmon resonance effect in all investigated films. Correlation between the optical absorption spectra and photoexcited charge carrier relaxation time recorded by the pump probe spectroscopy was found. The highest relaxation time was observed at the excitation wavelength close to the absorption surface plasmon resonance peak wavelength The highest maximum relaxation time was observed for the DLC:Cu film deposited by using HIPIMS pulse of 400 μs on time. It was explained by the dependence of the relaxation time on Cu nanocluster size.
关键词： Pulse length,Diamond-like carbon,High-power pulsed magnetron sputtering,Structure,Optical properties,X-ray photoelectron spectroscopy,Copper,Nanoclusters
更新于2025-09-23 15:23:52
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Performance evaluation of mode group power coupling for short reach SDM
摘要： The profound understanding of mode coupling in spatial multiplexed optical systems is required for performance optimization purposes. In this contribution different optical coupler technologies are compared with respect to their bit-error rate (BER) performance as multiplex devices in a (2 × 2) multiple-input multiple-output (MIMO) environment. Therefore, the power coupling coefficients between mode groups for all testbed components are determined at 1327 nm with a method based on impulse response measurements. This method and its refinements are presented in this work. By taking the obtained power coupling coefficients, the MIMO impulse responses are simulated and the corresponding BER performance for different launch parameters is studied. The simulation setup includes single-mode fiber (SMF) to multi-mode fiber (MMF) splices aligned with different radial eccentricities for mode group specific excitation, different multi-mode couplers for mode multiplexing, a 1 km OM4 grade MMF and a multi-mode fusion coupler for demultiplexing. Here, the setup with the customized fusion coupler shows the best BER results in comparison to other coupler technologies. In addition, the optimal choice of the SMF to MMF launch eccentricity highly depends on the implemented coupler technology. Particularly, deviations of 2 μm from the optimal launch setup can lead to a tenfold increase in the BER. It is noteworthy, that the optimal setup does not always include the center launch condition.
关键词： Multi-Mode MIMO,Mode Group Power Coupling,Coupler Technology
更新于2025-09-23 15:23:52
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Radiative energy and exergy analyses of spectrally-selective surfaces for CSP systems
摘要： This work presents a new methodology for calculations of spectral radiative energy and radiative exergy to evaluate the performances of concentrated solar power (CSP) systems. Spectral radiative properties and the operating temperature of selective surfaces, along with the temperature of the environment, are taken into account in analyses. The fundamental expressions needed for the spectral radiative energy and exergy analyses are introduced first. Then, the two approaches are used to assess the spectral performance of five selective coatings. The spectral analysis is performed in the wavelength range of 250 nm to 20,000 nm, while thermal analysis is carried out for the temperature range of 325 K to 800 K. NREL 6A coating was found to result in the highest radiative energy and radiative exergy for both efficiencies and gains, and for the best thermal stability compared to the other coatings.
关键词： selective coating,spectral radiative energy analysis,concentrating solar power systems,spectral radiative exergy analysis
更新于2025-09-23 15:23:52
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Outlier Events of Solar Forecasts for Regional Power Grid in Japan Using JMA Mesoscale Model
摘要： To realize the safety control of electric power systems under high penetration of photovoltaic power systems, accurate global horizontal irradiance (GHI) forecasts using numerical weather prediction models (NWP) are becoming increasingly important. The objective of this study is to understand meteorological characteristics pertaining to large errors (i.e., outlier events) of GHI day-ahead forecasts obtained from the Japan Meteorological Agency, for nine electric power areas during four years from 2014 to 2017. Under outlier events in GHI day-ahead forecasts, several sea-level pressure (SLP) patterns were found in 80 events during the four years; (a) a western edge of anticyclone over the Pacific Ocean (frequency per 80 outlier events; 48.8%), (b) stationary fronts (20.0%), (c) a synoptic-scale cyclone (18.8%), and (d) typhoons (tropical cyclones) (8.8%) around the Japanese islands. In this study, the four case studies of the worst outlier events were performed. A remarkable SLP pattern was the case of the western edge of anticyclone over the Pacific Ocean around Japan. The comparison between regionally integrated GHI day-ahead forecast errors and cloudiness forecasts suggests that the issue of accuracy of cloud forecasts in high- and mid-levels troposphere in NWPs will remain in the future.
关键词： outlier events,regional integration,global horizontal irradiance (GHI),photovoltaic (PV) power generation,numerical weather prediction (NWP),day-ahead forecast
更新于2025-09-23 15:23:52
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Analysis of Nonlinear Dynamics of a Quadratic Boost Converter Used for Maximum Power Point Tracking in a Grid-Interlinked PV System
摘要： In this paper, the nonlinear dynamics of a PV-fed high-voltage-gain single-switch quadratic boost converter loaded by a grid-interlinked DC-AC inverter is explored in its parameter space. The control of the input port of the converter is designed using a resistive control approach ensuring stability at the slow time-scale. However, time-domain simulations, performed on a full-order circuit-level switched model implemented in PSIM c software, show that at relatively high irradiance levels, the system may exhibit undesired subharmonic instabilities at the fast time-scale. A model of the system is derived, and a closed-form expression is used for locating the subharmonic instability boundary in terms of parameters of different nature. The theoretical results are in remarkable agreement with the numerical simulations and experimental measurements using a laboratory prototype. The modeling method proposed and the results obtained can help in guiding the design of power conditioning converters for solar PV systems, as well as other similar structures for energy conversion systems.
关键词： subharmonic oscillations,DC-DC converters,maximum power point tracking (MPPT),nonlinear dynamics,photovoltaic (PV),quadratic boost
更新于2025-09-23 15:23:52
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Effects of Metal Dopings on CuCr <sub/>2</sub> O <sub/>4</sub> Pigment for Use in Concentrated Solar Power Solar Selective Coatings
摘要： The process of fabricating the solar absorbing spinel-structured CuCr2O4 black oxide pigment doped with different metals (Mn, Ni, Co, Al, Zn, and Sn) was discovered to improve the solar selective property. Manganese stands out as an ideal dopant to Copper Chromite (CuCr2O4) for highly solar absorptive pigments compared to the other metal dopings. XRD analysis confirmed that various molar ratio of CuCr(2-x)MnxO4 spinel black oxides were successfully fabricated. Mn-doped black oxide has the highest absorptivity (the lowest band gap value of 1.35 eV) among other metal doping black oxides produced by the hydrothermal synthesis. Manganese is the only dopant that suppresses reflectance peaks exhibited by the copper chromium oxide at 1 μm and 1.5 μm in the light spectrum, raising the solar absorptivity of the pigment. Different manganese doping compositions are introduced to CuCr(2-x)MnxO4 where x = 0.1, 0.25, 0.5, 1, 1.5, 1.75, and 1.9. The high selective solar absorptivity appears after 100% (x=1) manganese doping with solar absorbance 0.9874 and a Figure of Merit (FOM) value of 0.9284.
关键词： Concentrated Solar Power,Solar selective coating,Solar-absorbing pigment,Black paint,Spinel black oxide.
更新于2025-09-23 15:23:52
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Simulation-Based Sensitivity Analysis of Conduction and Switching Losses for Silicon Carbide Power MOSFETs
摘要： The behavior of silicon carbide power MOSFETs is analyzed using TCAD device simulations with respect to conduction and switching losses. Device designs with varying breakdown voltages are simulated. The contributions to the on-state resistance are shown at room and elevated temperature. Whereas channel and substrate resistance dominate at low breakdown voltages, drift and JFET resistance dominate at high breakdown voltages. With increasing temperature, the channel resistance decreases and thus the drift resistance is the main contributor already at medium breakdown voltages. Manufacturing processes of a device can have a high influence on its losses. Variations in interface mobility, drift doping, and p-body doping can lead to a significant change of on-resistance, internal capacitances, and reverse recovery charge. For higher voltage classes the drift layer properties should be of major interest as it influences on-resistance and reverse recovery charge.
关键词： SiC power MOSFET,TCAD device simulation,sensitivity analysis,losses
更新于2025-09-23 15:23:52
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Effects of Nd:YAG laser surface treatment on tribological properties of cold sprayed Ti-6Al-4V coatings tested against 100Cr6 steel under dry condition
摘要： The surfaces of cold sprayed Ti-6Al-4V (Ti64) coatings were laser irradiated with different laser powers of 50-200 W to study the effects of Nd:YAG laser surface treatment on their tribological properties. The hardness of the laser treated Ti64 coatings became higher with higher laser power due to the more rapid cooling caused by a larger temperature difference between the coating surface and room temperature. The wear of the laser treated Ti64 coatings tested against 100Cr6 steel balls under dry condition at room temperature decreased with increased laser power as a result of their increased surface wear resistance associated with their increased surface hardness. It could be concluded that the laser surface treatment of the cold sprayed Ti64 coatings improved their surface wear resistance compared to that of the untreated Ti64 coatings.
关键词： Ti-6Al-4V,laser power,hardness,wear,laser surface melting,Cold spray
更新于2025-09-23 15:23:52
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[IEEE 2018 International Semiconductor Conference (CAS) - Sinaia (2018.10.10-2018.10.12)] 2018 International Semiconductor Conference (CAS) - Interface Trap Effects in the Design of a 4H-SiC MOSFET for Low Voltage Applications
摘要： The current-voltage characteristics of a 4H-SiC MOSFET dimensioned for a breakdown voltage of 650 V are investigated by means of a numerical simulation study that takes into account the defect state distribution at the oxide-semiconductor interface in the channel region. The modelling analysis reveals that, for these low-voltage devices, the channel resistance component plays a key role in determining the MOSFET specific ON-state resistance (RON) under different voltage biases and temperatures. The RON value is in the order of a few mΩ×cm2.
关键词： numerical simulations,power devices,ON-state resistance,4H-SiC,defects states
更新于2025-09-23 15:23:52