- 标题
- 摘要
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- 实验方案
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Increasing Fracture Toughness and Transmittance of Transparent Ceramics using Functional Low-Thermal Expansion Coatings
摘要： Transparent polycrystalline ceramics have the potential to enable applications no other materials can, but to do so their strength and toughness must be improved. However, surface strengthening treatments like those used for glasses have so far remained elusive. Here for the first time, we report on engineering unprecedented surface compression, of the magnitude achieved for ion-exchange strengthened glasses (~750 MPa) in transparent ceramics. This was achieved by applying functional, low thermal-expansion yttria coatings onto yttria-stabilized zirconia substrates and thermally treating. In some instances, the treatment more than doubled the fracture toughness while simultaneously increasing light transmittance.
关键词： surface compression,transparent ceramics,fracture toughness,thermal-expansion mismatch,yttria coatings
更新于2025-09-23 15:21:01
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Heterodyned photoacoustic effect generated by irradiation of single particles by two laser beams modulated at different frequencies
摘要： When a modulated light beam is absorbed by an incompressible particle, the photoacoustic e?ect can take place through heat di?usion into the surrounding ?uid followed by thermal expansion and the generation of sound. When two laser beams modulated at di?erent frequencies irradiate a particle in aqueous solution, the e?ect of one laser is to modulate the thermal expansion coe?cient of the solution in the proximity of the particle at its modulation frequency. Heat di?usion into the same region of ?uid from absorption of radiation from the second laser takes place in ?uid where the thermal expansion coe?cient is modulated so that the photoacoustic e?ect is produced at the sum and di?erence frequencies of the two lasers. Here, a theory for the photoacoustic e?ect at the heterodyne frequency for a single particle and the corresponding experiments with carbon particles of di?erent sizes are reported.
关键词： Heterodyne measurement,Heterodyned photoacoustic e?ect,Modulation of thermal expansion coe?cient
更新于2025-09-23 15:19:57
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In situ atomic level studies of thermally controlled interlayer stacking shifts in 2D transition metal dichalcogenide bilayers
摘要： We show interlayer stacking shifts occur in transition metal dichalcogenides (TMD) bilayers due to the strain introduced during sample heating, and attributed to rippling of one layer relative to the other. The atomic structure of the interlayer stacking is studied using annular dark field scanning transmission electron microscopy with an in situ heating holder. Before heating, bilayers show uniform interlayer stacking of AA9 and AB. When heated, contrast change is seen and associated with interlayer stacking changes at the atomic scale due to ripples. When cooled down to room temperature, these contrast features disappear, confirming it is a reversible process that is not related to defects or vacancies. Because the bottom layer is attached to the in situ heating chip made from Si3N4 and the top layer is in contact with the underlying TMD layer with weak van der Waals interaction, the two layers experience different forces during thermal expansion.
关键词： transition metal dichalcogenides,thermal expansion,scanning transmission electron microscopy,interlayer stacking,2D materials
更新于2025-09-23 15:19:57
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2D Material-enabled Nanomechanical Bolometer
摘要： We here describe a novel type of long-wavelength radiation detector that measures illumination intensity at room temperature through mechanical transduction. Compared to semiconductor-based bolometers, our nanomechanical detector exhibits low measurement noise and is inherently transparent and flexible. The presented solid-state device is based on a 2D-material film that acts as radiation absorber and detector of mechanical strain at the substrate-absorber interface. Optimization of the 2D material properties and realization of a novel edge-on device geometry combines unprecedented detectivity of 3.34 × 108 cm Hz1/2 W-1 with micrometer-scale spatial resolution. The observed combination of superior performance with the facile and scalable fabrication using only liquid processes shows the potential of the presented detector for future ubiquitous and wearable electronics.
关键词： thermal expansion,MoS2,infrared detectors,graphene,Bolometer
更新于2025-09-23 15:19:57
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Thermal expansion of α-nitrogen ice in terahertz spectroscopy
摘要： The volumetric thermal expansion coef?cient of a-nitrogen (N2) ice is calculated for temperatures between 10 and 25 K using its terahertz transmission data and a phonon model. The observed dip in terahertz transmission around 1.45 THz is modeled as phonon absorption based on an intermolecular potential which is sum of the Lennard-Jones potential and quadrupole–quadrupole interaction term. Using this model and our experimental data, the lattice parameters of a-N2 ice were obtained.
关键词： Thermal expansion,Terahertz,Time-domain spectroscopy,a-Nitrogen ice
更新于2025-09-23 15:19:57
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Thermal properties of high purity zinc-tellurite glasses for fiber-optics
摘要： The thermal properties of the series glasses (TeO2)(0.86-x)(ZnO)x(La2O3)0.04(Na2O)0.1 were studied. The heat capacity and characteristics of transitions between aggregative states were determined by the method of differential scanning calorimetry (DSC) in the temperature range 320-950 K. The experimentally obtained values of thermal conductivity, density and coefficient of thermal expansion at room temperature are as follows: 1.14 ± 0.06 W/(m?K), 5.20 ± 0.02 g/cm3 and (54.6 ± 1.2)?10-6 K-1, respectively. The model-statistical processing of calorimetric data was used to determine the complete set of standard thermodynamic functions together with their approximation to the unexplored low-temperature region by means of parametric similarity. The approach allows predicting the functions for unexplored intermediate glasses compositions.
关键词： heat capacity,thermal conductivity,thermodynamic functions,coefficient of thermal expansion,density,Zinc-tellurite glasses
更新于2025-09-19 17:15:36
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with two-dimensional and three-dimensional local environments
摘要： ZnNi(CN)4 is a three-dimensional (3D) framework material consisting of two interpenetrating PtS-type networks in which tetrahedral [ZnN4] units are linked by square-planar [NiC4] units. Both the parent compounds, cubic Zn(CN)2 and layered Ni(CN)2, are known to exhibit 3D and 2D negative thermal expansion (NTE), respectively. Temperature-dependent inelastic neutron scattering measurements were performed on a powdered sample of ZnNi(CN)4 to probe phonon dynamics. The measurements were underpinned by ab initio lattice dynamical calculations. Good agreement was found between the measured and calculated generalized phonon density-of-states, validating our theoretical model and indicating that it is a good representation of the dynamics of the structural units. The calculated linear thermal expansion coefficients are αa = ?21.2 × 10?6 K?1 and αc = +14.6 × 10?6 K?1, leading to an overall volume expansion coefficient, αV of ?26.95 × 10?6 K?1, pointing towards pronounced NTE behavior. Analysis of the derived mode-Grüneisen parameters shows that the optic modes around 12 and 40 meV make a significant contribution to the NTE. These modes involve localized rotational motions of the [NiC4] and/or [ZnN4] rigid units, echoing what has previously been observed in Zn(CN)2 and Ni(CN)2. However, in ZnNi(CN)4, modes below 10 meV have the most negative Grüneisen parameters. Analysis of their eigenvectors reveals that a large transverse motion of the Ni atom in the direction perpendicular to its square-planar environment induces a distortion of the units. This mode is a consequence of the Ni atom being constrained only in two dimensions within a 3D framework. Hence, although rigid-unit modes account for some of the NTE-driving phonons, the added degree of freedom compared with Zn(CN)2 results in modes with twisting motions, capable of inducing greater NTE.
关键词： framework compound,ZnNi(CN)4,negative thermal expansion,lattice dynamics,ab initio calculations,inelastic neutron scattering
更新于2025-09-19 17:15:36
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Crystallization and spectroscopic characterizations of binary SrO-B2O3 glasses doped with LiF, NaF, CaF2, or TiO2
摘要： Glasses based on the basic chemical composition of binary strontium borate (SrO 50-B2O350 mol%) together with samples containing dopant (2%) with one of the fluorides (LiF, NaF, CaF2) or TiO2 have been synthesized through the routinely melting and annealing technique. Collective structural, optical, and thermal properties have been measured for the prepared glasses. X-ray diffraction and SEM measurements were carried out for their corresponding glass-ceramics which were synthesized by controlled thermal heat treatment with two-step regime. FT infrared absorption spectra reveal composite vibrational modes in the mid-range 400–1600 cm?1 which are related to the co-presence of both triangular and tetrahedral borate building units in their particular different wavenumber sites. The low dopant level did not make any distinct variations in the IR spectra. X-ray diffraction patterns elucidate the formed crystal phases after crystallization mainly strontium metaborate and other related borate phase and the LiF shows no distinct variation while NaF2 and CaF2 induce the formation of additional crystalline Na-containing or Ca-containing phases besides the formation of NaF or fluorite (CaF2). TiO2 acts as a nucleating agent and also separate as rutile. The crystallization behavior has been correlated with the assumption of the tendency of SrO to induce phase separation in the host binary borate glass and controlled heat treatment initiates the separation of strontium metaborate crystalline phase in the base binary SrO-B2O3 in accordance with its composition and the role of dopants is found to be varying with the type of dopant. The measured thermal expansion parameters of the prepared glasses reveal variations in their values for transformation and softening temperatures depending on the type of added dopant. The changes in the thermal expansion coefficients in the different parts of the thermal curves are related to the ability of the network to absorb lattice expansion through bending of the bonds. The uniform observed ultraviolet absorption bands are related to traces of iron (Fe3+) ions present as impurities.
关键词： LiF,CaF2,NaF,Thermal expansion,FTIR optical spectra,SrO.B2O3 glass,Glass-ceramics,TiO2
更新于2025-09-19 17:15:36
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Enhanced sensitivity of distributed-temperature sensor with Al-coated fiber based on OFDR
摘要： In this paper, we present a distributed-optical fiber temperature sensor with enhanced sensitivity with Al coating using the Rayleigh backscattering (RBS) spectrum shift measured via optical frequency-domain reflectometry (OFDR). The Al-coated sensing fiber having a larger thermal expansion coefficient than that of silica produces a strain-coupled shift in the RBS under an increase in temperature. This effect leads to an enhanced temperature sensitivity of the distributed measurement scheme. In order to analyze the principle of temperature sensitivity enhancement, a simple analysis was performed by considering the fiber directional strain and force equilibrium between the optical fiber and Al-coated layer. Our results revealed that the temperature sensitivity achieved with the Al-coated fiber in OFDR was ～56% higher relative to that of a single-mode fiber.
关键词： Al-coated fiber,Distributed sensor,Thermal expansion,Optical frequency-domain reflectometry,Temperature sensitivity
更新于2025-09-19 17:15:36
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Ultrasound-assisted electrodeposition of Fe-Ni film for OLED mask
摘要： Fe-Ni alloy is considered as the most suitable metal for OLED mask making due to its excellent properties. However, electrodeposited Fe-Ni ?lm is often companied with poor surface quality and thermal expansion. To get proper ?lm for masks making, experiments of electroforming Fe–Ni were performed with di?erent ultrasonic powers and current densities. Results show that Fe-Ni ?lm with smooth surface could be electrodeposited at high current density due to the reducing of internal stress of ?lm by ultrasonic power. The iron content, grain size, micro-hardness and Young’s modulus of ?lm all present an upward trend with ultrasonic power increases from 13 W to 93 W, and then a downward trend due to the intensively transient cavitation caused by higher ultrasonic power 120 W. With the ultrasonic power of 93 W and current density of 1 A/dm2, a good surface quality of Fe-Ni ?lms with 60.07 wt.% iron content, microhardness 351 HV, Young's modulus 167.5 GPa and CTE 3.38 × 10?6/℃ can be electrodeposited.
关键词： Fe-Ni ?lm,Electroforming,Young's modulus,Ultrasonic power,Thermal expansion
更新于2025-09-19 17:13:59