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Robust CsPbX <sub/>3</sub> (X = Cl, Br, and I) perovskite quantum dot embedded glasses: nanocrystallization, improved stability and visible full-spectral tunable emissions
摘要： Currently, all inorganic perovskite quantum dots (QDs) of cesium lead halides (CsPbX3, X = Cl, Br, and I) have been mainly fabricated using wet chemical methods. Unfortunately, applications of perovskite QDs have been limited due to their poor stability. In the present work, the in situ growth of whole-family CsPbX3 (X = Cl, Br, and I) perovskite QDs in Zn–P–B–Sb based oxide glass via a glass crystallization strategy is reported. The as-prepared CsPbX3 QDs@glass nanocomposites exhibit typical excitonic recombination emissions and superior chemical stability benefited from the protection of the robust inorganic glass matrix. Through modifying the molar ratio of halide sources in glass, multi-color tunable emissions in the entire visible spectral range of 400–750 nm are achieved. As a result, light-emitting diode devices can be constructed by coupling blue-emissive CsPbBrCl2, green-emissive CsPbBr3 and red-emissive CsPbBr0.5I2.5 QDs@glass powders with a commercial ultraviolet chip, yielding bright white light luminescence with excellent optoelectronic performance.
关键词： stability,light-emitting diodes,tunable emissions,glass crystallization,perovskite quantum dots
更新于2025-11-20 15:33:11
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Nanoparticle Emissions from Metal-Assisted Chemical Etching of Silicon Nanowires for Lithium Ion Batteries
摘要： As one of the most promising anode materials for high-capacity lithium ion batteries (LIBs), silicon nanowires (SiNWs) have been studied extensively. The metal-assisted chemical etching (MACE) is a low-cost and scalable method for SiNWs synthesis. Nanoparticle emissions from the MACE process, however, are of grave concerns due to their hazardous effects on both occupational and public health. In this study, both airborne and aqueous nanoparticle emissions from the MACE process for SiNWs with three sizes of 90 nm, 120 nm, and 140 nm are experimentally investigated. The prepared SiNWs are used as anodes of LIB coin cells, and the experimental results reveal that the initial discharge and charge capacities of LIB electrodes are 3636 and 2721 mAh g-1 with 90 nm SiNWs, 3779 and 2712 mAh g-1 with 120 nm SiNWs, and 3611 and 2539 mAh g-1 with 140 nm SiNWs. It is found that, for 1 kW h of LIB electrodes, the MACE process for 140 nm SiNWs produces a high concentration of airborne nanoparticle emissions of 2.48 × 109 particles/cm3; the process for 120 nm SiNWs produces a high mass concentration of aqueous particle emissions, with a value of 9.95 × 105 mg/L. The findings in this study can provide experimental data of nanoparticle emissions from the MACE process for SiNWs for LIB applications, and can help the environmental impact assessment and life cycle assessment of the technology in the future.
关键词： Lithium ion batteries (LIBs),Metal-assisted chemical etching (MACE),Nanoparticle emissions,Silicon nanowires (SiNWs)
更新于2025-09-23 15:23:52
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The upconversion photoluminescence and temperature sensing abilities of Pb(Zn1/3Nb2/3)O3-9PbTiO3 crystals induced by Er3+/Yb3+ doping
摘要： Er3+/Yb3+-doped Pb(Zn1/3Nb2/3)O3-9PbTiO3 ferroelectric crystals were grown by the high-temperature solution method. The micromorphology, phase structure, and upconversion photoluminescence of obtained crystals were analyzed and investigated. As the results suggest, the crystals displayed typical lamellar growth and possessed a pure perovskite structure. Excited by a 980 nm laser, the characteristic upconversion (UC) emissions of Er3+ were observed at room temperature. The luminescence intensity improved with the increasing of excitation power and reached its maximum at 1056 mW. Two-photon process was demonstrated at lower power range. As the temperature increased from 213 to 493 K, the luminescence intensity weakened continuously. An apparent difference in variation trend between two thermally coupled levels (2H11/2 and 4S3/2) was also observed, which was ascribed to the redistribution of electrons at two levels at the heating process. Based on this dependence, the temperature sensing abilities were examined with the help of the fluorescence intensity ratio (FIR) technique. The absolute sensitivity SA increased in the measurement temperature range and its maximum of 0.0033 K-1 was obtained at 493 K. Moreover, low conversion from incident light into heat was also demonstrated, which indicates the feasibility for crystal luminescence at high power pumping. These results make Er3+/Yb3+-doped Pb(Zn1/3Nb2/3)O3-9PbTiO3 crystals become a promising candidate in optical devices and temperature sensors.
关键词： Two-photon process,Temperature sensing,FIR technique,Ferroelectric crystals,UC emissions
更新于2025-09-23 15:23:52
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The impact of out of band emissions: A measurement based performance comparison of UF-OFDM and CP-OFDM
摘要： Long Term Evolution (LTE) networks, along with their recent releases, rely on the cyclic prefix orthogonal frequency division multiplexing (CP-OFDM) waveform as the foundation. However, high sidelobes, synchronization problems and spectral efficiency constraints of CP-OFDM cannot meet future requirements of cellular network design targets. At this point, universal filtered orthogonal frequency division multiplexing (UF-OFDM) emerges as a strong candidate. Equipped with the advantages of using filters, UF-OFDM provides additional design flexibility to address the fundamental problems of CP-OFDM. In this study, the effect of adjacent channels that causes interference between different frequency channels because of out-of-band (OoB) emissions on UF-OFDM performance is investigated by performing real-time tests on software defined radio (SDR) nodes with multiple reception paths. Frequency domain carrier frequency offset (CFO) and symbol timing offset (STO) correction techniques are used. By the application of the same correction approaches to CP-OFDM, these two waveforms are evaluated in terms of signal to noise ratio (SNR), bit/symbol error rate (BER/SER) and error vector magnitude (EVM). Test results indicate that, based on lower OoB emissions, UF-OFDM uses the spectrum more efficiently and provides better results than CP-OFDM in congested environments.
关键词： synchronization,CP-OFDM,out-of-band emissions,software defined radio nodes,UF-OFDM
更新于2025-09-23 15:23:52
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Rela??es empíricas entre características dendrométricas da Caatinga brasileira e dados TM Landsat 5
摘要： The objective of this work was to adjust models to estimate dendrometric characteristics of the Brazilian dry tropical forest (Caatinga) from Landsat 5 TM sensor data. Measures for tree diameter and height were taken in 60 inventory plots (400 m2), in two municipalities of the state of Sergipe, Brazil. Basal area and wood volume were estimated using an allometric equation and form factor (f = 0.9). Explanatory variables were taken from the TM sensor, after radiometric and geometric correction, having considered, in the analysis, six spectral bands, with 30 m spatial resolution, besides the indexes of simple ratio (SR), of normalized difference vegetation (NDVI), and of soil-adjusted vegetation (Savi). To choose the best explanatory variables, the coefficient of determination (R2), the root mean square error (RMSE), and the Bayesian information criterion (BIC) were considered. The basal area per hectare did not show a significant correlation with any of the explanatory variables used. The best models were adjusted to tree mean height per plot (R2 = 0.4; RMSE = 13%) and to wood volume per hectare (R2 = 0.6; RMSE = 42%). The metrics derived from the Landsat 5 TM sensor have great potential to explain variation in the mean height of trees and in the wood volume per hectare, in remaining areas of the tropical dry forest in the Brazilian Northeast.
关键词： Savi,REDD,vegetation index,reducing emissions,remote sensing,NDVI
更新于2025-09-23 15:22:29
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Simultaneously enhanced far-red luminescence and thermal stability in Ca3Al4ZnO10:Mn4+ phosphor via Mg2+ doping for plant growth lighting
摘要： Non-rare-earth-based Ca3Al4ZnO10:Mn4+,Mg2+ (CAZO:Mn4+,Mg2+) phosphors with admirable luminescence performance and great potential as far-red light source for plant growth light-emitting diodes (LEDs) were reported in this paper. The concentration-dependent optical properties of the as-prepared phosphors were investigated in detail. Under ultraviolet-light excitation at 358 nm, the composition-optimized CAZO:0.4%Mn4+,14%Mg2+ phosphor showed an intense broad far-red emission band in the 625-830 nm wavelength range with a maximum at 714 nm, which was due to the 2Eg→4A2g transition of Mn4+ ions. The luminescence intensity of the CAZO:0.4%Mn4+,14%Mg2+ phosphor was about 1.82 times higher than that of CAZO:0.4%Mn4+ phosphor, and the corresponding mechanism for the luminescence enhancement via Mg2+ doping was studied. Amazingly, the internal quantum efficiency of the CAZO:0.4%Mn4+ phosphor was increased from 31 to 60% after co-doping 14 mol% Mg2+. The CAZO:0.4%Mn4+,14%Mg2+ phosphor also showed enhanced thermal stability compared with the CAZO:0.4%Mn4+ counterpart. It was found that, for CAZO:0.4%Mn4+,14%Mg2+ phosphor, the emission intensity at 423 K (150 oC) was about 51% of that at 303 K (30 oC), while the corresponding activation energy was determined to be 0.245 eV.
关键词： thermal stability,plant growth,phytochrome,far-red emissions,LEDs.,Mn4+ ions
更新于2025-09-23 15:22:29
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Differential Column Measurements Using Compact Solar-Tracking Spectrometers
摘要： We demonstrate the use of compact solar-tracking Fourier transform spectrometers (Bruker EM27/SUN) for differential measurements of the column-averaged dry-air mole fractions of CH4 and CO2 within urban areas. Using Allan variance analysis, we show that the differential column measurement has a precision of 0.1% for XCO2 and XCH4 using an optimum integration time of 10 min, which corresponds to standard deviations of 0.04 ppm, and 0.2 ppb, respectively. The sensor system is very stable over time and after relocation across the continent. We report tests of the differential column measurement, and its sensitivity to emission sources, by measuring the downwind minus upwind column gradient ?XCH4 across dairy farms in the Chino California area and using the data to verify emissions reported in the literature. Spatial column gradient ratios ?XCH4/?XCO2 were observed across Pasadena within the Los Angeles basin, indicating values consistent with regional emission ratios from the literature. Our precise, rapid measurements allow us to determine significant short-term variations (5-10 minutes) of XCO2 and XCH4, and to show that they represent atmospheric phenomena. Overall, this study helps establish a range of new applications for compact solar-viewing Fourier transform spectrometers. By accurately measuring the small differences in integrated column amounts across local and regional sources, we directly observe the mass loading of the atmosphere due to the influence of emissions in the intervening locale. The inference of the source strength is much more direct than inversion modeling using only surface concentrations, and less subject to errors associated with small-scale transport phenomena.
关键词： compact solar-tracking spectrometers,urban emissions,differential column measurements,CH4,CO2
更新于2025-09-23 15:21:21
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Assessing the Effect of Incentive Policies on Residential PV Investments in Colombia
摘要： As the cost of solar photovoltaic (PV) falls, their potential for transforming modern electricity generation increases. Solar PV provides a simpler way of producing clean and affordable energy, which makes it an attractive investment. Great investments in solar PV have occurred in industrialized countries, but government efforts to promote this technology have not been effective in nonindustrialized countries. Despite this, some of these countries may have a high solar PV potential, such as Colombia, where policies to encourage solar PV are only just starting to take place. Therefore, this paper proposes a simulation model to assess different policies—feed-in tariff, net metering, and capital subsidy—to promote solar PV investments in the Colombian residential sector. Policies are assessed considering the criteria of efficiency and effectiveness. Simulation results suggest that (i) net metering is the most efficient policy with a cost indicator of 20,298 USD/MW; (ii) feed-in tariff is the most effective policy as it reaches the highest level of avoided CO2 emissions—4,792,823 million tons of CO2—and a meaningful PV installed capacity of 7522 MW; (iii) capital subsidy is the least efficient policy as it has the highest cost indicator of 509,616 USD/MW.
关键词： net metering,feed-in tariff,capital subsidy,PV adoption,effectiveness,CO2 emissions,efficiency
更新于2025-09-23 15:21:21
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Photovoltaic Solar Energy: Is It Applicable in Brazil? a?? A Review Applied to Brazilian Case
摘要： The photovoltaic technologies have been developed year by year in different countries; however, there are some countries where this kind of energy is being born, such as the Brazilian case. In this paper, some important parameters are analysed and applied to different solar cell materials, identifying that if the fossil fuels were substituted by solar cells, it would reduce the CO2 emissions by 93.2%. In addition, it is shown that the efficiency of solar cells is not as farther as it could be thought from coal thermoelectrical plants in Brazil and the cost of energy using solar cells could be as good as these thermoelectrical plants. Finally, the potentiality of Brazilian territory to implant this technology is presented, identifying that with the use of 0.2% of the territory, the energy demand could be supplied.
关键词： Brazil,CO2 Emissions,Thermoelectrical plants,Solar cells,Fossil fuels
更新于2025-09-23 15:21:01
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Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor
摘要： The development of phosphor materials with outstanding photoluminescence properties is critical for next-generation high-quality solid-state white lighting. As there is a blue-green cavity existed in the emission spectra of the traditional phosphor-converted white-light-emitting diodes (w-LEDs), cyan-emitting phosphor serves an important function in compensating the spectral gap to realize the “full-visible-spectrum lighting”. Herein, we reported the discovery of an efficient cyan-emitting Ce3+-doped Ca2YHf2Al3O12 (CYHAO) garnet phosphor with good thermal stability. The as-prepared CYHAO:Ce3+ phosphor exhibited a broad excitation band in the range of 360 to 460 nm with a maximum at 408 nm, making this phosphor compatible with an efficient 400 nm NUV-emitting LED chip. Under the 408 nm excitation, the optimal sample of CYHAO:0.03Ce3+ exhibited bright broadband cyan emission (λem = 493 nm; bandwidth = 100 nm) together with extra-high internal quantum efficiency (IQE) of 89.5% and external quantum efficiency (EQE) of 69.1%. Notably, the as-prepared CYHAO:0.03Ce3+ phosphor showed good thermal stability (64.2% of emission intensity retained at 423K) and excellent color stability when working in the temperature range of 303-463 K. Importantly, the constructed w-LED device exhibited bright well-distributed warm white light with high color rendering index (CRI; Ra = 93.5 and R12 = 90.4) and low correlated color temperature (3700 K) under 60 mA driven current, indicating that the title cyan phosphor can be utilized as the compensation of the blue-green cavity to apply in full-visible-spectrum lighting. Furthermore, these findings provide new insights into exploring high-performance cyan phosphors for NUV-pumped high-CRI warm w-LEDs.
关键词： White LEDs,Color rendering index,Cyan emissions,Phosphors,Full-visible-spectrum lighting
更新于2025-09-23 15:21:01