研究目的
Investigating the in situ growth of whole-family CsPbX3 (X = Cl, Br, and I) perovskite quantum dots in Zn–P–B–Sb based oxide glass for improved stability and tunable visible full-spectral emissions.
研究成果
The successful nanocrystallization of CsPbX3 within the glass matrix and the realization of intense exciton emission from QDs@glass. The as-prepared nanocomposites exhibit superior thermal stability and moisture resistance, suggesting promising applications in optoelectronics fields.
研究不足
The PLQY values are relatively low compared with those of colloidal QDs, probably owing to the existence of defect states in QDs produced by high-temperature crystallization as well as the influence of interface defects between QDs and the glass matrix.
1:Experimental Design and Method Selection:
The in situ growth of CsPbX3 QDs in Zn–P–B–Sb based oxide glass via a melt-quenching route and subsequent crystallization.
2:Sample Selection and Data Sources:
Glass matrices with molar compositions of
3:3Zn(PO3)2–4H3BO3–15Sb2O3–7BaCO3–5Na2CO3 and added perovskite-related components Cs2CO3–PbX2–KX (X = Cl, Br, and I). List of Experimental Equipment and Materials:
Muffle furnace, corundum crucibles, water-cooled copper mold, powder diffractometer (MiniFlex600 RIGAKU), transmission electron microscope (JEOL JEM-2010), spectrofluorometer (Edinburgh Instruments FS5), fluorescence lifetime spectrometer (Edinburgh Instruments, LifeSpec-II).
4:Experimental Procedures and Operational Workflow:
Mixing and grinding raw materials, sintering in a muffle at 800°C, pouring into a water-cooled copper mold, heat treatment at 300–400°C for 2 h.
5:Data Analysis Methods:
XRD for phase structure, TEM for microstructure, PL and PLE spectra for optical properties, time-resolved spectra for lifetime analysis.
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powder diffractometer
MiniFlex600
RIGAKU
X-ray diffraction analysis to identify the crystallized phase structure of the as-prepared samples.
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transmission electron microscope
JEM-2010
JEOL
Microstructural observation of QDs@glass.
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spectrofluorometer
FS5
Edinburgh Instruments
Recording PL, PL excitation (PLE) spectra and two-dimensional excitation–emission mapping.
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fluorescence lifetime spectrometer
LifeSpec-II
Edinburgh Instruments
Recording time-resolved spectra of CsPbX3 QDs@glass samples.
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spectroradiometer
HAAS-2000
Everfine
Measuring photoelectric parameters of the LED devices.
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