研究目的
To develop a simple synthetic 0D–2D heterogeneous material with more efficient photocatalytic degradation by constructing acetylene black (AB) as a bridge to connect a graphitic carbon nitride (g-C3N4) nano-layer and two-dimensional MoS2 sandwich structure.
研究成果
The ternary g-C3N4/AB/3.1%MoS2 photocatalyst shows high photocatalytic activity and stability, with a degradation rate of 94.29% for methyl blue within 130 min. The AB phase plays a key role in promoting electron transport and reducing charge carrier recombination, making the material a promising solution for environmental applications.
研究不足
The study does not address the scalability of the synthesis method for industrial applications or the long-term stability of the photocatalytic materials under various environmental conditions.
1:Experimental Design and Method Selection:
The study employs a simple hydrothermal synthesis and ultrasonic chemical loading method to construct the ternary heterogeneous material.
2:Sample Selection and Data Sources:
The samples include pure g-C3N4, MoS2, and their composites with AB.
3:List of Experimental Equipment and Materials:
Instruments include X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR) spectra, UV–vis diffused reflectance spectra (DRS), photoluminescence (PL) spectra, scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray analyzer (EDX), cyclic voltammetry analysis, and BET surface area measurements.
4:Experimental Procedures and Operational Workflow:
The synthesis involves dissolving thiourea and urea in deionized water, drying, heating, and annealing to obtain g-C3N4 nanosheets. MoS2 nanosheets are prepared by dissolving sodium molybdate and thiourea in deionized water, heating, centrifuging, and drying. The ternary composite is prepared by dissolving g-C3N4 in deionized water, adding MoS2 and AB, sonicating, and drying.
5:Data Analysis Methods:
The photocatalytic performance is evaluated by the degradation rate of methyl blue solution under visible light illumination.
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X-ray diffraction
Rigaku
Determining the crystal structure of the samples
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X-ray photoelectron spectroscopy
Thermo ESCALAB 250Xi
Analyzing the chemical composition and valence states of the composites
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Fourier transform infrared spectrophotometer
Nicolet, 6700
Obtaining FT-IR spectra of the samples
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UV–vis spectrophotometer
Shimadzu UV-2600
Obtaining UV–vis diffused reflectance spectra of the samples
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Fluorescence Spectrophotometer
Agilent Cary Eclipse
Obtaining photoluminescence spectra of the samples
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Scanning electron microscopy
Zeiss Supra 40
Measuring the morphology of the obtained samples
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Transmission electron microscopy
JEM2100UHR
Observing TEM and HRTEM images
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Energy dispersive X-ray analyzer
Elemental identification and quantitative compositional information
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Electrochemical workstation
CHI660A
Obtaining cyclic voltammetry analysis
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BET surface area measurement
Quadrasorb EVO
Quantachrome Instruments
Measuring BET surface areas
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