研究目的
To demonstrate the broadband visible organic photodetectors (OPDs) by introducing a non-fullerene acceptor of ITIC into the bulk heterojunction (BHJ) based on a conventional system of P3HT:PC71BM, aiming to broaden the long wavelength detective spectrum and achieve high-performance broadband visible OPDs.
研究成果
The introduction of ITIC into the P3HT:PC71BM system effectively broadens the photodetection range to cover the full visible spectrum (380–760 nm). The optimized OPDs exhibit high detectivity, attributed to better film morphology, efficient energy transfer, and reduced electron mobility. This approach offers a reliable strategy for high-performance broadband visible OPDs.
研究不足
The study focuses on the introduction of ITIC into the P3HT:PC71BM system to broaden the photodetection range. Potential limitations include the optimization of ITIC ratios for balanced performance and the scalability of the fabrication process.
1:Experimental Design and Method Selection:
The study introduces ITIC into the P3HT:PC71BM BHJ system to form broadband OPDs. UV-Vis absorption spectrum, steady-state photoluminescence, atomic force microscopy, and space-charge-limited current property were applied to analyze the film characteristics.
2:Sample Selection and Data Sources:
Active layer materials include P3HT, PC71BM, and ITIC, with different mass ratios to study their effects on OPD performance.
3:List of Experimental Equipment and Materials:
Equipment includes Shimazu UV1700 UV-Vis spectroscopy system, Hitachi F-7000 PL spectroscopy, AFM 5500, and Keithley 4200 programmable voltage-current source. Materials include ITO, PEDOT:PSS, P3HT, PC71BM, ITIC, Bphen, and Ag.
4:Experimental Procedures and Operational Workflow:
ITO substrates were cleaned and treated with oxygen plasma. PEDOT:PSS was spin-coated, followed by the active layer solutions. Ag was deposited as the anode.
5:Data Analysis Methods:
EQE spectra, responsivity (R), and detectivity (D*) were calculated to evaluate OPD performance.
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