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Picosecond Laser Interference Patterning of Periodical Micro-Architectures on Metallic Molds for Hot Embossing

DOI:10.3390/ma12203409 期刊:Materials 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: In this work, it is demonstrated that direct laser interference patterning (DLIP) is a method capable of producing microtextured metallic molds for hot embossing processes. Three different metals (Cr, Ni, and Cu), relevant for the mold production used in nanoimprinting systems, are patterned by DLIP using a picosecond laser source emitting at a 532 nm wavelength. The results show that the quality and surface topography of the produced hole-like micropatterns are determined by the laser processing parameters, such as irradiated energy density and the number of pulses. Laser-induced periodic surface structures (LIPSS) are also observed on the treated surfaces, whose shapes, periodicities, and orientations are strongly dependent on the accumulated fluence. Finally, the three structured metals are used as embossing molds to imprint microlenses on polymethyl methacrylate (PMMA) foils using an electrohydraulic press. Topographical profiles demonstrate that the obtained structures are comparable to the masters showing a satisfactory reproduction of the texture. The polymeric microlens arrays that showed the best surface homogeneity and overall quality were those embossed with the Cr molds.
作者: Yangxi Fu,Marcos Soldera,Wei Wang,Bogdan Voisiat,Andrés Fabián Lasagni
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To optimize the microstructuring process of metallic molds using four-beam laser interference patterning to produce 'hole-like' periodic arrays with higher surface-area-to-volume ratios than the simpler 'line-like' grooves achieved by two-beam DLIP and to find a replacement for Ni molds to improve worker health and safety.

Direct laser interference patterning is capable of producing Cr, Ni, and Cu molds for nanoimprinting systems. Using pulsed ps-laser radiation with optimized processing parameters, hole-like micropatterns with satisfactory quality and homogeneity were produced on those metal substrates. The laser induced microstructures on the three metals were replicated on PMMA foils using a hot embossing process. When Cr was used as mold material, the results showed a reliable reproduction of homogenously distributed hemispherical microlenses.

The multi-pulse ablation process involves different effects such as melting, recrystallization, quenching, native oxide layer formation involving exothermic processes, defect generation and phase transformation, that can result in unexpected structure depth dependences with the number of pulses and fluence as well as modified mechanical properties of the final structured surface.

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