研究目的
Investigating the regeneration kinetics of the boron–oxygen defect in boron-doped p-type Czochralski-grown silicon (Cz-Si) solar cells as a function of the excess carrier concentration Δn at the regeneration conditions.
研究成果
The experimental results show a proportional increase of the regeneration rate constant Rde with the excess carrier concentration Δn during the regeneration process, confirming the previously proposed defect model of the regeneration process.
研究不足
The study is limited to boron-doped p-type Czochralski-grown silicon solar cells under specific regeneration conditions (elevated temperature and forward-bias voltage). The variation in Δn during the regeneration process is smaller than 10%, which is considered almost constant but may affect the precision of the results.
1:Experimental Design and Method Selection:
The regeneration process is examined by performing parallel EL and current–voltage (I-V) measurements on passivated emitter and rear cells (PERCs) fabricated on boron-doped Cz-Si wafers.
2:Sample Selection and Data Sources:
3:6 × 6 cm2 PERCs were laser cut into 5 × 5 cm2 cells, with a centrally arranged busbar. List of Experimental Equipment and Materials:
Setup for in situ measurements of the cell current Icell and the EL intensity ΦEL, Si-CCD camera (Sensicam QE, PCO), LOANA tool (pv-tools GmbH).
4:Experimental Procedures and Operational Workflow:
Solar cells were characterized in the fully degraded state, then embedded into a mounting bracket, and put on a precision hot plate. After reaching thermal equilibrium, a forward-bias voltage Vappl was applied, and EL and I-V measurements were carried out.
5:Data Analysis Methods:
The regeneration kinetics was analyzed by monoexponential fitting to the measured data to determine the regeneration rate constant Rde.
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