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Green and red phosphor for LED backlight in wide color gamut LCD

DOI:10.1016/j.jre.2019.10.005 期刊:Journal of Rare Earths 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: Wide color gamut (WCG) backlight for liquid crystal display (LCD) utilizing white light-emitting diodes (LED) has attracted considerable attention for their high efficiency and color reduction. In this review, recent developments in crystal structure, luminescence and applications of phosphors for wide color gamut LED backlight are introduced. As novel red phosphors, Mn4+ activate fluoride and aluminate phosphors are advanced in quantum efficiency, thermal quenching and color saturation for their characteristic spectrum with broad excitation band and linear emission. The crystal structure and fluorescence properties of Mn4+ doped fluosilicate, fluorogermanate, fluotitanate, as well as Sr4Al14O25, CaAl12O19 and BaMgAl10O17 phosphors are discussed in detail. A serial of narrow-band red-emitting Eu2+, Eu3+ and Pr3+-doped nitride silicates and molybdate phosphors are also introduced. Rare-earth-doped oxynitride and silicate green-emitting phosphors have attracted more and more attention because of the wide excitation, narrow emission, high quenching temperature, high quantum efficiency, such as β-sialon:Eu2+, Ba3Si6O12N2:Eu2+, MSi2O2N2:Eu2+ (M=Ca, Sr, Ba), γ-AlON: Mn2+ and Ca3Sc2Si3O12:Ce3+. All above phosphors demonstrate their adaptability in wide color gamut LCD display. Especially for Mn4+ doped fluosilicate red phosphor and β-sialon: Eu2+ green phosphor. To achieve an ultra-high color gamut in white LED backlight and against the OLED, innovative narrow-band emission red and green phosphor materials with independent intellectual property rights are continuously pursed.
作者: Yunpeng Zhang,Lin Luo,Guantong Chen,Yuanhong Liu,Ronghui Liu,Xiaochun Chen
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To review recent developments in crystal structure, luminescence, and applications of phosphors for wide color gamut LED backlight, focusing on novel red and green phosphors for LCD displays.

The review highlights the importance of developing narrow-band emission phosphors for wide color gamut LCD displays. Mn4+ doped fluoride and aluminate red phosphors, along with rare-earth-doped oxynitride and silicate green phosphors, show promise for high-efficiency, high-color-saturation LED backlights. However, challenges such as thermal and moisture resistance in fluoride phosphors and the need for high luminous efficiency in aluminate phosphors remain.

The paper does not discuss specific experimental procedures or data analysis methods in detail, as it is a review article summarizing existing research.

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