研究目的
To improve the device efficiency of thin film photovoltaic devices through surface texturing based light trapping technologies, including the use of textured hydrogenated ZnO:Al films as transparent conducting oxide (TCO) electrodes, nanostructured materials, silicon nitride as an index matching layer, and metal nanoparticles for plasmonic light trapping.
研究成果
The research demonstrated that textured ZnO:Al:H thin films, silicon nitride as an index matching layer, and metal nanoparticles for plasmonic light trapping effectively improve the efficiency of photovoltaic devices. However, silicon nanowires need further optimization to enhance their application in solar cells due to issues like gold impurities acting as recombination centers.
研究不足
The study notes that while textured TCO, index matching layers, and plasmonic nanoparticles improve device efficiency, nanowires-based devices require further optimization for higher efficiency. The presence of gold impurities in silicon nanowires acts as charge recombination centers, reducing device conversion efficiency.
1:Experimental Design and Method Selection:
The study involved the deposition of hydrogenated ZnO:Al films by pulsed dc magnetron sputtering, texturization using wet chemical etching, and characterization using XRD, AFM, and spectrophotometry. Silicon nitride films were deposited using RF-PECVD, and silicon nanowires were grown using PECVD with Au as a seed layer. Metal nanoparticles were deposited via thermal evaporation.
2:Sample Selection and Data Sources:
Samples included hydrogenated ZnO:Al films on glass and silicon substrates, silicon nitride films on glass substrates, and silicon nanowires on ZnO:Al coated quartz substrates.
3:List of Experimental Equipment and Materials:
Pulsed dc magnetron sputtering unit, RF-PECVD system (OXFORD Plasma Lab System-100), spectrophotometer (Perkin-Elmer-UV/VIS Lambda 750), integrating sphere (600 nm Lab-Sphere), four probe method for resistivity measurement, SEM and XRD for characterization.
4:Experimental Procedures and Operational Workflow:
Detailed procedures included film deposition, texturization, optical and structural characterization, nanowire growth, and solar cell fabrication and testing.
5:Data Analysis Methods:
Optical properties were analyzed using spectrophotometry, structural properties via XRD and AFM, and device performance through I-V measurements under simulated AM1.5 spectrum.
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