研究目的
To develop a D-shaped optical fiber-based sensor for detecting plumbum ions in aqueous solutions using surface plasmon resonance (SPR) with a FiberBench rotating wave plate for enhanced sensitivity and accuracy.
研究成果
The developed D-shaped optical fiber SPR sensor demonstrated high sensitivity and accuracy in detecting Pb2+ ions in aqueous solutions, with a limit of detection of 0.3 ppb. The use of a FiberBench rotating wave plate allowed for control over the SPR curve's depth and width, enhancing sensor performance.
研究不足
The study focused on static water environments and may require further validation in dynamic conditions. The sensor's performance at concentrations below 0.3 ppb was not detectable.
1:Experimental Design and Method Selection:
The study utilized a D-shaped optical fiber SPR setup with a polarization controller to enhance sensor performance. The SPR effect was leveraged to detect Pb2+ ions in water.
2:Sample Selection and Data Sources:
Different concentrations of Pb2+ ions in aqueous solutions were prepared and tested. The sensing layer was a nanocomposite of reduced graphene oxide (rGO) and maghemite (Fe2O3) with EDC/NHS crosslink.
3:List of Experimental Equipment and Materials:
Equipment included a white light source (Avantes), FiberBench model FB-51 (Thorlabs), D-shaped fiber (Phoenix Photonics), and a spectrometer (AvaSpec-ULS2048L-USB2-UA-RS Avantes). Materials included rGO/Fe2O3 nanocomposite and EDC/NHS.
4:Experimental Procedures and Operational Workflow:
The D-shaped fiber was coated with Au and the sensing layer. The transmission response curves were analyzed for wavelength and intensity shifts at different Pb2+ concentrations.
5:Data Analysis Methods:
Sensitivity and accuracy were calculated based on wavelength shifts and full-width-half maximum (FWHM) of the SPR curve.
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