研究目的
Investigating the influence of graphene on the optical properties of CdSe quantum dots for potential applications in photoelectric devices.
研究成果
The coupling of CdSe quantum dots with graphene sheets enhances the photocurrent generation and retards electron-hole recombination, making the nanocomposites suitable for photovoltaic applications. The graphene sheets influence the optical properties by decreasing the growth rate of quantum dots, enhancing size distribution, and increasing the stokes shift.
研究不足
The study focuses on the optical properties and does not extensively explore the electrical or thermal properties of the nanocomposites. The synthesis process requires precise control of conditions, which may limit scalability.
1:Experimental Design and Method Selection:
The study involved the synthesis of CdSe quantum dots and their nanocomposites with graphene through thermal decomposition of organometallic complexes. The synthesis was performed both in the absence and presence of graphene to study its effects.
2:Sample Selection and Data Sources:
Natural graphite powder and other chemicals of analytical grade were used. The samples were characterized using X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and UV/visible spectrophotometry.
3:List of Experimental Equipment and Materials:
Perkin Elmer Lambda 40 double beam spectrophotometer, PerkinElmer LS55 Spectro?uorometer, X’Pert Philips Materials Research diffractometer, Joel JEM-2100 electron microscope.
4:Experimental Procedures and Operational Workflow:
The synthesis involved dissolving CdO in oleic acid, mixing with oleylamine and TOPO, and injecting Se in TOP under vigorous stirring. Reduced graphene oxide was dispersed into oleylamine for nanocomposite preparation.
5:Data Analysis Methods:
The optical properties were analyzed using absorption and emission spectra, with particle size distribution and stokes shift calculated from the data.
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