研究目的
Investigating the photochemical reactions of Bis(cyclopentadienyl)dicarbonyl titanium (TiCp2(CO)2) in solid nitrogen and argon matrices using infrared spectroscopy and density functional theory calculations.
研究成果
UV-photolysis of TiCp2(CO)2 in a N2 matrix produces nitrogen-containing compounds, with TiCp2(N2)2 being the most stable product. Theoretical calculations support the experimental findings.
研究不足
The cage effect in Ar matrix limits the yield of TiCp2(CO). The study is limited to low-temperature matrix conditions.
1：Experimental Design and Method Selection:
UV-photolysis of TiCp2(CO)2 in Ar and N2 matrices at 18 K, followed by infrared spectroscopy.
2：Sample Selection and Data Sources:
TiCp2(CO)2 was isolated in Ar or N2 matrices.
3：List of Experimental Equipment and Materials:
Closed cycle refrigerator, FT-IR spectrometer, super high-pressure mercury lamp.
4：Experimental Procedures and Operational Workflow:
UV-irradiation at 270-390 nm, annealing at 30 K, measurement of IR spectra.
5：Data Analysis Methods:
Comparison with theoretical calculations using mPW2PLYP/cc-pVTZ.
独家科研数据包，助您复现前沿成果，加速创新突破
获取完整内容
