研究目的
Investigating carbon distribution and precipitation in directional solidification of multicrystalline silicon for photovoltaic applications.
研究成果
The formation of SiC precipitates can be avoided if the initial content of carbon in the silicon melt is below the solubility limit. Samples can be grown at high growth rates without forced convection, since the carbon precipitation rate increases only at the end of the growth process.
研究不足
The study is limited by the assumptions made in the numerical model, such as neglecting random variations of the growth rate during the solidification process and the unknown CO content of the gas atmosphere in VGF experiments.
1:Experimental Design and Method Selection:
Numerical modeling using COMSOL Multiphysics to solve heat transfer, momentum, and species equations for an axisymmetric domain.
2:Sample Selection and Data Sources:
Silicon ingots of 6 cm diameter and 4 cm length grown in open fused silica crucibles at different growth rates.
3:List of Experimental Equipment and Materials:
Vertical Bridgman Freezing (VGF) system, fused silica crucibles.
4:Experimental Procedures and Operational Workflow:
Steady-state simulations followed by transient computations using a deformable mesh technique.
5:Data Analysis Methods:
Comparison of numerically computed concentration profiles to experimental results to estimate unknown parameters.
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