研究目的
To provide a comprehensive understanding of the luminescent nature of copper nanoclusters (CuNCs), detail the synthetic protocols and templates used for their synthesis, discuss characterization techniques, and highlight their applications as next-generation fluorophores.
研究成果
CuNCs can serve as next-generation fluorophores with applications in sensing, bio-imaging, and nano-thermometry. Despite challenges like stability and quantum yield, rational use of templates and synthetic protocols can lead to stable CuNCs with specific atomic compositions and versatile applications.
研究不足
The propensity of CuNCs to undergo oxidation and the limitations in controlling their ultra-fine size make them less stable compared to other noble metal NCs. Additionally, the quantum yields of CuNCs are generally lower than those of Au/Ag counterparts.
1:Experimental Design and Method Selection:
The chapter reviews various synthetic approaches for CuNCs, including top-down and bottom-up methods, and the use of different templates like proteins, DNA, thiols, and polymers.
2:Sample Selection and Data Sources:
The synthesis involves the reduction of copper ions to atoms followed by their aggregation into clusters, stabilized by various templates.
3:List of Experimental Equipment and Materials:
Includes spectrofluorimeters for steady-state spectroscopy, transmission electron microscopy (TEM) for morphological characterization, and MALDI-TOF mass spectrometry for determining the chemical composition of NCs.
4:Experimental Procedures and Operational Workflow:
Detailed protocols for synthesizing CuNCs using different templates are provided, including conditions like temperature, pH, and reaction times.
5:Data Analysis Methods:
Emission spectroscopy is used to study the luminescent properties, TEM for size and shape analysis, and MALDI-TOF for composition analysis.
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