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Resonant Metagratings for Spectral and Angular Control of Light for Colored Rooftop Photovoltaics

DOI:10.1021/acsaem.0c00027 期刊:ACS Applied Energy Materials 出版年份:2020 更新时间:2025-09-19 17:13:59
摘要: We design semi-transparent metagrating supercells that enable control over the spectrum and directivity of incident light for applications in photovoltaics with tailored angular appearance. The building block of the supercells is a 110-120 nm wide and 175 nm tall silicon nanowire that shows a strong Mie resonance around λ= 650 nm. By arranging the resonant Mie scatterers into metagratings of increasing pitch (675-1300 nm) we create a Lambertian-like scattering distribution over an angular range of choice. The millimeter-sized metasurfaces were fabricated using electron beam lithography and reactive ion etching. The fabricated metasurface nearly fully suppress specular reflection on resonance while 10% of the incoming light around the resonance is scattered into the angular range between 30-75°, creating a bright red appearance over this specific range of angles. Off-resonant light in the blue, green and near-infrared is efficiently transmitted through the metasurface and absorbed in the underlying photovoltaic cell. The implemented silicon heterojunction solar cells with integrated metagrating supercells show a reduction in external quantum efficiency matching the resonant scattering spectral range. The short circuit current is reduced by 13% due to the combined effects of resonant scattering, reflection from the high-index substrate and absorption in the Si nanowires. In addition, to efficient colorful photovoltaics with tailored angular appearance, the metagrating concept can find application in many other light management designs for photovoltaics and other opto-electronic devices.
作者: Floris Uleman,Verena Neder,Andrea Cordaro,Andrea Alù,Albert Polman
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Investigating the use of resonant metagratings for spectral and angular control of light in colored rooftop photovoltaics to achieve tailored angular appearance and high efficiency.

The study successfully demonstrates the use of resonant metagratings for spectral and angular control of light in photovoltaics, achieving a bright red appearance over a specific angular range with minimal efficiency loss. The concept holds promise for applications in building-integrated photovoltaics and other opto-electronic devices.

The study is limited by fabrication imperfections leading to slightly different dimensions of silicon nanowires and small slanting of sidewalls, which may affect the resonance properties. Additionally, the design is optimized for one polarization direction and could be expanded to two dimensions for broader applications.

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