研究目的
To develop high-performance, low-cost, and environmentally-friendly white light-emitting diodes (WLEDs) using quantum dots (QDs) and carbon quantum dots (CDs) nanocomposites.
研究成果
The study successfully synthesized white-light-emitting AIS-CDs nanocomposites with a core-shell structure, demonstrating high stability and a PLQY of 35%. The corresponding WLEDs showed a color coordinate close to pure white light and a luminous efficiency of 15.1 lm W-1, indicating potential for high-performance, low-cost, and eco-friendly WLEDs.
研究不足
The study focuses on the synthesis and initial characterization of AIS-CDs nanocomposites for WLEDs. Further optimization and scalability for commercial applications may be required.
1:Experimental Design and Method Selection:
The study involves the synthesis of core–shell structure nanocomposites based on Ag-In-S/ZnS@SiO2 quantum dots (AIS@SiO2) and carbon quantum dots (CDs) to overcome the quenching effect of CDs.
2:Sample Selection and Data Sources:
AIS QDs and CDs are prepared according to previous works.
3:List of Experimental Equipment and Materials:
Includes silver nitrate, sodium sulfide hydrate, Indium(III) chloride, NH4OH, zinc(II) acetate dihydrate, glutathione, ethylenediamine, 2-propanol, ethanol, 3-aminopropyltriethoxysilane (APTES), Poly (methyl methacrylate) (PMMA), citric acid (CA) and tetraethyl orthosilicate (TEOS).
4:Experimental Procedures and Operational Workflow:
The synthesis involves three sequential steps: preparation of AIS QDs and CDs, preparation of AIS@SiO2 composites, and synthesis of AIS-CDs composites by electrostatic adsorption.
5:Data Analysis Methods:
The optical properties were characterized by PL and absorption spectra, TEM, HRTEM, XRD, XPS, FTIR, and fluorescence lifetimes measurements.
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Shimadzu UV-2600 spectrophotometry
UV-2600
Shimadzu
Obtaining absorption spectra
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JEOL JEM 2100 microscope
JEM 2100
JEOL
Recording TEM and HRTEM images
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Shimadzu/6100 X-ray diffractometer
6100
Shimadzu
Acquiring XRD patterns
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Fluorescence spectrofluorometer
F-7000
Hitachi
Measuring fluorescence lifetimes
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Varian Cary Eclipse instrument
Varian
Obtaining PL and absorption spectra
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X-ray photoelectron spectroscopy (XPS)
ESCA Lab220I-XL
Obtaining XPS spectra
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Fourier transform infrared (FTIR) spectrophotometer
IRPrestige-21
Collecting FTIR spectra
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Edinburgh ?uorescence spectrometer
FS 5
Carrying out PLQY measurements
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PR-670 Spectra Scan spectrophotometer
PR-670
Characterizing WLEDs
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