研究目的
Developing color stable luminescent materials to avoid the color drift of WLED at high temperature.
研究成果
The phosphor YTaO4:Bi3+ exhibits stable blue emission upon ultraviolet excitations and can achieve white emission under specific excitation schemes. This work demonstrates the potential for single phase white emitting phosphors activated by a single ion of Bi3+ for WLEDs with high chromatic stability.
研究不足
The study focuses on the development of a single phase white emitting phosphor activated by Bi3+ for WLEDs, but the practical application in high power pc-WLEDs may require further optimization for temperature stability and efficiency.
1:Experimental Design and Method Selection:
The samples Y1-xTaO4: xBi3+ were synthesized by conventional solid state reactions at high temperature. The starting materials were Y2O3, Ta2O5, and Bi2O
2:The raw powders with stoichiometric molar ratios were mixed and milled thoroughly, then sintered at 1573 K for 6 h in air. Sample Selection and Data Sources:
The samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscope (FESEM), and photoluminescence (PL) spectra.
3:List of Experimental Equipment and Materials:
Bruker D8 advance powder diffractometer, Kratos Axis Ultra DLD spectrometer, Zeiss Sigma 500 FESEM, Edinburgh Instruments FLS 920 PL spectrometer.
4:Experimental Procedures and Operational Workflow:
The mixtures were sintered and cooled down to room temperature naturally. The products were ground for subsequent measurements.
5:Data Analysis Methods:
The PL spectra were recorded and analyzed for emission properties and thermal quenching behaviors.
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X-ray diffractometer
D8 advance
Bruker
Characterizing the crystal structure and crystallinity of samples
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X-ray photoelectron spectrometer
Axis Ultra DLD
Kratos
Identifying the valence state of Bi
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Field emission scanning electron microscope
Sigma 500
Zeiss
Obtaining surface morphologies and elemental maps of the phosphors
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PL spectrometer
FLS 920
Edinburgh Instruments
Recording static and dynamic PL spectra
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