研究目的
Investigating the removal of humic acid from aqueous solutions using ultraviolet irradiation coupled with hydrogen peroxide and zinc oxide nanoparticles.
研究成果
The UV/ZnO/H2O2 process was the most efficient in removing HA under optimal conditions (HA = 2 mg/L, H2O2 = 50 mg/L, ZnO = 0.2 g/L, pH = 4.0, contact time = 15 min) with an efficiency of 99.99%. The adsorption reaction followed the pseudo-second-order kinetic model.
研究不足
The study focused on batch-scale experiments, and the practical application in continuous flow systems was not explored. The effect of real water matrices on the process efficiency was not investigated.
1:Experimental Design and Method Selection:
The study assessed the individual and combined performance of UV irradiation, ZnO nanoparticles, and H2O2 processes for HA removal. Factors like ZnO concentration, H2O2 concentration, UV power, pH, initial HA concentration, and interferences were studied.
2:Sample Selection and Data Sources:
HA stock solution was prepared from Across Company's HA impure powder.
3:List of Experimental Equipment and Materials:
Spectrophotometer UV/VIS Lambda 25 Perkin Elmer, Metrohm pH meter 827, medium-pressure mercury lamp (125 W), ZnO nanoparticles (6–12 nm) from Isfahan Nano Spadana Company.
4:Experimental Procedures and Operational Workflow:
Batch-scale experiments were conducted in a 1-L cylindrical reactor with UV irradiation, varying parameters like pH, contact time, and concentrations of HA, H2O2, and ZnO.
5:Data Analysis Methods:
Excel software was used for analyzing results, and reaction kinetics were performed to obtain optimum conditions.
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