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Inkless Multi-Color Writing and Copying of Laser-Programmable Photonic Crystals

DOI:10.1039/D0MH00150C 期刊:Materials Horizons 出版年份:2020 更新时间:2025-09-23 15:19:57
摘要: Rewritable papers, as an environmentally friendly alternative for information delivery, hold great promise to reduce the abundant uses of ordinary papers that cause severe environmental problems. In recent decades, photonic crystals (PCs) have shown great potential in developing rewritable papers. However, existing PC papers still confront many challenges, including poor storage stability, short-cycle lifetime, monotonous colors, and absence of copying capability. Herein, we report the fabrication of a rewritable PC paper based on programmable configurations of a synthesized shape memory polymer (SMP). The resulting SMP-based PC paper does not need additional inks and can be facilely written by near infrared (NIR) light with assistance from a pre-printed black paper as a photothermal layer. Heating from the black paper induces various stable configurations of the PCs, thus creating multiple colors in the irradiated areas. Moreover, the PC paper possesses excellent colorful copying capability that can transform information from a paper with pre-printed black letters or complex images via scanning with NIR light. These images can be stably stored for more than 6 months at ambient conditions, which can be even erased and rewritten over 50 times without significant loss in color quality. This environment-friendly SMP-based PC paper with extraordinary properties holds great promise in the fields of next-generation office papers, smart price tags, and anti-counterfeiting labels.
作者: Yunlong Wang,Qilong Zhao,Xuemin Du
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研究概述 实验方案 设备清单

To develop a novel rewritable PC paper based on programmable configurations of a synthesized shape memory polymer (SMP) that can be written and copied using NIR light without additional inks, offering superior stability, long-term durability, and excellent reversibility.

The novel SMP-based PC paper demonstrates unprecedented capabilities of displaying reversible and multi-stable colors simultaneously without inks, stamps, and photothermal agents. It can be applied in the fields of next-generation office papers, smart price tags, anti-counterfeiting labels, etc., which will decrease the consumption of forests and reduce the damage to ecosystems.

The slight color diffusion at the edge of the letters due to the thermal gradient in the film resulted from the high-energy gradient of the laser beam and the manual writing. This issue could be resolved by employing more uniform energy laser or more automated processes.

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