摘要： The gap length between plasmonic nanoparticles determines the strength of the optical coupling that results in electromagnetic field enhancement for spectroscopic and other applications. Although gap plasmon resonances have been the focus of increasing research interest, experimental observations have primarily been limited to the coupling of spherical nanoparticles that may not provide clear spectral contrast of the optical response as the interaction evolves from capacitive to charge transfer with the gap size decreasing to subnanometer. Here, by taking advantage of the sharp plasmon resonances of colloidal gold nanorods coupled to gold film, we present the spectral evolution of gap plasmon resonance as the particle-film spacing varies from over 30 nm to the touching limit. We find that, the capacitive gap plasmon resonance of the coupled system red shifts and narrows continuously until it vanishes at the quantum tunneling limit, in contrast to the nonlocal and Landau damping effects that are expected to result in relative blue shifting and spectral broadening. When the spacer thickness is further decreased, high order cavity modes appear, and eventually single peak broad resonances that are characteristic of tunneling and direct contact particle-film interaction emerge. The experimental observations show that nanorods are better suited for creating cavity plasmon resonances with high quality factor, and the spectral contrast at the transition provides clarity to develop improved theoretical modeling of optical coupling at subnanometer gap lengths.