研究目的
Investigating the method for recovering nonradiative recombination loss in scalable organic solar cells to improve photovoltaic performance.
研究成果
The introduction of ICBA in blade-coating devices effectively reduces nonradiative recombination loss, leading to a recovered voltage and improved photovoltaic performance. This ternary strategy provides a promising approach for upscaling OSCs with reduced efficiency loss.
研究不足
The study focuses on the PBDB-T-2F:IT-4F system with ICBA as a third component, and the findings may not be directly applicable to other material systems. The scalability of the blade-coating process to industrial levels is not fully explored.
1:Experimental Design and Method Selection:
The study employs blade coating and spin coating as fabrication processes for organic solar cells (OSCs) with a conventional device structure. A ternary strategy involving the introduction of ICBA into a PBDB-T-2F:IT-4F system is used to control the active layer morphology.
2:Sample Selection and Data Sources:
The study uses PBDB-T-2F as a wide bandgap polymer donor and ITIC-4F as a halogenated nonfullerene acceptor, with ICBA as a third component to optimize morphology.
3:List of Experimental Equipment and Materials:
Equipment includes a silicon wafer for blade coating, and materials include PBDB-T-2F, IT-4F, ICBA, and PDINO/Al for device fabrication.
4:Experimental Procedures and Operational Workflow:
The solution is dropped on glass and pulled by the movement of the blade to fabricate a uniform film with substrate heating. The film thickness is controlled by the gap between the blade and substrate and the speed of the blade.
5:Data Analysis Methods:
The study analyzes photovoltaic performance through J-V curves, energy loss through FTPS-EQE and EL spectra, and morphology through AFM and TEM images.
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