摘要： In organic electronics, the use of self-assembled monolayer dielectric functional groups is considered an effective surface modification strategy that can significantly improve device performance. A flexible polymer (PEDOT:PSS) photodetector on the substrate polyimide (PI) with broadband response (450 nm~980 nm) and high response (0.56 A/W) is reported, which is superimposed on the surface by small molecule (C60) thermal evaporation. In addition, the planeness of organic semiconductor and the overall performance of organic thin film photodetector can be improved significantly by using small molecule modified polymer thin film, the response of small molecule modified organic device is improved by an order of magnitude, which provides a guarantee for better application of organic thin films in circuits. Moreover, the device has strong flexibility stability performance, which can meet the requirements of flexible stability of future photoelectric devices.