研究目的
To report the first high-resolution continuous profile of dissolved methane in the shallow water of Lake Kivu, Rwanda, using an in situ dissolved gas sensor, and to compare the results with discrete in situ measurements conducted with the commercial HydroC? sensor.
研究成果
The Sub-Ocean sensor allowed fast vertical profiles of CH4 which are in good agreement with the discrete in situ measurements made with the commercial HydroC? HP sensor. The instrument is well suited for fast profiling in different water bodies and could be further adapted to the entire vertical column of Lake Kivu by using a less sensitive gas analyzer.
研究不足
The instrument could not measure below 150 m depth due to too large dissolved CH4 concentrations for the methane absorption spectrum to be correctly retrieved. The accuracy of the instrument was estimated to ±22 % (2σ) from the standard deviation of eight profiles at 80 m depth.
1:Experimental Design and Method Selection:
The Sub-Ocean sensor, based on a membrane-based extraction technique coupled with a highly sensitive optical spectrometer, was used for in situ measurements. The spectrometer and extraction system were modified to extend the dynamical range up to 6 orders of magnitude.
2:Sample Selection and Data Sources:
Measurements were performed in Lake Kivu, Rwanda, focusing on the top 150 m of the water column.
3:List of Experimental Equipment and Materials:
The Sub-Ocean sensor, HydroC? HP sensor, Sea-Bird Electronics SBE 5T pump, Sea & Sun Marine Tech CTD-60, and a subsea battery (Seacell, STR) were used.
4:Experimental Procedures and Operational Workflow:
The sensor was lowered at a speed of ~6 m min?1, with a response time of ~10 s, providing a vertical resolution of 1 m.
5:Data Analysis Methods:
The concentration of CH4 was calculated using the solubility of the gas in water under given physical conditions and its fugacity.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容