摘要： Programmable complex shape-deformation, multi-responsive property and convenient fabrication are all crucial for the development of actuators. However, a simultaneous realization of all these advantages has not been reported. Here, we report a new type of light- and humidity-driven actuator with programmable complex shape-deformations. The fabrication employs a laser printing technology. The light-driven actuation is based on a dual-mode actuation mechanism which utilizes the water adsorption/desorption properties. When irradiated by near infrared light, the actuator shows a large bending actuation with a curvature up to 2.1 cm-1. More importantly, programmable complex shape-deformations can be realized by printing patterns with different/gradient grayscale distributions on the actuators. The bending rates and amplitudes of actuators can be programmed and controlled. Complex 3D shapes, such as an anomalous tube and a helical cylinder, are obtained. In addition, the actuator can also perform a curvature of 1.3 cm-1 when driven by humidity. Finally, a series of smart biomimetic devices with programmable complex shape-deformations are demonstrated, including a self-adjustment iris responding to incident light, a biomimetic hand demonstrating a complex “OK” gesture, and a lotus with folding petals of different bending rates. This new-type actuator will have great potential in robotics and biomimetic applications.