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Strong Quantum Confinement Effects in Nanometer Devices with Graphene Directly Grown on Insulator by Catalyst-free Chemical Vapor Deposition

DOI:10.2174/2452273201666170221124819 期刊:Current Graphene Science 出版年份:2017 更新时间:2025-09-23 15:21:01
摘要: Background: The understanding of electrical properties of defective graphene in nanometer regime has lagged behind. Objective: This report intends to characterize defective but practically useful graphene as nanometer devices. Method: A-few-layer-thick graphene was directly grown on SiO2 substrate by alcohol-chemical vapor deposition (alcohol-CVD) using ethanol as carbon source and without the use of any catalytic metal. The graphene film was delineated into nanometer structures by electron beam lithography to make the nanoscale devices. Results: The Raman spectra of the graphene sheet on SiO2 shows relatively large D peak, which means the graphene is defective and consists of nanograins with an estimated size of 17 nm. Modulation of the graphene resistance by the gate voltage Vg was studied at room temperature. The film shows only p-type conduction, with a sheet resistance of 3.7 kΩ/□ and field-effect mobility calculated to be 44 cm2/Vs. From the temperature dependence of the graphene sheet, it is found that the resistance increases only by 7% from room temperature to 10 K, indicating low potential barrier between the domains, even though the graphene film is as thin as 1.6 nm and defective. From the conductance (Id/Vd) contour plot measured at 10 K of these nanodevices, aperiodic Coulomb-blockade feature and transport with a large gap were observed. Conclusion: Correlation among narrowest constriction widths, the variation of the addition energies and transport gaps in disordered graphene nanostructures is evident. These graphene nanodevices may have promising application in various nanodevices like single-electron (or single-hole) transistor, single-molecule transistor, van-der-Waals stacked nanodevices, etc.
作者: Hiroto Sato,Atsushi Nakamura,Amit Banerjee,Kenji Yamada,Hiroaki Satoh,Jiro Temmyo,Hiroshi Inokawa
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To characterize defective but practically useful graphene as nanometer devices.

The study demonstrated that defective graphene directly grown on SiO2 substrate by alcohol-CVD can be used to fabricate nanodevices with promising applications in various fields. The unique features of graphene were preserved even in disordered material, showing potential for applications in single-electron transistors, single-molecule transistors, and van-der-Waals stacked nanodevices.

The mechanism of transport in the present CVD graphene nanostructures is still not known in details, and is an interesting subject of study considering the possibility of application in several genres of nanodevices made of graphene.

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