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Thermochromism from Ultrathin Colloidal Sb <sub/>2</sub> Se <sub/>3</sub> Nanowires Undergoing Reversible Growth and Dissolution in an Amine-Thiol Mixture

DOI:10.1002/adma.201806164 期刊:Advanced Materials 出版年份:2018 更新时间:2025-09-23 15:21:01
摘要: Thermochromism from Ultrathin Colloidal Sb2Se3 Nanowires Undergoing Reversible Growth and Dissolution in an Amine–Thiol Mixture. Liquid-based thermochromics can be incorporated into an arbitrarily shaped container and provide a visual map of the temperature changes within its volume. However, photochemical degradation, narrow temperature range of operation, and the need for stringent encapsulation processes are challenges that can limit their widespread use. Here, a unique solution-based thermochromic comprising ultrathin colloidal Sb2Se3 nanowires in an amine–thiol mixture is introduced. The nanowires undergo reversible growth and dissolution with repeated cycles of heating and cooling between 20 and 160 °C, exhibiting intense and contrasting color changes during these processes. Furthermore, the transition temperature in which a change in color first appears can be continuously tuned over a range larger than 100 °C by introducing controlled amounts of Sn2+. The colloidal nanowire dispersion in the amine–thiol mixture retains its thermochromic properties over hundreds of temperature cycles, continuous heating at 80 °C over months, and shelf life of up to 2 years in an open container under ambient conditions. To illustrate its utility as a robust liquid thermochromic, the nanowire solution is coated onto standard filter paper and its uses as a rewritable surface by thermal scribing, as well as an inexpensive means of visualizing the temperature distribution of an anisotropically heated block are demonstrated.
作者: Wen-Ya Wu,Yang Xu,Xuanwei Ong,Sumit Bhatnagar,Yinthai Chan
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To introduce a versatile and robust liquid thermochromic system based on ultrathin colloidal Sb2Se3 nanowires in an amine–thiol mixture that undergoes reversible growth and dissolution with temperature changes, offering a wide temperature range of operation and excellent stability.

The study successfully demonstrates a novel liquid thermochromic system based on Sb2Se3 nanowires in an amine–thiol mixture, offering reversible color changes over a wide temperature range, excellent stability, and potential applications in temperature visualization and rewritable surfaces.

The study does not address the potential environmental impact of the materials used, and the scalability of the synthesis process for industrial applications is not discussed.

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