研究目的
To develop a new lead-free sol-gel composite, Bi4Ti3O12(BiT)/SrTiO3(ST), with high temperature durability and poling facility for ultrasonic transducers.
研究成果
The BiT/ST sol-gel composite demonstrated high temperature durability up to 500°C and the ability to polarize at room temperature, making it a promising lead-free material for high-temperature ultrasonic transducer applications.
研究不足
The ST sol-gel solution contained SrCO3 alongside SrTiO3, which may affect performance. The study suggests that removing SrCO3 could improve performance further.
1:Experimental Design and Method Selection:
The study involved the development of a BiT/ST sol-gel composite for ultrasonic transducers. The methodology included the fabrication of ST sol-gel solution, mixing with BiT powder, and fabrication of composite films on titanium substrates using sol-gel spray technique. Polarization processes were carried out at room temperature and 400°C. High temperature durability tests were performed from room temperature to 500°C.
2:Sample Selection and Data Sources:
Commercial BiT powder and self-manufactured ST sol-gel solution were used. The samples were fabricated on titanium substrates.
3:List of Experimental Equipment and Materials:
Equipment included a digital oscilloscope, pulser/receiver machine, hot plate, and XRD for analysis. Materials included strontium acetate, titanium butoxide, acetic acid, methanol, and BiT powder.
4:Experimental Procedures and Operational Workflow:
The ST sol-gel solution was fabricated by dissolving strontium acetate in deionized water, then adding to a mixture of titanium butoxide, acetic acid, and methanol. The mixture was ball milled for homogeneity. Films were fabricated by spray coating, followed by drying and firing processes. Polarization was performed using DC corona poling.
5:Data Analysis Methods:
Ultrasonic response was recorded and analyzed. Sensitivity was calculated to assess performance at various temperatures.
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