研究目的
Comparing ultrasonication method with mechanochemical deagglomeration method to find the homogenization and deagglomeration effects on the structural properties of BaTiO3 ceramics.
研究成果
Ultrasonication remarkably improves the structure of BaTiO3 ceramics in the shortest time, decreasing the particle sizes with perfect homogeneity and increasing the stability of the material. This method is more effective than mechanochemical deagglomeration for obtaining well-homogenized powders and decreasing the grain size of the powders.
研究不足
The study focuses on the structural differences of BaTiO3 ceramics modified by ultrasonic and mechanochemical methods, but does not explore the electrical or optical properties in depth. The comparison is limited to two deagglomeration methods.
1:Experimental Design and Method Selection:
BaTiO3 powders were synthesized by a solid-state method modified with two deagglomeration methods, ultrasonic and mechanochemical deagglomeration methods.
2:Sample Selection and Data Sources:
BaCO3 and TiO2 (Merck, 99.9%) were used as starting materials.
3:9%) were used as starting materials. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Ultrasonic processor with 7 mm titanium probe (Hielscher Ultrasonics GmbH, Deutschland), shaker (Edmund Bühler, Deutschland), Fourier Transform Infrared Spectroscopy (FT-IR) (Shimadzu, IRAffinity-1S, Japon), X-ray diffractometer (Rigaku, Smartlab, Japan), electron microscope (SEM) (JEOL, JSM 5500LV, Japan), energy dispersive X-ray spectroscopy (EDX) (Oxford, INCAx-act, England).
4:Experimental Procedures and Operational Workflow:
Homogenization using ultrasonic processor for 5 min in 30 ml acetone and using shaker for 12 h in 20 ml acetone. The mixed powders were dried at 110°C and calcined at 1100°C for 4 h. The powders were pressed into pellets and sintered at 1400°C for 8 h.
5:Data Analysis Methods:
FT-IR and XRD were used to verify the structure of the samples. SEM and EDX were used to analyze the surface morphology and composition of the ceramic powders and pellets.
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Fourier Transform Infrared Spectroscopy
IRAffinity-1S
Shimadzu
Checking the process of the samples
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X-ray diffractometer
Smartlab
Rigaku
Characterizing the structure of the calcined powders
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Electron microscope
JSM 5500LV
JEOL
Analyzing the surface morphology of the ceramic powders pellet
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Energy dispersive X-ray spectroscopy
INCAx-act
Oxford
Analyzing the composition of the samples
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Ultrasonic processor
7 mm titanium probe
Hielscher Ultrasonics GmbH
Homogenization of BaCO3 and TiO2 powders
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Shaker
Edmund Bühler
Mixing powders and zirconium balls in a polypropylene vial
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