研究目的
To measure the real and imaginary parts of the dielectric function of VO2 thin films across its metal-insulator transition using visible-infrared ellipsometry and to analyze the applicability of Bruggeman’s effective medium model for describing the dielectric function in different wavelength ranges.
研究成果
The study successfully measures the dielectric function of VO2 thin films across its phase transition and demonstrates the applicability of Bruggeman’s model for certain wavelength ranges. The hysteresis loop of the VO2 emissivity is consistent with previous measurements, providing valuable data for optical and radiative applications.
研究不足
Bruggeman’s effective medium model is suitable for describing the dielectric function in visible and near-infrared wavelengths but generally fails for longer infrared wavelengths. The substrate effect is significant in the insulating phase due to the high transmittance of VO2 in the IR region.
1:Experimental Design and Method Selection:
The study employs visible-infrared ellipsometry to measure the dielectric function of VO2 thin films across its phase transition. The Tauc-Lorentz, Gaussian, and Drude oscillator models are used to describe the ellipsometric signals.
2:Sample Selection and Data Sources:
VO2 thin films are deposited on r-plane sapphire via pulsed laser deposition. The crystalline structure and Raman spectra are analyzed to confirm the phase transition.
3:List of Experimental Equipment and Materials:
A M-2000 ellipsometer and IR-VASE Mark-II ellipsometer are used for measurements. A KrF pulsed excimer laser is used for film deposition.
4:Experimental Procedures and Operational Workflow:
Ellipsometric signals are measured across a range of wavelengths and temperatures during both heating and cooling processes. The temperature is controlled and measured with precision.
5:Data Analysis Methods:
The CompleteEASE? software is used for data analysis, fitting the experimental data to oscillator models to determine the dielectric function.
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