摘要： Purpose – This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles. Design/methodology/approach – Sol-gel methods have been used to design superhydrophobic glass substrates through surface modi?cation by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace. Findings – The glass substrate achieved the water contact angle as high as 154 6 2° and 150.4 6 2° for Si/ITMS and Si/ETMS ?lms, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS ?lm sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C. Research limitations/implications – Findings will be useful to develop superhydrophobic coatings with high thermal stability. Practical implications – Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness. Originality/value – Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.