研究目的
Investigating the applicability and limitations of selected optical scattering instruments for PM mass measurement by evaluating their responses to different particle characteristics (size, composition, concentration) and comparing them with reference instruments.
研究成果
The study found that the response of optical scattering instruments to aerosol mass concentration is strongly dependent on aerosol size and to a lesser extent on aerosol composition. A Mie scattering calculation was used to explain the instrument responses. The study highlights the importance of considering aerosol size distribution and composition when using optical scattering sensors for PM mass measurement. Despite the complexity of determining calibration factors, these compact optical instruments can provide reliable data covering a greater spatial extent with additional studies and measurements.
研究不足
The study focused on dry aerosol (RH below 40%), and the dependence of optical instruments on RH needs further study. The SMPS measurements had an upper size limit < 700 nm, and AMS measurements had an upper size limit < 1000 nm, detecting only non-refractory species. The study period was relatively short, and more ambient measurements are needed to fully map out the range of calibration factors required for optical instruments.
1:Experimental Design and Method Selection:
The study evaluated the performance of optical sensors (DRX, PDR, and OPC-N2) using poly- and mono-disperse test aerosol in the laboratory and sampling ambient aerosol. A Mie scattering calculation was used to explain the dependence of the optical instruments’ response to aerosol size and composition.
2:Sample Selection and Data Sources:
Mono-disperse PSL particles and synthetic particles with different chemical compositions were used in laboratory tests. Ambient aerosol was sampled for field tests.
3:List of Experimental Equipment and Materials:
Instruments included Thermo Personal Data RAM (PDR-1500), TSI Environmental DustTrak DRX (Model 8543), Alphasense Optical Particle Counter (OPC-N2), TSI Scanning Mobility Particle Sizer (SMPS), Aerodyne HR-TOF-AMS, and a tapered element oscillating microbalance (TEOM).
4:Experimental Procedures and Operational Workflow:
Laboratory tests involved generating aerosol with a constant output atomizer, drying the aerosol, and sampling with the instruments. Ambient tests involved connecting instruments to a dryer and sampling outside air.
5:Data Analysis Methods:
Data from optical instruments were compared with reference instruments. Mie scattering calculations were performed to understand instrument responses.
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