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Exploring the applicability and limitations of selected optical scattering instruments for PM mass measurement

DOI:10.5194/amt-11-2995-2018 期刊:Atmospheric Measurement Techniques 出版年份:2018 更新时间:2025-09-09 09:28:46
摘要: Two optical scattering instruments for particle mass measurement, the Thermo Personal Data RAM (PDR-1500) and the TSI Environmental DustTrak DRX (Model 8543) were evaluated by (1) using poly- and mono-disperse test aerosol in the laboratory, and (2) sampling ambient aerosol. The responses of these optical scattering instruments to different particle characteristics (size, composition, concentration) were compared with responses from reference instruments. A Mie scattering calculation was used to explain the dependence of the optical instruments’ response to aerosol size and composition. Concurrently, the detection efficiency of one Alphasense Optical Particle Counter (OPC-N2) was evaluated in the laboratory as well. The relationship between aerosol mass concentration and optical scattering was determined to be strongly dependent on aerosol size and to a lesser extent on aerosol composition (as reflected in the refractive indices of the materials tested) based on ambient measurements. This confirms that there is no simple way to use optical scattering instruments over a wide range of conditions without adjustments based on knowledge of aerosol size and composition. In particular, a test period measuring ambient aerosol with optical scattering instruments and a mass based method (an Aerodyne Aerosol Mass Spectrometer) determined that roughly two thirds of the variance (R2 = 0.64) of the optical to mass signal ratio is explained by the aerosol mass median diameter alone. These observations and calculations help evaluate the applicability and limitations of these optical scattering instruments, and provide guidance to designing suitable applications for each instrument by considering aerosol sources and aerosol size.
作者: Jie Zhang,Joseph P. Marto,James J. Schwab
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Investigating the applicability and limitations of selected optical scattering instruments for PM mass measurement by evaluating their responses to different particle characteristics (size, composition, concentration) and comparing them with reference instruments.

The study found that the response of optical scattering instruments to aerosol mass concentration is strongly dependent on aerosol size and to a lesser extent on aerosol composition. A Mie scattering calculation was used to explain the instrument responses. The study highlights the importance of considering aerosol size distribution and composition when using optical scattering sensors for PM mass measurement. Despite the complexity of determining calibration factors, these compact optical instruments can provide reliable data covering a greater spatial extent with additional studies and measurements.

The study focused on dry aerosol (RH below 40%), and the dependence of optical instruments on RH needs further study. The SMPS measurements had an upper size limit < 700 nm, and AMS measurements had an upper size limit < 1000 nm, detecting only non-refractory species. The study period was relatively short, and more ambient measurements are needed to fully map out the range of calibration factors required for optical instruments.

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