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Sulfur dioxide (SO<sub>2</sub>) vertical column density measurements by Pandora spectrometer over the Canadian oil sands

DOI:10.5194/amt-9-2961-2016 期刊:Atmospheric Measurement Techniques 出版年份:2016 更新时间:2025-09-04 15:30:14
摘要: Vertical column densities (VCDs) of SO2 retrieved by a Pandora spectral sun photometer at Fort McKay, Alberta, Canada, from 2013 to 2015 were analysed. The Fort McKay site is located in the Canadian oil sands region, approximately 20 km north of two major SO2 sources (upgraders), with total emission of about 45 kt yr?1. Elevated SO2 VCD values were frequently recorded by the instrument, with the highest values of about 9 Dobson Units (DU; DU = 2.69 × 1016 molecules cm?2). Comparisons with co-located in situ measurements demonstrated that there was a very good correlation between VCDs and surface concentrations in some cases, while in other cases, elevated VCDs did not correspond to high surface concentrations, suggesting the plume was above the ground. Elevated VCDs and surface concentrations were observed when the wind direction was from south to southeast, i.e. from the direction of the two local SO2 sources. The precision of the SO2 measurements, estimated from parallel measurements by two Pandora instruments at Toronto, is 0.17 DU. The total uncertainty of Pandora SO2 VCD, estimated using measurements when the wind direction was away from the sources, is less than 0.26 DU (1σ ). Comparisons with integrated SO2 pro?les from concurrent aircraft measurements support these estimates.
作者: Vitali E. Fioletov,Chris A. McLinden,Alexander Cede,Jonathan Davies,Cristian Mihele,Stoyka Netcheva,Shao-Meng Li,Jason O’Brien
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To analyze vertical column densities (VCDs) of SO2 retrieved by a Pandora spectral sun photometer over the Canadian oil sands and to study the relationship between total columns and surface concentrations.

The Pandora spectrometer is effective for monitoring SO2 VCDs in regions with significant emissions, such as the Canadian oil sands. The study demonstrated a correlation between VCDs and surface concentrations under certain conditions, with the instrument's precision and uncertainty well characterized. However, elevated VCDs did not always correspond to high surface concentrations, indicating the presence of plumes above the ground. The research supports the use of ground-based measurements for validating satellite data and improving air quality monitoring.

The study's limitations include the instrument's sensitivity to ozone absorption features, which can introduce errors in SO2 retrievals, and the need for further algorithm development to improve accuracy. Additionally, the comparison between satellite and ground-based measurements was limited by satellite pixel size and measurement uncertainties.

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