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Hyperspectral inversion of heavy metal content in reclaimed soil from a mining wasteland based on different spectral transformation and modeling methods

DOI:10.1016/j.saa.2018.12.032 期刊:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 出版年份:2018 更新时间:2025-09-04 15:30:14
摘要: Conventional methods for investigating heavy metal contamination in soil are time consuming and expensive. We explored reflectance spectroscopy as an alternative method for assessing heavy metals. Four spectral transformation methods, first-order differential (FDR), second-order differential (SDR), continuum removal (CR) and continuous wavelet transform (CWT), are used for the original spectral data. Spectral preprocessing effectively eliminated the noise and baseline drifting and also highlighted the locations of the spectral feature bands. Partial least squares regression (PLSR) and radial basis function neural network (RBF) were used to study the hyperspectral inversion of four heavy metals (Cr, As, Ni, Cd). The inversion models of four heavy metals were established in the bands with the highest correlation coefficient. The inversion effects were evaluated by the coefficient of determination (R2), root mean square error (RMSE) and residual predictive deviation (RPD) indexes. The R values of the correlation coefficient were significantly improved after smoothing and spectral transformation compared to the original waveband. The method combining continuous wavelet transform (CWT) with radial basis function neural network (RBF) had the best inversion effect on the four heavy metals. When compared to partial least squares regression (PLSR), the RMSE values were reduced by approximately 2. The CWT-RBF method can be used as a means of inversion of heavy metals in mining wasteland reclaimed land.
作者: Shiwen Zhang,Qiang Shen,Chaojia Nie,Yuanfang Huang,Jianhua Wang,Qingqing Hu,Xuejiao Ding,Yan Zhou,Yuanpeng Chen
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Investigating the therapeutic effects of a specific herbal medicine on a particular disease.

By combining CWT with an RBF neural network, we explored the concentrations of four heavy metals (Cr, As, Ni, and Cd) in an inversion model. The model precision was studied by applying and comparing different methods to the inversion model. The results showed that the heavy metal hyperspectral inversion model could effectively improve the prediction ability of heavy metals by using a CWT-RBF method.

The spectral characteristics of the soil samples were affected by the combined effects of soil texture, pH, salt, organic matter, iron oxide, and the presence of heavy metals, combined with natural environmental factors, such as soil parent material and soil formation conditions. The unique environmental background of reclaimed mining wasteland soil, and the spectral characteristics of soil heavy metal concentrations, were complex and displayed regional characteristics.

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