研究目的
Investigating the corrosion susceptibility of three types of Ag-based metallizations (HT Ag Paste, LT Ag Paste, and RSI) to dilute acetic acid, comparable to conditions in field-exposed photovoltaic modules.
研究成果
HT Ag Paste and RSI are more susceptible to corrosion by acetic acid than LT Ag Paste. The study presents a methodology to study corrosion in a controlled manner, useful for future research on corrosion resistance in solar cell metallizations.
研究不足
The study focuses on corrosion by acetic acid under controlled conditions, which may not fully replicate all environmental factors in field-exposed modules. Quantitative characterization of corrosion rates and the influence of non-Ag constituents require further investigation.
1:Experimental Design and Method Selection:
Samples were exposed to dilute acetic acid to mimic conditions in field-exposed modules. Raman spectroscopy and SEM were used to monitor corrosion.
2:Sample Selection and Data Sources:
Three sets of samples (HT Ag Paste, LT Ag Paste, RSI) were prepared on Si substrates.
3:List of Experimental Equipment and Materials:
Renishaw Confocal InVia Raman system, Amray 1910 Field Emission SEM, acetic acid solutions, cellulose sponge.
4:Experimental Procedures and Operational Workflow:
Samples were exposed to acetic acid in sealed containers, intermittently monitored by Raman spectroscopy and SEM over 2936 h.
5:Data Analysis Methods:
Raman spectra were analyzed for the presence of silver acetate, SEM images were compared before and after exposure.
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