研究目的
Investigate the properties of ZnO:Al thin films for use as flexible electrodes in optoelectronic devices.
研究成果
ZnO:Al thin films deposited at room temperature on polyimide substrates showed satisfactory properties for flexible optoelectronic applications, with a resistivity of 6x10-4 W.cm and transmittance of 75% in the visible range. Optimal deposition conditions were identified, balancing electrical and optical properties.
研究不足
The study was limited by the substrate's influence on film properties, particularly the higher roughness of polyimide compared to glass, which affected electrical resistance. Additionally, the need for thicker films to reduce resistance could impact optical transmittance and introduce internal stresses.
1:Experimental Design and Method Selection:
The study utilized radio frequency magnetron sputtering to deposit ZnO:Al thin films on polyimide and soda lime glass substrates at room temperature. The effects of power and thickness on the films' properties were examined.
2:Sample Selection and Data Sources:
Films were deposited on polyimide (Kapton? 100CS) and soda lime glass substrates. The polyimide substrates were provided by Dupont.
3:List of Experimental Equipment and Materials:
A non-commercial radio frequency magnetron sputtering system was used. Targets were ZnO:Al (98% ZnO/2% Al) from AJA International. Characterization tools included a Veeco Dektak 150 profilometer, Bio-Rad HL 5500 Hall effect measurement system, Varian Cary 5000 spectrophotometer, and Park Systems XE7 atomic force microscope.
4:Experimental Procedures and Operational Workflow:
Films were deposited at various working powers (45 to 180 W) with argon pressure at 1 mTorr. Substrates were cleaned ultrasonically with deionized water and neutral detergent. The deposition rate was monitored, and film thickness was controlled to around 180 nm for initial studies.
5:Data Analysis Methods:
Electrical properties were measured using the Van der Pauw method. Optical transmittance was measured, and the bandgap was calculated from absorption spectra. Surface morphology was analyzed using atomic force microscopy.
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