1：Experimental Design and Method Selection:

The study involves a heat-assisted photoacidic oxidation (HAPO) method using photoacid generators (PAGs) to hydroxylate polymer surfaces, followed by self-assembled monolayer (SAM) deposition. Methods include UV ozone treatment for certain polymers and HAPO for others, with characterization via AFM, FT-IR, XPS, GIXD, and electrical measurements.

2：Sample Selection and Data Sources:

Four high-k polymers were selected: poly(4-vinyl alcohol) (PVA), poly(4-vinyl phenol) (PVP), polychloroprene (PCP), and poly(acrylonitrile-co-butadiene) (PAB). Samples were prepared on Si substrates by spin-coating and crosslinking.

3：List of Experimental Equipment and Materials:

Equipment includes spin coaters, UV lamps, UV ozone cleaner, AFM, FT-IR spectrometer, XPS, GIXD, ellipsometer, contact angle meter, LCR meter, semiconductor analyzer. Materials include polymers, crosslinking agents, PAGs (e.g., triflate), organosilanes (e.g., OTS), solvents (e.g., toluene, γ-butyrolactone).

4：Experimental Procedures and Operational Workflow:

Polymer films were prepared, crosslinked, oxidized via UVO or HAPO, then immersed in SAM solutions at controlled temperatures (0°C or 30°C), washed, baked, and characterized. OTFT devices were fabricated by depositing organic semiconductors and electrodes.

5：Data Analysis Methods:

Data were analyzed using software for AFM, FT-IR, XPS, GIXD, and electrical measurements to assess surface properties, SAM ordering, and device performance.