1：Experimental Design and Method Selection:

The study used a conventional solid-state reaction method to synthesize Ca5(BO3)3F: Tb3+/Eu3+ phosphors, with XRD for phase confirmation, and various spectroscopic techniques for luminescence analysis. Theoretical models included Dexter's energy transfer formula and Arrhenius equation for thermal stability.

2：Sample Selection and Data Sources:

Samples were prepared with varying concentrations of Tb3+, Eu3+, and charge compensators (Li+, Na+, K+), using raw materials like CaCO3, H3BO3, CaF2, Eu2O3, Tb4O7, and M2CO

3：List of Experimental Equipment and Materials:

Equipment included Rigaku D/max-ⅡB X-ray diffractometer, Philips-FEI Tecnai G2 S-Twin F20 TEM, JSM-6700F SEM with EDX, Edinburgh Instruments FLS920 fluorescence spectrometer with R928 photomultiplier tube and 450 W xenon lamp, and integrating sphere for quantum efficiency.

4：Experimental Procedures and Operational Workflow:

Raw materials were ground, sintered at 1050°C for 5 hours, cooled, and ground again. Measurements involved XRD for structure, TEM/SEM for morphology, PL/PLE spectra for luminescence, decay curves for lifetimes, and temperature-dependent spectra for thermal stability.

5：Data Analysis Methods:

Data were analyzed using GSAS for Rietveld refinement, linear fits for energy transfer mechanisms, and Arrhenius plots for activation energy calculation.