1：Experimental Design and Method Selection:

The study involves synthesizing ASiO3 (A= Ca, Ba, Sr) phosphors doped with Eu2+ and Er3+ ions using conventional solid state reaction method, followed by structural, morphological, and thermoluminescent analyses. Theoretical models include crystallographic analysis and kinetic parameter estimation using CGCD and peak shape methods.

2：Sample Selection and Data Sources:

Samples are synthesized with doping concentrations varying from 0 mol% to 1 mol% for both Eu2+ and Er3+ ions. Primary reactants include CaCO3, BaCO3, SrCO3, SiO2, Eu2O3, and Er2O3 with 99.99% purity from Sigma Aldrich.

3：99% purity from Sigma Aldrich. List of Experimental Equipment and Materials:

3. List of Experimental Equipment and Materials: Equipment includes PANalytical XPERT-Powder X-ray diffractometer for PXRD, JEOL-JSM-5200 for FESEM, Hitachi H-600 TEM analyzer, and TL/OSL Reader 1008 from Nucleonix Systems. Materials are the chemical reactants listed.

4：Experimental Procedures and Operational Workflow:

Synthesis involves grinding stoichiometric mixtures, calcining at 1000°C for 1.5 hr, grinding again, and heating at 1350°C for 4 hrs. PXRD, FESEM, and TEM analyses are performed. TL behavior is studied after UV (254 nm for 5 min) and gamma (5 Gy from Co60 source) irradiation, with heating at 10°C/s up to 500°C.

5：5 hr, grinding again, and heating at 1350°C for 4 hrs. PXRD, FESEM, and TEM analyses are performed. TL behavior is studied after UV (254 nm for 5 min) and gamma (5 Gy from Co60 source) irradiation, with heating at 10°C/s up to 500°C. Data Analysis Methods:

5. Data Analysis Methods: Kinetic parameters (activation energy, order of kinetics, etc.) are estimated using CGCD technique with Glowfit and TLanal software, and peak shape method.