1：Experimental Design and Method Selection:

The study utilized thiol-ene "click" chemistry for polymerization, involving UV-initiated radical addition reactions. Rare earth ion coordination was employed to modify fluorescence properties.

2：Sample Selection and Data Sources:

Monomers used were 1,3-diethenyl-1,1,3,3-tetramethyl-disiloxane (MMvi) and trimethylolpropane tris(3-mercaptopropionic acid) ester (TTMP), with initiator 2,2-Dimethoxy-2-phenylacetophenone (DMPA). Rare earth salts Eu(NO3)3 and Tb(NO3)3 were coordinated. HeLa cells were used for biological imaging.

3：List of Experimental Equipment and Materials:

UV lamp for irradiation, NMR spectrometer (400 MHz and 100 MHz), FT-IR spectrometer, Abbe refractometer, TGA instrument, fluorescence spectrometer, confocal microscope. Materials included THF, methanol, and various chemicals as specified.

4：Experimental Procedures and Operational Workflow:

For P1 and P2 synthesis, mixtures of monomers and initiator in THF were irradiated under UV lamp for 30 minutes, followed by purification with methanol. For P1-Ln3+, P1 was mixed with rare earth salts in THF and stirred for 24 hours. Cell imaging involved incubating HeLa cells with complexes and using MTT assay for cytotoxicity.

5：Data Analysis Methods:

NMR and FT-IR for structural characterization, GPC for molecular weight, refractive index measured with Abbe refractometer, fluorescence spectra analyzed, TGA for thermal stability, and image analysis for cell studies.